Process for making crosslinked cable insulation using high melt strength ethylene-based polymer made in a tubular reactor and optionally modified with a branching agent
US-11912852-B2 · Feb 27, 2024 · US
US9669385B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9669385-B2 |
| Application number | US-201615337033-A |
| Country | US |
| Kind code | B2 |
| Filing date | Oct 28, 2016 |
| Priority date | Dec 3, 2013 |
| Publication date | Jun 6, 2017 |
| Grant date | Jun 6, 2017 |
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Disclosed herein are a superabsorbent polymer resin incorporated with a particles meeting the following properties i) to ii): i) a BET specific surface area of 300 to 1500 m 2 /g, ii) a porosity of 50% or more, and a method for preparing the same.
Opening claim text (preview).
The invention claimed is: 1. A superabsorbent polymer resin, meeting both the conditions represented by the following Mathematical Formulas 1 and 2: RA 1= D am (850 μm+)/ D bm (850 μm+)≧0.2 [Math Formula 1] RA 2= D am (600 μm+)/ D bm (600 μm+)≧0.65 [Math Formula 2] (wherein, D am (x μm+) is a proportion of superabsorbent polymer resins having a particle size of x μm or greater after milling and D bm (x μm+) is a proportion of superabsorbent polymer resins having a particle size of x μm or greater before milling). 2. The superabsorbent polymer resin of claim 1 , further meeting the condition represented by the following Mathematical Formula 3: RA3=[ D bm (850 μm+)/ D bm (150˜850 μm)]*100≦4.0 [Math Formula 3] (wherein, D bm (x μm+) is a proportion of superabsorbent polymer resins having a particle size of x μm or greater before milling, and D bm (y˜z μm) is a proportion of superabsorbent polymer resins having a particle size of from y μm to z μm before milling). 3. The superabsorbent polymer resin of claim 1 , further meeting the condition represented by the following Mathematical Formula 4: RA4=[ D bm (850 μm+)/ D bm (300˜850 μm)]*100≦4.5 [Math Formula 4] (wherein, D bm (x μm+) is a proportion of superabsorbent polymer resins having a particle size of x μm or greater before milling, and D bm (y˜z μm) is a proportion of superabsorbent polymer resins having a particle size of from y μm to z μm before milling). 4. The superabsorbent polymer resin of claim 1 , wherein the superabsorbent polymer resin is incorporated with a particle meeting the following properties i) to ii): i) a BET specific surface area of 300 to 1500 m 2 /g, ii) a porosity of 50% or more. 5. A superabsorbent polymer resin, meeting both the conditions represented by the following Mathematical Formulas 2 and 3: RA 2= D am (600 μm+)/ D bm (600 μm+)≧0.65 [Math Formula 2] RA 3=[ D bm (850 μm+)/ D bm (150˜850 μm)]*100≦4.0 [Math Formula 3] (wherein, D am (x μm+) is a proportion of superabsorbent polymer resins having a particle size of x μm or greater after milling, D bm (x μm+) is a proportion of superabsorbent polymer resins having a particle size of x μm or greater before milling, and D bm (y˜z μm) is a proportion of superabsorbent polymer resins having a particle size of from y μm to z μm before milling). 6. The superabsorbent polymer resin of claim 5 , further meeting the condition represented by the following Mathematical Formula 4: RA 4=[ D bm (850 μm+)/ D bm (300˜850 μm)]*100≦4.5 [Math Formula 4] (wherein, D bm (x μm+) is a proportion of superabsorbent polymer resins having a particle size of x μm or greater before milling, and D bm (y˜z μm) is a proportion of superabsorbent polymer resins having a particle size of from y μm to z μm before milling). 7. The superabsorbent polymer resin of claim 5 , wherein the superabsorbent polymer resin is incorporated with a particles meeting the following properties i) to ii): i) a BET specific surface area of 300 to 1500 m 2 /g, ii) a porosity of 50% or more.
the macromolecular compounds being water soluble or water swellable, e.g. aqueous gels · CPC title
Compositions of unspecified macromolecular compounds · CPC title
Expanded, porous or hollow particles · CPC title
Homopolymers or copolymers of acids; Metal or ammonium salts thereof · CPC title
Differential crosslinking of one polymer with one crosslinking type, e.g. surface crosslinking · CPC title
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