Thermoelectric conversion material and producing method thereof, and thermoelectric conversion element using the same

Patent metadata

Field	Value
Publication number	US-9660165-B2
Application number	US-201414470564-A
Country	US
Kind code	B2
Filing date	Aug 27, 2014
Priority date	Aug 29, 2008
Publication date	May 23, 2017
Grant date	May 23, 2017

Abstract

Thermoelectric conversion materials, expressed by the following formula: Bi 1-x M x Cu 1-w O a-y Q1 y Te b-z Q2 z . Here, M is at least one element selected from the group consisting of Ba, Sr, Ca, Mg, Cs, K, Na, Cd, Hg, Sn, Pb, Mn, Ga, In, Tl, As and Sb; Q1 and Q2 are at least one element selected from the group consisting of S, Se, As and Sb; x, y, z, w, a, and b are 0≦x<1, 0<w<1, 0.2<a<4, 0≦y<4, 0.2<b<4, 0≦z<4 and x+y+z>0. These thermoelectric conversion materials may be used for thermoelectric conversion elements, where they may replace thermoelectric conversion materials in common use, or be used along with thermoelectric conversion materials in common use.

First claim

The invention claimed is:

1. Thermoelectric conversion materials, expressed by the following formula 1:
Bi 1-x M x Cu 1-w O a-y Q1 y Te b-z Q2 z   Formula 1

where M is at least one element selected from the group consisting of Ba, Sr, Ca, Mg, Cs, K, Na, Cd, Hg, Sn, Pb, Mn, Ga, In, Tl, As and Sb; Q1 and Q2 are at least one element selected from the group consisting of S, Se, As and Sb; x, y, z, w, a, and b are 0≦x<1, 0<w<1, 0.2<a<4, 0≦y<4, 0.2<b<4, 0≦z<4, b>z and x+y+z>0.

2. The thermoelectric conversion materials according to claim 1 ,
wherein x, y and z of the formula 1 are respectively 0≦x≦1/2, 0≦y≦a/2 and 0≦z≦b/2.

3. The thermoelectric conversion materials according to claim 1 ,
wherein a, y, b and z of the formula 1 are respectively a=1, 0≦y<1, b=1 and 0≦z<1.

4. The thermoelectric conversion materials according to claim 3 ,
wherein x, w, a, y, b and z of the formula 1 are respectively 0≦x<0.15, 0≦w<0.2, a=1, 0≦y<0.2, b=1 and 0≦z<0.5.

5. The thermoelectric conversion materials according to claim 3 ,
wherein M of the formula 1 is any one selected from the group consisting of Sr, Cd, Pb and Tl.

6. The thermoelectric conversion materials according to claim 3 ,
wherein Q1 and Q2 of the formula 1 are respectively Se or Sb.

7. The thermoelectric conversion materials according to claim 3 ,
wherein x, w, a, y, b and z of the formula 1 are respectively 0≦x<0.15, 0<w≦0.2, a=1, 0≦y<0.2, b=1 and 0≦z<0.5; M is any one selected from the group consisting of Sr, Cd, Pb and Tl; Q1 and Q2 are respectively Se or Sb.

8. The thermoelectric conversion materials according to claim 7 ,
wherein x, a, y, b and z of the formula 1 are respectively 0<x<0.15, a=1, y=0, b=1 and z=0.

9. The thermoelectric conversion materials according to claim 7 ,
wherein x, y and z of the formula 1 are respectively x=0, a=1, y=0, b=1 and 0<z≦0.5.

10. A method for producing thermoelectric conversion materials,
wherein Bi 2 O 3 , Bi, Cu, Te, and at least one selected from the group consisting of Ba, Sr, Ca, Mg, Cs, K, Na, Cd, Hg, Sn, Pb, Mn, Ga, In, Tl, As and Sb, or their oxides, are mixed and then sintered to produce the thermoelectric conversion materials expressed by the formula 1 in the claim 1 .

11. The method for producing thermoelectric conversion materials according to claim 10 ,
wherein the sintering process is executed at a temperature of 400 to 570° C.

12. A method for producing thermoelectric conversion materials,
wherein Bi 2 O 3 , Bi, Cu, and Te are mixed with at least one selected from the group consisting of S, Se, As and Sb, or their oxides, and then at least one selected from the group consisting of Ba, Sr, Ca, Mg, Cs, K, Na, Cd, Hg, Sn, Pb, Mn, Ga, In, Tl, As and Sb, or their oxides, are selectively further mixed thereto and then sintered to produce the thermoelectric conversion materials expressed by the formula 1 in the claim 1 .

13. The method for producing thermoelectric conversion materials according to claim 12 ,
wherein the sintering process is executed at a temperature of 400 to 570° C.

14. A thermoelectric conversion element, which includes the thermoelectric conversion materials defined in claim 1 .

Assignees

• Lg Chemical Ltd

Inventors

• Park Cheol-Hee
• Sohn Se-Hui
• Hong Seung-Tae
• Kwon Won-Jong
• Kim Tae-Hoon

Classifications

• H01B1/08

  oxides · CPC title

• Y02E10/50

  Photovoltaic [PV] energy · CPC title

• H01L35/16

  Electricity · mapped topic

• H01L31/0725

  Electricity · mapped topic

• H01L31/0272

  Electricity · mapped topic