Flame retardant thermoplastic polyurethane compositions

Patent metadata

Field	Value
Publication number	US-9657172-B2
Application number	US-201213983385-A
Country	US
Kind code	B2
Filing date	Feb 29, 2012
Priority date	Mar 1, 2011
Publication date	May 23, 2017
Grant date	May 23, 2017

Abstract

The present invention relates to flame retardant thermoplastic polyurethane (TPU) compositions that are prepared by compounding certain TPU's and with a polyphosphonate homopolymer or copolymer, and more specifically TPU compositions that pass ASTM E84 Class 1 and UL94 V0 ratings. The invention also relates to compositions that further include an inherently dissipative polymer to provide a TPU composition that has flame retardant properties, electrostatic discharge performance, good clarity and/or transparency, or any combination thereof.

First claim

We claim:

1. A composition comprising a blend of:
(i) 20% to 80% by weight of the composition of a thermoplastic polyurethane component; and
(ii) 15% to 40% by weight of the composition of a polyphosphonate polymer component, and
(iii) a salt-modified inherently dissipative polymer component, wherein the salt-modified inherently dissipative polymer component is selected from thermoplastic polyurethane polymers, polyolefin polyether copolymers, thermoplastic polyester elastomers, polyether block amide elastomer, or combinations thereof, and wherein the salt-modified inherently dissipative polymer component comprises about 0.10 to about 0.75 parts by weight of metal-containing salt based on 100 parts by weight of the salt-modified inherently dissipative polymer component.

2. The composition of claim 1 further comprising a secondary flame retardant additive.

3. The composition of claim 1 wherein the composition:
meets a Class II or better rating as measured according to ASTM E84;
(ii) meets a V1 or better rating as measured according to UL94;
(iii) has a haze of lower than 50% at 40 mil thickness as measured according to ASTM D-1003;
(iv) has a surface resistivity of between 1E6 and 1E12 ohms/sq as measured at 50% relative humidity according to ASTM D-257; or
(v) any combination thereof.

4. The composition of claim 1 wherein component (i), the thermoplastic polyurethane component, has a hardness of no more than 70D, as measured by ASTM D2240.

5. The composition of claim 1 wherein component (i), the thermoplastic polyurethane component, comprises a thermoplastic polyurethane made by reacting (a) at least one polyol intermediate with (b) at least one diisocyanate and (c) at least one chain extender;
wherein the thermoplastic polyurethane is present at 20-80 weight percent of the overall composition.

6. The composition of claim 1 wherein component (ii), the polyphosphonate component, comprises a homopolymer of a phosphonate, a copolymer of two or more phosphonates, or a combination thereof.

7. The composition of claim 1 wherein component (iii), the salt-modified inherently dissipative polymer component, comprises:
(a) a chain extended low molecular weight polyoxirane;
(b) a chain extended low molecular weight polyester polyol derived from at least one dialkylene glycol and at least one dicarboxylic acid, ester, or anhydride; or
(c) a combination thereof.

8. The composition of claim 7 where the chain extended low molecular weight polyoxirane is a chain extended polyether oligomer, wherein said polyether oligomer comprises a homopolymer or copolymer of polyethylene glycol, polypropylene glycol, or combination thereof.

9. The composition of claim 8 wherein the homopolymer or copolymer of polyethylene glycol comprises a homopolymer of ethylene glycol having a weight average molecular weight of about 500 to about 2500 or a copolymer of ethylene glycol and at least one other glycol where the copolymer has a weight average molecular weight of about 500 to about 5000.

10. The composition of claim 1 wherein the composition further comprises one or more additional performances additives, said additional performance additives comprising waxes, process aids, antioxidants, heat stabilizers, UV stabilizers, hydrolysis stabilizers, colorants, flame retardants, ionic additives, or any combination thereof.

11. A method of producing a composition comprising a blend of:
(i) 20% to 80% by weight of the composition of a thermoplastic polyurethane component; and
(ii) 15% to 40% by weight of the composition of a polyphosphonate polymer component and,
(iii) a salt-modified inherently dissipative polymer component, wherein the salt-modified inherently dissipative polymer component is selected from thermoplastic polyurethane polymers, polyolefin polyether copolymers, thermoplastic polyester elastomers, polyether block amide elastomer, or combinations thereof, and wherein the salt-modified inherently dissipative polymer component comprises about 0.10 to about 0.75 parts by weight of metal-containing salt based on 100 parts by weight of the salt-modified inherently dissipative polymer component;
wherein said method comprises the steps of:
(I) mixing components (i), (ii), and (iii) in an internal mixing device.

12. A shaped polymeric article comprising the flame retardant thermoplastic polyurethane composition of claim 1 .

13. The shaped polymeric article of claim 12 wherein said article is prepared by traditional polymer processing methods comprising: injection molding, sheet extrusion, profile extrusion, blown film extrusion, melt lamination, compression molding, or any combination thereof.

14. The shaped polymeric article of claim 12 , wherein said article comprises: packaging materials for electronic components or parts; construction components for buildings, clean rooms, or data centers; parts or tools used in clean rooms; fabric coatings, hoses and tubing; wires and cables; or combinations thereof.

15. A composition comprising a blend of:
(i) 20% to 80% by weight of the composition of a thermoplastic polyurethane component; and
(ii) 15% to 40% by weight of the composition of a polyphosphonate polymer component, wherein the polyphosphonate polymer component is substantially free of phosphine oxide-based materials; and
(iii) a salt-modified inherently dissipative polymer component, wherein the salt-modified inherently dissipative polymer component is selected from thermoplastic polyurethane polymers, polyolefin polyether copolymers, thermoplastic polyester elastomers, polyether block amide elastomer, or combinations thereof, and wherein the salt-modified inherently dissipative polymer component comprises about 0.10 to about 0.75 parts by weight of metal-containing salt based on 100 parts by weight of the salt-modified inherently dissipative polymer component;
wherein the blend is substantially free of halogen atoms, halogen containing salts, and/or other halogen containing compounds.

16. The composition of claim 15 wherein the composition further comprises a secondary flame retardant additive selected from brominated diols, brominated mono-alcohols, brominated ethers, brominated esters, brominated phosphates, and combinations thereof.

17. The composition of claim 1 , wherein the salt-modified inherently dissipative polymer component comprises a salt selected from sodium salt of an amidoalkanesulfonic acid; a lithium salt of styrene sulfonic acid; a copolymer of a lithium salt of an amidoalkanesulfonic acid and acrylic acid; a terpolymer of a lithium salt of an amidoalkanesulfonic acid, a lithium salt of styrene sulfonic acid, and acrylic acid; a copolymer of a sodium salt of an amidoalkanesulfonic acid and acrylic acid; a terpolymer of a sodium salt of an amidoalkanesulfonic acid, a sodium salt of styrene sulfonic acid, and acrylic acid or combinations thereof.

Assignees

• Cao Feina
• Nestlerode Greg S
• Lu Qiwei
• Lubrizol Advanced Mat Inc

Inventors

• Cao Feina
• Nestlerode Greg S
• Lu Qiwei

Classifications

• C08G18/48

  Polyethers · CPC title

• C08L85/02

  containing phosphorus · CPC title

• C08G18/42

  Polycondensates having carboxylic or carbonic ester groups in the main chain · CPC title

• C08K5/5317

  Phosphonic compounds, e.g. R—P(:O)(OR')2 · CPC title

• C08L75/04 Primary

  Polyurethanes · CPC title