Polyester film, method for producing the same, back sheet for solar cell, and solar cell module

Patent metadata

Field	Value
Publication number	US-9660119-B2
Application number	US-201414169616-A
Country	US
Kind code	B2
Filing date	Jan 31, 2014
Priority date	Aug 25, 2011
Publication date	May 23, 2017
Grant date	May 23, 2017

Abstract

A polyester film has excellent resistance to hydrolysis, excellent heat resistance in high temperatures and low humidity, and mechanical strength. The polyester film satisfies a stress heat resistant coefficient f(125)≧3 and a wet thermo retention (=100×S(120)/S(0)) of 30% or more. f(125) is a value obtained by substituting t=125° C. in an approximation represented by f(t); t represents a temperature (° C.) at thermo processing; f(t) represents a stress heat resistant coefficient f at the thermo temperature t and represents an approximation to a straight line obtained by linear approximation by a least squares method of values plotted from a relationship between the thermo temperature t and a logarithm (log T(t)) of time T at which a rupture stress is 50% when t is 150° C., 160° C., 170° C., or 180° C.; T(t) is a time (hr) at which the maximum stress in a tensile test after thermo processing at t° C. and 0% RH is 50% of the maximum stress in a tensile test before thermo processing; S(120) is breaking elongation (%) after aging for 100 hours at 120° C. and 100% RH, and S(0) represents a breaking elongation (%) before aging.

First claim

What is claimed is:

1. A polyester film, having a stress heat resistant coefficient f(125) that satisfies the following Equation (1) and a wet thermo retention represented by the following Equation (2) of 30% or higher:
[ A ] stress heat resistant coefficient 5≧ f (125)≧3  Equation (1)

[ B ] wet thermo retention (%)=100× S (120)/ S (0)  Equation (2)

wherein, in Equation (1), f(125) is a value obtained by substituting t=125° C. in an approximation represented by f(t); t represents a temperature (° C.) at a time of heat treatment (thermo processing); f(t) represents a stress heat resistant coefficient f at a thermo temperature t and represents an approximation to a straight line obtained by linear approximation by a least squares method of values plotted from a relationship between the thermo temperature t and a logarithm (log T(t)) of time T at which a rupture stress is 50% when the thermo temperature t is 150° C., 160° C., 170° C., or 180° C.;
T(150) is a time (hr) at which the maximum stress in a tensile test after thermo processing at 150° C. and 0% RH is 50% of the maximum stress in a tensile test before thermo processing;
T(160) is a time (hr) at which the maximum stress in a tensile test after thermo processing at 160° C. and 0% RH is 50% of the maximum stress in a tensile test before thermo processing;
T(170) is a time (hr) at which the maximum stress in a tensile test after thermo processing at 170° C. and 0% RH is 50% of the maximum stress in a tensile test before thermo processing;
T(180) is a time (hr) at which the maximum stress in a tensile test after thermo processing at 180° C. and 0% RH is 50% of the maximum stress in a tensile test before thermo processing; and
S(120) represents a breaking elongation (%) after aging for 100 hours at 120° C. and 100% RH, and S(0) represents a breaking elongation (%) before aging at 120° C. and 100% RH.

2. The polyester film according to claim 1 , wherein the maximum stress in a tensile test after dry thermo processing for 48 hours at 150° C. and 0% RH is in a range of from 180 MPa to 230 MPa.

3. The polyester film according to claim 2 , wherein a yield stress in a tensile test after dry thermo processing for 100 hours at 180° C. and 0% RH is in a range of from 95 MPa to 120 MPa, and a half-value stress period, at which the maximum stress in the tensile test after dry thermo processing at 180° C. and 0% RH reaches 50% of the maximum stress in the tensile test before dry thermo processing, is 500 hours or more.

4. The polyester film according to claim 3 , wherein an intrinsic viscosity (IV) is in a range of from 0.65 dL/g to 0.9 dL/g, and a terminal carboxyl group content (AV) is 20 eq/ton or less.

5. The polyester film according to claim 1 , wherein a yield stress in a tensile test after dry thermo processing for 100 hours at 180° C. and 0% RH is in a range of from 95 MPa to 120 MPa.

6. The polyester film according to claim 1 , wherein a half-value stress period, at which the maximum stress in the tensile test after dry thermo processing at 180° C. and 0% RH reaches 50% of the maximum stress in the tensile test before dry thermo processing, is 500 hours or more.

7. The polyester film according to claim 1 , wherein the polyester film comprises a polyester having an intrinsic viscosity (IV) in a range of from 0.65 dL/g to 0.9 dL/g and a terminal carboxyl group content (AV) of 20 eq/ton or less.

8. A back sheet for a solar cell, comprising the polyester film according to claim 1 .

9. A solar cell module, comprising: a transparent front substrate through which sunlight enters; a cell structural portion comprising a solar cell element and a sealing material that seals the solar cell element, the cell structural portion being disposed on the front substrate; and the back sheet for a solar cell according to claim 8 , the back sheet being disposed at an opposite side from a side at which the front substrate is disposed with respect to the cell structural portion.

Assignees

• Fujifilm Corp

Inventors

• Hashimoto Kiyokazu
• Aritoshi Yohei

Classifications

• Y02E10/50

  Photovoltaic [PV] energy · CPC title

• C08J2367/02

  Polyesters derived from dicarboxylic acids and dihydroxy compounds; (C08J2367/06 takes precedence) · CPC title

• B32B27/36

  comprising polyesters · CPC title

• C08L67/03

  the dicarboxylic acids and dihydroxy compounds having the carboxyl- and the hydroxy groups directly linked to aromatic rings · CPC title

• B32B2367/00

  Polyesters, e.g. PET, i.e. polyethylene terephthalate · CPC title