Catalytic composition for the electrochemical reduction of carbon dioxide

Patent metadata

Field	Value
Publication number	US-9662635-B2
Application number	US-201414539337-A
Country	US
Kind code	B2
Filing date	Nov 12, 2014
Priority date	Dec 26, 2012
Publication date	May 30, 2017
Grant date	May 30, 2017

Abstract

The catalytic composition for the electrochemical reduction of carbon dioxide is a metal oxide supported by multi-walled carbon nanotubes. The metal oxide may be nickel oxide (NiO) or tin dioxide (SnO 2 ). The metal oxides form 20 wt % of the catalyst. In order to make the catalysts, a metal oxide precursor is first dissolved in deionized water to form a metal oxide precursor solution. The metal oxide precursor solution is then sonicated and the solution is impregnated in a support material composed of multi-walled carbon nanotubes to form a slurry. The slurry is then sonicated to form a homogeneous solid solution. Solids are removed from the homogeneous solid solution and dried in an oven for about 24 hours at a temperature of about 110° C. Drying is then followed by calcination in a tubular furnace under an argon atmosphere for about three hours at a temperature of 450° C.

First claim

We claim:

1. A method of making a catalytic composition for the electrochemical reduction of carbon dioxide, comprising the steps of:
dissolving nickel nitrate hexahydrate, Ni(NO 3 ) 2 .6H 2 O, in deionized water to form a nickel precursor solution;
sonicating the nickel precursor solution;
impregnating the sonicated nickel precursor solution in a support material comprising multi-walled carbon nanotubes to form a slurry;
sonicating the slurry to form a homogenous solid solution;
removing solids from the homogenous solid solution;
drying the solids; and
calcining the dried solids in an argon atmosphere to form the catalytic composition.

2. The method of making a catalytic composition for the electrochemical reduction of carbon dioxide as recited in claim 1 , wherein the step of sonicating the slurry comprises sonicating the slurry for about two hours.

3. The method of making a catalytic composition for the electrochemical reduction of carbon dioxide as recited in claim 1 , wherein the step of drying the solids comprises drying the solids at a temperature of about 110° C. for a period of about 24 hours.

4. The method of making a catalytic composition for the electrochemical reduction of carbon dioxide as recited in claim 1 , wherein the step of calcining the dried solids comprises calcining the dried solids for about three hours at a temperature of about 450° C.

Assignees

• Univ King Fahd Pet & Minerals
• King Abdulaziz City Sci & Tech

Inventors

• Rahman Saleem Ur
• Ahmed Shakeel
• Hossain Mohammad Mozahar
• Bashir Shahid Muhammad

Classifications

• B01J23/14 Primary

  of germanium, tin or lead · CPC title

• B01J37/08

  Heat treatment {(B01J37/0009, B01J37/0018 take precedence)} · CPC title

• C25B11/0452

  Chemistry & Metallurgy · mapped topic

• B01J37/341

  making use of electric or magnetic fields, wave energy or particle radiation (use of flames, plasma or lasers B01J37/349) · CPC title

• B01J37/0201

  Impregnation · CPC title