High voltage electrolyte and lithium ion battery

Patent metadata

Field	Value
Publication number	US-9666906-B2
Application number	US-201514709525-A
Country	US
Kind code	B2
Filing date	May 12, 2015
Priority date	May 15, 2014
Publication date	May 30, 2017
Grant date	May 30, 2017

Abstract

The present application discloses a high voltage electrolyte including an electrolyte solvent which includes a mixture of a dinitrile solvent and a nitrile solvent and is stable at voltage of about 5 V or above. The dinitrile solvent may include at least one selected from the group consisting of malononitrile, succinonitrile, glutaronitrile, adiponitrile, pimelonitrile, suberonitrile, azelanitrile and sebaconitrile. The nitrile solvent may include at least one selected from the group consisting of acetonitrile, propionitrile, butyronitrile, pivalonitrile and capronitrile. The present application also discloses a lithium ion battery including the above high voltage electrolyte. The lithium ion battery exhibits a cyclic performance of greater than about 300 cycles and with a capacity retention of greater than about 80%.

First claim

What is claimed is:

1. A high voltage electrolyte comprising an electrolyte solvent which comprises a mixture of a dinitrile solvent and a nitrile solvent, wherein the electrolyte is stable at voltage of about 5 V, wherein the volume ratio of the dinitrile solvent to the nitrite solvent is in the range of about 90:10 to 50:50, wherein the dinitrile solvent is adiponitrile and the nitrile solvent is butyronitrile, wherein the mixture of the dinitrile solvent and the nitrile solvent is in an amount of about 10-40% of the total volume of the high voltage electrolyte.

2. The high voltage electrolyte of claim 1 further comprising at least one additive.

3. The high voltage electrolyte of claim 2 , wherein the additives are selected from the group consisting of vinyl carbonate (VC), 4-fluoro-1,3-dioxolan-2-one (FEC) and 4-vinyl-1,3-dioxolan-2-one (VEC).

4. The high voltage electrolyte of claim 2 , wherein the additive is in an amount of about 0.1-10% by volume of the electrolyte solvent.

5. The high voltage electrolyte of claim 1 , wherein the mixture of the dinitrile solvent and the nitrile solvent is in an amount of about 25% of the total volume of the high voltage electrolyte.

6. A lithium ion battery comprising a cathode, an anode and an electrolyte,
wherein the electrolyte comprises an electrolyte solvent comprising a mixture of a dinitrile solvent and a nitrile solvent,
wherein the lithium ion battery is stable at voltage of about 5 V,
wherein the volume ratio of the dinitrile solvent to the nitrile solvent is in the range of about 90:10 to 50:50,
wherein the dinitrile solvent is adiponitrile and the nitrile solvent is butyronitrile, and
wherein the mixture of the dinitrile solvent and the nitrile solvent is in an amount of about 10-40% of the total volume of the high voltage electrolyte.

7. The lithium ion battery of claim 6 , wherein the electrolyte further comprises one or more additives.

8. The lithium ion battery of claim 7 , wherein the additives are selected from the group consisting of vinyl carbonate (VC), 4-fluoro-1,3-dioxolan-2-one (FEC) and 4-vinyl-1,3-dioxolan-2-one (VEC).

9. The lithium ion battery of claim 7 , wherein the additive is in an amount of about 0.1-10% by volume of the electrolyte solvent.

10. The lithium ion battery of claim 6 , wherein the lithium ion battery has a cyclic performance of about 300 cycles and with a capacity retention of about 80%.

Assignees

• Nano & Advanced Materials Inst Ltd

Inventors

• Ho Kam Piu
• Ho Kwok Keung Paul
• Wang Ranshi
• Xu Yeming
• Luk Wai Chun
• Hsu Mei Mei

Classifications

• H01M10/0567

  characterised by the additives · CPC title

• H01M10/0569 Primary

  characterised by the solvents · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M2300/0037

  Mixture of solvents · CPC title

• Y02E60/10

  Energy storage using batteries · CPC title