Preparation method of a super absorbent polymer

Patent metadata

Field	Value
Publication number	US-9656296-B2
Application number	US-201214370151-A
Country	US
Kind code	B2
Filing date	Apr 13, 2012
Priority date	Apr 13, 2012
Publication date	May 23, 2017
Grant date	May 23, 2017

Abstract

The present invention relates to a method of preparing a super absorbent polymer (SAP), and more specifically to a method of preparing a SAP including the steps of spraying the monomer composition on a substrate having a hydrophobic surface of a certain tan angle and carrying out a UV polymerization on a polymerization reactor having a slightly hydrophilic surface. The present invention can improve the conversion rate of polymerization because the shape of the monomer solution is changed from prior sheet form to droplet form so that UV rays reach the deeper layer of the droplets, can minimize or simplify the recycling process because it is easy to control the particles of the prepared polymer, and can provides the SAP of high caliber by narrowing the particle diameter distribution and improving the uniformity.

First claim

The invention claimed is:

1. A method of preparing a super absorbent polymer (SAP), including the steps of:
preparing a monomer composition including a water-soluble ethylenic unsaturated monomer and a polymerization initiator;
preparing a monomer mixture of fine droplets having a sprayed droplet size of 300 μm or less by spraying said monomer composition onto a substrate having a hydrophobic surface, such that said fine droplets flow down from the hydrophobic surface of the substrate to an adjacent polymerization reactor;
preparing a fine hydrogel polymer by polymerizing said monomer mixture of fine droplets on the polymerization reactor by receiving said fine droplets from the hydrophobic surface of the substrate to a moving surface of the polymerization reactor, and irradiating said fine droplets with UV rays; and
drying said fine hydrogel polymer,
wherein the substrate having the hydrophobic surface is positioned such that a plane parallel to the hydrophobic surface of the substrate is inclined at an angle θ 1 having a value of 20° to 70° with respect to a plane including the moving surface of the polymerization reactor.

2. The method according to claim 1 , wherein the substrate having the hydrophobic surface is a substrate having a surface coated with polytetrafluoroethylene or a substrate coated with silicone.

3. The method according to claim 1 , wherein the moving surface of the polymerization reactor has a slightly hydrophilic surface and the contact angle to water of the slightly hydrophilic surface is 30° to less than 90°.

4. The method according to claim 1 , wherein the monomer composition is sprayed on the substrate having the hydrophobic surface with a spraying speed of 0.5 to 5 ms −1 .

5. The method according to claim 1 , wherein the monomer composition is sprayed so that the sprayed droplet size is 10 μm or more.

6. The method according to claim 1 , wherein the monomer composition is sprayed so that the sprayed droplet size is 10 to 150 μm.

7. The method according to claim 1 , wherein the monomer composition is sprayed so that the sprayed droplet size is 20 to 200 μm.

8. The method according to claim 1 , wherein the UV polymerization is carried out at a temperature of 25 to 99° C. for 10 secs to 5 mins by irradiating with UV rays.

9. The method according to claim 1 , wherein the monomer composition further includes a cross-linking agent.

10. The method according to claim 1 , wherein the water-soluble ethylenic unsaturated monomer is one or more compounds selected from the group consisting of:
anionic monomers of acrylic acid, methacrylic acid, maleic anhydride, fumaric acid, crotonic acid, itaconic acid, 2-acryloyl ethane sulfonic acid, 2-methacryloyl ethane sulfonic acid, 2-(meth)acryloyl propane sulfonic acid, and 2-(meth)acrylamide-2-methyl propane sulfonic acid, and salts thereof;
nonionic hydrophilic monomers of (meth)acrylamide, N-substituted (meth)acrylate, 2-hydroxyethyl(meth)acrylate, 2-hydroxypropyl(meth)acrylate, methoxy polyethylene glycol(meth)acrylate, and polyethylene glycol (meth)acrylate; and
amino-containing unsaturated monomers of (N,N)-dimethylaminoethyl (meth)acrylate and (N,N)-dimethylaminopropyl (meth)acrylamide.

11. The method according to claim 1 , wherein a concentration of the water-soluble ethylenic unsaturated monomer is 20 to 60 weight %.

12. The method according to claim 1 , wherein the polymerization initiator is any one compound selected from the group consisting of an azo-based initiator, a peroxide-based initiator, a redox-based initiator, an organic halide initiator, acetophenone, benzoin, benzophenone, and benzyl.

13. The method according to claim 1 , further including a step of pulverizing the dried polymer by using any one pulverizing machine selected from the group consisting of a pin mill, a hammer mill, a screw mill, and a roll mill.

14. The method according to claim 1 , forming a powdery resin having a particle diameter of 150 to 850 μm.

15. The method according to claim 1 , wherein a moisture content of the dried polymer is 1 to 10 weight %.

Assignees

• Leem Gyu
• Kim Gi-Cheul
• Lee Sang-Gi
• Kim Kyu-Pal
• Won Tae-Young
• Han Chang-Sun
• Lg Chemical Ltd

Inventors

• Leem Gyu
• Kim Gi-Cheul
• Lee Sang-Gi
• Kim Kyu-Pal
• Won Tae-Young
• Han Chang-Sun

Classifications

• B05D1/02

  performed by spraying · CPC title

• C08F6/008

  Treatment of solid polymer wetted by water or organic solvents, e.g. coagulum, filter cakes · CPC title

• B01J2/26

  on endless conveyor belts · CPC title

• C08F2/01

  characterised by special features of the polymerisation apparatus used · CPC title

• C08F2/48

  by ultraviolet or visible light · CPC title