High surface area nano fibers for supercapacitor devices

Patent metadata

Field	Value
Publication number	US-9666380-B1
Application number	US-201314133998-A
Country	US
Kind code	B1
Filing date	Dec 19, 2013
Priority date	Nov 22, 2011
Publication date	May 30, 2017
Grant date	May 30, 2017

Abstract

An apparatus and method for the uniform dispersion of nano scaled redox particles in a conductive fiber including, combining at least one nano sized redox capable material having metal oxides and/or metals, at least one conductive binder, and at least one solvent to form electrically conductive metal imbedded fiber(s) by fiber spinning and the conductive polymeric binder having a molecular weight greater than 20,000 Daltons, and coating a substrate with the electrically conductive fiber(s) to form an active layer/substrate complex having a conductivity greater than 0.05 S/cm.

First claim

What is claimed:

1. A method for uniform dispersion of nano scaled redox particles in a conductive fiber or fibers, comprising:
combining at least one nano sized redox capable material having metal oxides and/or metals, at least one conductive binder, and at least one solvent to form electrically conductive metal and/or metal oxide imbedded fiber or fibers by fiber spinning and said conductive polymeric binder having a molecular weight greater than 20,000 Daltons;
coating a substrate with said electrically conductive fiber or fibers to form an active layer/substrate complex having a conductivity greater than 0.05 S/cm; and
forming a battery or a capacitor from said active layer/substrate complex.

2. The method according to claim 1 , wherein said solvent is conductive having a minimum conductivity of about 100 S/cm.

3. The method according to claim 1 , wherein said solvent(s) is selected from the group consisting of chloroform, dimethyl formamide, chlorobenzene, dichlorobenzene, and any combination thereof.

4. The method according to claim 1 , wherein said binder(s) is selected from the group consisting poly 3-hexylthiophene, Poly(2-methoxyl-5-(2-ethylhexoxy)1,4-phenylene vinylene, Poly(bis-2,5 (N-methyl, N-hexyl) 1,4-phenylene vinylene, Poly(ethylene dioxythiophene), Poly(propylene dioxythiophene), poly(pyrrole), substituted poly(pyrrole), and any other conjugated electroactive polymer.

5. The method according to claim 1 , wherein said method further comprising embedding said fibers in an active layer of photosensitive conformable material that is optically transparent.

6. The method according to claim 1 , wherein said nano sized redox capable materials are selected from the group consisting viologens, substituted viologens, and electron-poor conjugated materials, fullerenes, and any other material capable of electrochemical reduction.

7. The method according to claim 1 , wherein said substrate(s) is selected from the group consisting of indium tin oxide, thin metal films, thin metal films on glass, silicon wafer, and any combination thereof.

8. The method according to claim 1 , wherein said active layer is used as an anode in an electrochemical battery.

9. The method according to claim 1 , wherein said active layer is used as a cathode in an electrochemical battery.

10. The method according to claim 1 , wherein said active layer is used as a cathode in a supercapacitor.

11. The method according to claim 1 , wherein said active layer is used as an anode in a supercapacitor.

12. The method according to claim 5 , wherein said conformable material(s) is selected from the group consisting of epoxies, polyimides, and other polymer materials that is photopatternable.

13. The active layer/substrate complexes produced by the methods of claim 1 .

Assignees

• Us Navy

Inventors

• Lai William W
• Baca Alfred J
• Stenger-Smith John D
• Meylemans Heather

Classifications

• Y02E60/13

  Energy storage using capacitors · CPC title

• H01M4/48

  of inorganic oxides or hydroxides · CPC title

• H01M4/70

  characterised by shape or form · CPC title

• H01G11/60

  characterised by the solvent · CPC title

• H01G11/28

  arranged or disposed on a current collector; Layers or phases between electrodes and current collectors, e.g. adhesives · CPC title