Self-dispersing nanoparticles

Patent metadata

Field	Value
Publication number	US-9657209-B2
Application number	US-201214116599-A
Country	US
Kind code	B2
Filing date	May 4, 2012
Priority date	May 11, 2011
Publication date	May 23, 2017
Grant date	May 23, 2017

Abstract

The invention relates to a process for manufacturing nanoparticles that are self-dispersing in water. It also relates to the self-dispersing nanoparticles obtained by the process of the invention and also a process for manufacturing a heat-transfer fluid containing the nanoparticles according to the invention or obtained by the process of the invention. The process of the invention comprises the following steps: a) optionally, manufacture of an aqueous dispersion of nanoparticles chosen from the nanoparticles of alumina (Al 2 O 3 ), of zinc oxide (ZnO), of titanium oxide (TiO 2 ), of silica (SiO 2 ) and of beryllium oxide (BeO), b) addition to an aqueous dispersion of nanoparticles chosen from nanoparticles of alumina (Al 2 O 3 ), of zinc oxide (ZnO), of titanium oxide (TiO 2 ), of silica (SiO 2 ) and of beryllium oxide (BeO), of a water-soluble polymer chosen from polyvinyl alcohols, polyethylene glycols, polyvinylpyrrolidones, polyoxazolines, starches, and mixtures of two or more thereof, and c) thermal quenching of the dispersion obtained in step b), and d) lyophilization of the quenched dispersion obtained in step c). The invention finds an application in the field of coolants in particular.

First claim

The invention claimed is:

1. A process of manufacturing self-dispersing nanoparticles of a metal oxide, comprising:
a step of addition of a water-soluble polymer to a dispersion of nanoparticles;
a step of thermal quenching of the resulting dispersion in liquid nitrogen, wherein the step of thermal quenching comprises adding the resulting dispersion dropwise to the liquid nitrogen to form beads; and
a step of lyophilization of the quenched dispersion obtained, and

comprising, optionally, a step of manufacture of the dispersion of said nanoparticles, before the step of addition of the water-soluble polymer,
wherein the dispersion of nanoparticles is an aqueous dispersion of nanoparticles selected from the group consisting of nanoparticles of alumina (Al 2 O 3 ), of zinc oxide (ZnO), of titanium oxide (TiO 2 ), of silica (SiO 2 ) and of beryllium oxide (BeO), and
the water-soluble polymer is selected from the group consisting of polyvinyl alcohols, polyethylene glycols, polyvinylpyrrolidones, polyoxazolines, starches, and mixtures of two or more thereof.

2. The process of claim 1 wherein the water-soluble polymer is selected from the group consisting of polyvinyl alcohols, polyethylene glycols and polyvinylpyrrolidones.

3. The process of claim 1 wherein the water-soluble polymer is a polyvinyl alcohol having a weight-average molecular weight of between 31000 and 50000 g·mol −1 inclusive.

4. The process of claim 1 wherein the water-soluble polymer is poly(2-ethyloxazoline) with a weight-average molecular weight of 50000 g·mol −1 .

5. The process of claim 1 wherein the water-soluble polymer is a polyvinylpyrrolidone with a weight-average molecular weight of between 10000 and 40000 g·mol −1 inclusive.

6. The of claim 1 wherein the water-soluble polymer is a polyethylene glycol having a weight-average molecular weight of between 7000 and 35000 g·mol −1 inclusive.

7. The process of claim 1 wherein
the water-soluble polymer is a polyvinyl alcohol having a weight-average molecular weight of between 31000 and 50000 g·mol −1 inclusive,
the nanoparticles are nanoparticles of alumina or of zinc oxide, and
the nanoparticles/water-soluble polymer weight ratio is between 4.5 and 30 inclusive.

8. The process of claim 7 wherein the nanoparticles/water-soluble polymer weight ratio is between 6 and 7 inclusive.

9. The process of claim 1 further comprising a step of milling of the aggregates obtained after lyophilization of the quenched dispersion, when such aggregates are obtained after this step.

10. Self-dispersing nanoparticles obtained by the process as claimed in claim 1 , characterized
in that said self-dispersing nanoparticles are selected from the group consisting of self-dispersing nanoparticles of alumina, of zinc oxide, of titanium oxide, of silica oxide and of beryllium oxide,
in that said self-dispersing nanoparticles comprise a water-soluble polymer which is polyvinyl alcohol, and
in that said self-dispersing nanoparticles are instantaneously dispersible in water.

11. The self-dispersing nanoparticles of claim 10 wherein the polyvinyl alcohol has a weight-average molecular weight of between 31000 and 50000 g·mol −1 inclusive.

12. A process of manufacturing a dispersion of self-dispersing nanoparticles, comprising mixing self-dispersing nanoparticles obtained by the process as claimed in claim 1 , in water.

13. The process of claim 12 wherein the self-dispersing nanoparticles/water weight ratio is between 5/100 and 10/100 inclusive.

14. A heat-transfer fluid comprising water and self-dispersing nanoparticles obtained by the process as claimed in claim 1 .

15. The process of claim 1 wherein the step of thermal quenching is performed at a temperature below −180° C.

16. A process of manufacturing self-dispersing nanoparticles of a metal oxide, comprising:
a step of addition of a water-soluble polymer to a dispersion of nanoparticles;
a step of thermal quenching of the resulting dispersion at a temperature below −80° C.; and
a step of lyophilization of the quenched dispersion obtained, and

comprising, optionally, a step of manufacture of the dispersion of said nanoparticles, before the step of addition of the water-soluble polymer,
wherein the dispersion of nanoparticles is an aqueous dispersion of nanoparticles selected from the group consisting of nanoparticles of alumina (Al 2 O 3 ), of zinc oxide (ZnO), of titanium oxide (TiO 2 ), of silica (SiO 2 ) and of beryllium oxide (BeO), and
the water-soluble polymer is poly(2-ethyloxazoline) with a weight-average molecular weight of 50000 g·mol −1 .

17. The process of claim 16 wherein the nanoparticles are nanoparticles of alumina or of zinc oxide, and the nanoparticles/water-soluble polymer weight ratio is between 4.5 and 30 inclusive.

18. The process of claim 16 further comprising a step of milling of the aggregates obtained after lyophilization of the quenched dispersion, when such aggregates are obtained after this step.

Assignees

• Poncelet Olivier
• Borlet Renaud
• Getto Daniel
• Commissariat Energie Atomique

Inventors

• Poncelet Olivier
• Borlet Renaud
• Getto Daniel

Classifications

• C08K3/22

  of metals · CPC title

• C08G73/0233

  Polyamines derived from (poly)oxazolines, (poly)oxazines or having pendant acyl groups · CPC title

• C01F7/026

  Making or stabilising dispersions · CPC title

• C09C1/3676

  Treatment with macro-molecular organic compounds · CPC title

• C09K5/14

  Solid materials, e.g. powdery or granular · CPC title