Emulsion coagulant and tire puncture repair kit using same

Patent metadata

Field	Value
Publication number	US-9657164-B2
Application number	US-201414778934-A
Country	US
Kind code	B2
Filing date	Mar 20, 2014
Priority date	Mar 22, 2013
Publication date	May 23, 2017
Grant date	May 23, 2017

Abstract

An object of the present invention is to provide an emulsion coagulant capable of quickly coagulating an emulsion in an extremely low temperature environment. The present invention is an emulsion coagulant containing an amphoteric acrylic polymer, the amphoteric acrylic polymer having an amide group and a sulfonic acid group and having a weight average molecular weight of 30,000 or lower, and the emulsion coagulant being used to coagulate an emulsion. The present invention is also a tire puncture repair kit that uses the emulsion coagulant.

First claim

What is claimed is:

1. A composition comprising an emulsion coagulant including: an amphoteric acrylic polymer having an amide group and a sulfonic acid group and having a weight average molecular weight of 13,400 or lower,
wherein a molar ratio of the amide group to the sulfonic acid group (amide group:sulfonic acid group) is [0.05 or greater but ⅓ or less]:[0.95 or less but ⅔ or greater],
wherein the amphoteric acrylic polymer is produced by using at least an amide group-containing polymerizable monomer and a sulfonic acid group-containing polymerizable monomer;
the amide group-containing polymerizable monomer is acrylamide; and

the sulfonic acid group-containing polymerizable monomer is at least one of acrylamide t-butyl sulfonic acid and methallylsulfonic acid, and
wherein the amphoteric acrylic polymer further has a carboxylic acid group.

2. The composition according to claim 1 , wherein a molar ratio of the amide group to the sulfonic acid group (amide group:sulfonic acid group) is [0.05 or greater but less than 0.3]:[0.95 or less but greater than 0.7].

3. The composition according to claim 1 , wherein a molar ratio of the amide group to a total of the sulfonic acid group and the carboxylic acid group [amide group:(sulfonic acid group+carboxylic acid group)] is [0.05 or greater but less than 0.3]:[0.95 or less but greater than 0.7].

4. The composition according to claim 1 , wherein a molar ratio of the carboxylic acid group to the sulfonic acid group (carboxylic acid group:sulfonic acid group) is from 0.1:0.9 to 0.9:0.1.

5. The composition according to claim 1 , wherein the amphoteric acrylic polymer is produced by using at least an amide group-containing polymerizable monomer, a sulfonic acid group-containing polymerizable monomer, and a carboxylic acid group-containing polymerizable monomer; and
the carboxylic acid group-containing polymerizable monomer is methacrylic acid.

6. The composition according to claim 1 , further comprising water; wherein, an amount of the water is from 20 to 80% by mass in the emulsion coagulant; and an amount of the amphoteric acrylic polymer is from 10 to 70% by mass in the emulsion coagulant.

7. The composition according to claim 1 , wherein the emulsion is a tire puncture repair agent, and the tire puncture repair agent contains natural rubber latex and/or a synthetic resin emulsion, and an anti-freezing agent.

8. The composition according to claim 7 , wherein the anti-freezing agent is at least one type selected from the group consisting of ethylene glycol, propylene glycol, diethylene glycol, and glycerin.

9. A tire puncture repair kit comprising the composition described in claim 1 and a tire puncture repair agent.

10. The tire puncture repair kit according to claim 9 , wherein an amount of the emulsion coagulant is from 8 to 80 parts by mass per 100 parts by mass of the tire puncture repair agent.

Assignees

• Yokohama Rubber Co Ltd

Inventors

• Okamatsu Takahiro
• Naruse Masahiro
• Takahara Hideyuki

Classifications

• C08F228/02

  by a bond to sulfur · CPC title

• C08F220/58

  containing oxygen in addition to the carbonamido oxygen {, e.g. N-methylolacrylamide, N-(meth)acryloylmorpholine} · CPC title

• C08F220/56 Primary

  Acrylamide; Methacrylamide · CPC title

• C08F220/06

  Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof · CPC title

• B29C73/163

  Sealing compositions or agents, e.g. combined with propellant agents · CPC title