Polymeric compositions and processes for molding articles

Patent metadata

Field	Value
Publication number	US-9657166-B2
Application number	US-201514926604-A
Country	US
Kind code	B2
Filing date	Oct 29, 2015
Priority date	Oct 22, 2007
Publication date	May 23, 2017
Grant date	May 23, 2017

Abstract

The present invention is directed to a polymeric article comprising a blend of (a) a first polymeric component; (b) a second polymeric component the second polymeric component including an α-olefin multilock interpolymer present in the amount of about 20 percent or less by weight of the second polymeric component; and (c) at least one reinforcement material; wherein the concentration of the second polymeric component is greater than about 20 wt. % based on the total concentration of the first polymeric component and the second polymeric component. The polymeric articles desirably have one or more of the following characteristics: a soft touch feel, a low gloss appearance, or a high surface durability.

First claim

What is claimed is:

1. A soft-touch feel polymeric composition comprising a blend of:
i. at least about 20 weight percent and less than 55 weight percent of a first polymeric component including a relatively hard thermoplastic, wherein the first polymeric component is an isotactic polypropylene homopolymer, a random polypropylene copolymer, an impact polypropylene, a high density polyethylene, a low density polyethylene, a linear low density polyethylene, a medium density polyethylene, or any combination thereof, having a crystaiiinity of greater than about 31 weight percent as measured according to ASTM D3418.03;
ii. greater than 25 weight percent and less than about 60 weight percent of a second polymeric component including a relatively soft thermoplastic as compared with the first polymeric component, wherein the relatively soft thermoplastic is a lower-α-olefin/α-olefin interpolymer (“LAO/α-olefin interpolymer”) which is a multiblock copolymer having one or more hard blocks and one or more soft blocks, wherein the one or more hard blocks are A Blocks and the one or more soft blocks are B blocks, the multiblock copolymer having the structure of (AB) n , (AB) n A, or B(AB) n , where n is greater than 1; the LAO/α-olefin interpolymer has a density of 0.860 to 0.900 g/cm 3 ; the LAO/α-olefin interpolymer includes a first monomer that is ethylene or propylene, and a second monomer that is butene or octene, wherein the concentration of the second monomer is greater than 6 mole percent and less than 30 mole percent, based on the total moles of monomer in the LAO/α-olefin interpolymer; the total amount of the first and second monomer is greater than about 95 weight percent, based on the total weight of the LAO/α-olefin interpolymer; the concentration of the B blocks is about 50 to about 90 weight percent, based on the total weight of the LAO/α-olefin interpolymer; the concentration of the first monomer in the A blocks is greater than about 95 weight percent, and the concentration of the second monomer in the B blocks is greater than about 8 weight percent;
iii. 10 to 40 weight percent glass fibers, based on the total weight of the polymeric composition, wherein the glass fibers have an average length from about 0.5 to about 5 mm in the composition, and a diameter from about 3 to about 100 microns; and
iv. less than 5 weight percent of a grafted polypropylene; and
wherein the LAO/α-olefin interpolymer has a melt index greater than about 0.2 and less than about 20, as measured according to ASTM D1238 Condition 190° C./2.16 kg when the first monomer is ethylene and ASTM D1238 Condition 230° C./2.16 kg when the first monomer is propylene; and
the polymeric composition is characterized by a melt flow rate of at least about 5 g/10 min as measured according to ASTM D-1238 Condition 230° C./2.16 kg.

2. A polymeric composition of claim 1 wherein the LAO/α-olefin interpolymer has at least three of the hard blocks and at least three of the soft blocks.

3. A polymeric composition of claim 2 wherein the LAO/α-olefin interpolymer is an ethylene/α-olefin interpolymer.

4. A polymeric composition of claim 1 , wherein theLAO/α-olefin interpolymer is an ethylene/α-olefin interpolymer.

5. A polymeric composition of claim 1 , wherein the LAO/α-olefin interpolymer is a propylene/α-olefin interpolymer.

6. A polymeric composition of claims 4 wherein the LAO/α-olefin interpolymer is a copolymer of ethylene and 1-octene, wherein the sum of the concentrations of the ethylene and 1-octene monomers is greater than 95 wt. % based on the total weight of the LAO/α-olefin interpolymer.

