Method for producing aromatic hydrocarbons and aromatic hydrocarbon production plant

Patent metadata

Field	Value
Publication number	US-9656232-B2
Application number	US-201113637238-A
Country	US
Kind code	B2
Filing date	Mar 25, 2011
Priority date	Mar 26, 2010
Publication date	May 23, 2017
Grant date	May 23, 2017

Abstract

A method for producing aromatic hydrocarbons, the method including: (a) bringing a feedstock oil such as an LCO into contact with an aromatic production catalyst to obtain a reaction product containing aromatic hydrocarbons, (b) separating the reaction product into a tower top fraction and a tower bottom fraction using a distillation tower, (c) separating the tower top fraction into a crude aromatic fraction containing an LPG fraction, and an off-gas containing hydrogen, (d) separating the crude aromatic fraction containing an LPG fraction into an LPG fraction and a crude aromatic fraction, (e) separating the off-gas containing hydrogen into hydrogen and an off-gas, and (f) using the hydrogen obtained in step (e) to hydrotreat the crude aromatic fraction, thereby obtaining an aromatic fraction.

First claim

We claim:

1. A method for producing aromatic hydrocarbons, the method comprising:
(a) bringing one or more feedstock oils into contact with an aromatic production catalyst to conduct a dehydrogenation reaction to obtain a reaction product containing aromatic hydrocarbons and hydrogen under a pressure range of from 0.1 to 1.5 MPaG,
(b) separating the reaction product into a tower top fraction and a tower bottom fraction using a distillation tower, wherein the tower top fraction comprises BTX and the tower bottom fraction comprises a C 10 aromatics fraction,
(c) separating the tower top fraction into an LPG fraction-containing crude aromatic fraction, and an off-gas stream containing the hydrogen produced by the dehydrogenation reaction,
(d) separating the LPG fraction-containing crude aromatic fraction into an LPG fraction and a crude aromatic fraction,
(e) separating the off-gas stream into hydrogen and an off-gas, and
(f) using the hydrogen produced by the dehydrogenation reaction obtained in the step (e) to hydrotreat the crude aromatic fraction, thereby obtaining an aromatic fraction,
wherein the one or more feedstock oils is selected from the group consisting of light cycle oil obtained from a fluid catalytic cracking apparatus, hydrotreated light cycle oil, and naphtha and straight-run gas oil obtained from a crude oil distillation apparatus, and
wherein the aromatic production catalyst comprises a crystalline aluminosilicate containing gallium and phosphorous having an amount of the phosphorus within a range from 0.1 to 10.0% by mass relative to the total mass of the aromatic production catalyst.

2. The method for producing aromatic hydrocarbons according to claim 1 , wherein in the step (a), while the one or more feedstock oils is brought into contact with the aromatic production catalyst in a fluidized bed reactor, a heating fuel that is supplied from externally is combusted in presence of an oxygen-containing gas to heat the aromatic production catalyst extracted from the fluidized bed reactor.

3. The method for producing aromatic hydrocarbons according to claim 1 , the method further comprising:
(g) hydrotreating the tower bottom fraction using the hydrogen obtained in the step (e).

4. The method for producing aromatic hydrocarbons according to claim 2 , the method further comprising:
(g) hydrotreating the tower bottom fraction using the hydrogen obtained in the step (e).

Assignees

• Minami Hideki
• Sugi Yoshishige
• Fukui Atsushi
• Nagumo Atsuro
• Yasui Susumu
• Yanagawa Shinichiro
• Chiyoda Corp
• Jx Nippon Oil & Energy Corp

Inventors

• Minami Hideki
• Sugi Yoshishige
• Fukui Atsushi
• Nagumo Atsuro
• Yasui Susumu
• Yanagawa Shinichiro

Classifications

• B01J23/883

  and nickel · CPC title

• B01J2229/183

  in framework positions · CPC title

• C10G2300/1044

  Heavy gasoline or naphtha having a boiling range of about 100 - 180 °C · CPC title

• B01D3/143

  by two or more of a fractionation, separation or rectification step · CPC title

• B01J23/885

  and copper · CPC title