Resin composition

Patent metadata

Field	Value
Publication number	US-9660271-B2
Application number	US-201314391471-A
Country	US
Kind code	B2
Filing date	Mar 29, 2013
Priority date	Apr 9, 2012
Publication date	May 23, 2017
Grant date	May 23, 2017

Abstract

The present invention provides a resin composition for an electrically conductive resin film which is excellent in electric conductivity, tensile elongation, durability to bending and flexibility and is suitable as electrodes or protective coatings on the electrodes in redox flow batteries. A resin composition includes (A) 100 parts by mass of a thermoplastic resin, (B) 1 to 60 parts by mass of carbon nanotubes and (C) 1 to 100 parts by mass of at least one selected from the group consisting of acetylene black and graphite.

First claim

The invention claimed is:

1. A resin composition consisting essentially of:
(A) 100 parts by mass of a thermoplastic resin,
(B) 1 to 60 parts by mass of carbon nanotubes, and
(C) 1 to 100 parts by mass of acetylene black,
wherein an amount of graphite in the resin composition comprises 0 parts by mass of the total amount of the resin composition.

2. The resin composition according to claim 1 , wherein component (A) is at least one selected from the group consisting of polyethylenes and chlorinated polyethylenes.

3. The resin composition according to claim 1 , wherein the composition is to be used for an electrode of a redox flow battery.

4. An electrically conductive resin film made of the resin composition according to claim 1 .

5. The electrically conductive resin film according to claim 4 , wherein the film has a volume resistivity, ρ, measured according to JIS K 7194, of 10 Ω·cm or less and the volume resistivity, ρ, meets the following equation (1):
Log ρ<=0.02 E− 1.4  (1)

wherein E is a tensile elongation in % of the film which is measured according to JIS K 7127.

6. The resin composition according to claim 1 , wherein the amount of component (B) is more than 10 parts by mass and at most 60 parts by mass relative to 100 parts by mass of component (A).

7. The resin composition according to claim 1 , wherein the amount of component (B) is 20 to 60 parts by mass relative to 100 parts by mass of component (A).

8. A resin composition consisting essentially of:
(A) 100 parts by mass of a thermoplastic resin,
(B) 1 to 60 parts by mass of carbon nanotubes,
(C) 1 to 100 parts by mass of acetylene black, and
(D) 1 to 60 parts by mass of carbon fiber,
wherein an amount of graphite in the resin composition comprises 0 parts by mass of the total amount of the resin composition.

Assignees

• Riken Technos Corp

Inventors

• Takahashi Tomohiro
• Sugimoto Hidemasa

Classifications

• Y02E60/50

  Fuel cells · CPC title

• C08L23/02

  not modified by chemical after-treatment · CPC title

• H01M8/188

  by recharging of redox couples containing fluids; Redox flow type batteries · CPC title

• C08K7/24

  inorganic · CPC title

• H01M8/0226

  in the form of mixtures · CPC title