Method for accessing the quality of membrane electrodes assemblies

Patent metadata

Field	Value
Publication number	US-9666883-B2
Application number	US-201314391549-A
Country	US
Kind code	B2
Filing date	Mar 19, 2013
Priority date	Apr 17, 2012
Publication date	May 30, 2017
Grant date	May 30, 2017

Abstract

A method for assessing the quality of a membrane electrode assembly (MEA), the method comprising:
applying a first voltage across the thickness of a first (MEA) passed through a nip of a first pair of rollers thereby providing a first charge to the first MEA; determining a first electrical figure of merit (FOM) of the first charged MEA at a first period of time; after the first period of time applying a second voltage across the thickness of the first (MEA) passed through a nip of a second pair of rollers thereby providing a second charge to the first (MEA); determining a second electrical (FOM) of the second charged first (MEA) at a second, later period of time; and calculating a total electrical (FOM) using the first and second electrical (FOM); and comparing the total electrical (FOM) to a predetermined quality value to assess the quality of the first (MEA).

First claim

What is claimed is:

1. A method for assessing the quality of at least one membrane electrode assembly, the method comprising:
providing a first membrane electrode assembly having a thickness;
applying a first voltage across the thickness of the first membrane electrode assembly when passing the first membrane electrode assembly through a nip of a first pair of rollers thereby providing a first charge to the first membrane electrode assembly;
determining a first electrical figure of merit of the first charged membrane electrode assembly at a first period of time;
after the first period of time applying a second voltage across the thickness of the first membrane electrode assembly when passing the first membrane electrode assembly through a nip of a second pair of rollers thereby providing a second charge to the first membrane electrode assembly;
determining a second electrical figure of merit of the second charged first membrane electrode assembly at a second, later period of time; and
calculating a total electrical figure of merit using the first and second electrical figures of merit; and
comparing the total electrical figure of merit to a predetermined quality value to assess the quality of the first membrane electrode assembly,

wherein the first membrane electrode assembly has a width parallel to the respective axes of the rollers, and wherein the first and second charges are lines of charge on a web comprising the first membrane electrode assembly, and each of the lines of charge is greater in width than the widths of the first membrane electrode assembly.

2. The method of claim 1 , wherein the first electrical figure of merit is an array of values determined during the first period of time, and wherein the second electrical figure of merit electrical figure of merit is an array of values determined during the second period of time.

3. The method of claim 1 , wherein the first electrical figure of merit is at least one of voltage or current and the second electrical figure of merit is at least one of voltage or current.

4. The method of claim 1 , wherein each of the first and second roller pairs have parallel axes of rotation, and wherein each of the charges is applied in a line parallel to the axes of rotation of the respective roller pairs.

5. The method of claim 1 , wherein the membrane electrode assemblies each have width parallel to the respective axes of the rollers, and wherein each of the lines of charge is greater than the widths of the membrane electrode assemblies.

6. The method of claim 1 , wherein the lines of charge independently have a length of at least 15 cm.

7. The apparatus of claim 1 , wherein the first and second roller pairs are at least 8 cm apart.

8. The method of claim 1 further comprising:
applying a first voltage across the thickness of a second membrane electrode assembly thereby providing a first charge to the second membrane electrode assembly;
determining a first electrical figure of merit of a second charged membrane electrode assembly at a first period of time;
after a first point in time applying a second voltage across the thickness of the second membrane electrode assembly thereby providing a second charge to the second membrane electrode assembly;
determining a second electrical figure of merit of the second charged membrane electrode assembly at a second, later period of time; and
calculating a total electrical figure of merit using the first and second electrical figures of merit; and
comparing the total electrical figure of merit to a predetermined quality value to assess the quality of the second membrane electrode assembly.

9. The method of claim 1 , wherein the first electrical figure of merit is voltage and the second electrical figure of merit is voltage.

10. The method of claim 1 , wherein the first electrical figure of merit is current and the second electrical figure of merit is current.

11. The apparatus of claim 1 , wherein the first electrical figure of merit is both voltage and current and the second electrical figure of merit is both voltage and current.

12. The method of claim 1 , wherein the difference in time between the first and second periods of time is not greater than 5 seconds.

13. The method of claim 1 , wherein the first applied voltage is not less than the second voltage.

14. The method of claim 1 , wherein the first applied voltage is not greater than the second voltage.

Assignees

• 3M Innovative Properties Co

Inventors

• Knudson Orlin B
• Pierpont Daniel M
• Poch James F

Classifications

• H01M8/04544 Primary

  Voltage · CPC title

• G01R19/0084

  Measuring voltage only · CPC title

• H01M4/86

  Inert electrodes with catalytic activity, e.g. for fuel cells · CPC title

• H01M8/04 Primary

  Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids · CPC title

• H01M8/04574

  Current · CPC title