7. A polymeric composition of claim 6 , wherein the LAO/α-olefin interpolymer is characterized by: a density from about 0.850 to about 0.895 g/cm 3 , a Shore A hardness from about 15 to about 95; and a melt index ratio, I 10 /I 2 , from about 5 to about 35; and a melt index, I 2 , from about 0.5 to about 20 g/10 min.

8. A polymeric composition of claim 7 wherein the LAO/α-olefin interpolymer is characterized by a polydispersity index, Mw/Mn, defined by the ratio of the weight average molecular weight, Mw, and the number average molecular weight, Mn, from about 1.9 to about 7.

9. A polymeric composition of claim 7 wherein the LAo/α-olefin interpolymer is characterized by a concentration of soft block(s) from about 40 to about 95 wt. % based on the total weight of the LAO/α-olefin interpolymer and the LAO/α-olefin interpolymer is characterized by a weight average block index, ABI, from about 0.15 to about 0.8.

10. A polymeric composition of claim 9 wherein the glass fiber is present at a concentration from about 5 wt. % to about 40 wt. % based on the total weight of the polymeric composition.

11. A polymeric composition of claims 10 wherein the first polymer component consists essentially of the isotactic polypropylene homopolymer.

12. A process for manufacturing a molded article wherein the molded article contains a portion having a polymeric composition of claim 1 , and includes a step of removing the article from a mold.

13. A process for compounding a polymeric composition of claim 1 , wherein the process comprises the steps of:
i) melt-compounding the first polymeric component, the second polymeric component, and the glass fibers to form a melt blended polymeric composition;
ii) pelletizing the melt blended polymeric composition to form pellets or granules capable of feeding in a molding machine; and
iii) placing at least 5 kg of the pellets or granules in a container.

14. The polymeric composition of claim 1 , wherein
the first polymeric component is the isotactic polypropylene homopolymer, the random polypropylene copolymer, the impact polypropylene, or any combination thereof;
the first polymeric component has a melt flow rate from 10 to 100 g/10 min as measured according to ISO 1133; and
the first monomer of the LAO/α-olefin interpolymer is ethylene.

15. The polymeric composition of claim 14 , wherein
the first polymeric component has a melt flow rate from 20 to 100 g/10 min as measured according to ISO 1133; and
the second polymeric component is an ethylene/octene interpolymer.

16. The polymeric composition of claim 15 , wherein the concentration of the glass fibers in the composition is at least 20 weight percent, the concentration of the propylene coupling agent in the composition is at least 0.1 weight percent, and the polymeric composition has a melt flow rate of at least about 5 g/10 min as measured according to ASTM D-1238 at 230° C./2.16 kg.

17. An injection molded article comprising:
an insert; and
an over-molded layer;
wherein the overmolded layer includes the polymeric composition of claim 1 ;
wherein the first polymeric component is a polypropylene selected from the group consisting of a polypropylene homopolymer, an impact polypropylene, a random polypropylene copolymer of ethylene and propylene having less than about 5 wt. % ethylene, and any combination thereof, wherein the polypropylene has a melting temperature greater than about 125° C. and is characterized by a melt flow rate from 10 to 100 g/10 min as measured according to ISO 1133 at 230° C./2.16 kg.

18. The molded article of claim 17 , wherein
the first polymeric component has a melt flow rate from 20 to 100 g/10 min as measured according to ISO 1133; and
the second polymeric component is an ethylene/octene interpolymer.

19. The molded article of claim 18 , wherein the concentration of the glass fibers in the composition is at least 5 weight percent, the concentration of the propylene co

Assignees

• Trinseo Europe Gmbh

Inventors

• Van Riel Norwin
• Lakeman Pascal E R E J

Classifications

• C08L2205/02

  containing two or more polymers of the same C08L -group · CPC title

• C08L51/06

  grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond · CPC title

• C08L23/142 Primary

  at least partially crystalline copolymers of propene with other olefins · CPC title

• C08L23/10

  Homopolymers or copolymers of propene · CPC title

• C08L23/12

  Polypropene · CPC title