Pesticidal compositions and processes related thereto

Patent metadata

Field	Value
Publication number	US-9655365-B2
Application number	US-201414547188-A
Country	US
Kind code	B2
Filing date	Nov 19, 2014
Priority date	Oct 26, 2011
Publication date	May 23, 2017
Grant date	May 23, 2017

Abstract

This document discloses molecules having the following formula (“Formula One”):

and processes related thereto.

First claim

We claim:

1. A formulation comprising a carrier and a molecule according to

wherein
(a) A is

(b) R1 is H, F, Cl, Br, I, or substituted or unsubstituted C 1 -C 6 alkyl, wherein each said R1, which is substituted, has one or more substituents selected from F, Cl, Br, or I;
(c) R2 is H, F, Cl, Br, I, or substituted or unsubstituted C 1 -C 6 alkyl, wherein each said R2, which is substituted, has one or more substituents selected from F, Cl, Br, or I;
(d) R3 is H, F, Cl, Br, I, or substituted or unsubstituted C 1 -C 6 alkyl, wherein each said R3, which is substituted, has one or more substituents selected from F, Cl, Br, or I;
(e) R4 is H, F, Cl, Br, I, or substituted or unsubstituted C 1 -C 6 alkyl, wherein each said R4, which is substituted, has one or more substituents selected from F, Cl, Br, or I;
(f) R5 is H;
(g) R6 is R11;
(h) R7 is O or S;
(i) R8 is (substituted or unsubstituted C 1 -C 6 alkyl)-S(O) n -(substituted or unsubstituted C 1 -C 6 alkyl) wherein said substituents on said substituted alkyls are selected from F, Cl, Br, or I;
(j) R9 is unsubstituted C 1 -C 6 alkyl;
(k) n is 0, 1, or 2;
(l) X is CR n1 where R n1 is H, F, Cl, Br, I, CN, NO 2 , or substituted or unsubstituted C 1 -C 6 alkyl, wherein each said R n1 which is substituted, has one or more substituents selected from F, Cl, Br, or I;
(p) R11 is Q 1 (C≡C)R12, wherein Q 1 is an unsubstituted C 1 -C 6 alkyl; and
(q) R12 is R9.

2. A formulation according to claim 1 wherein said molecule has one of the following structures

3. A formulation according to claim 1 wherein said molecule said R1 is H.

4. A formulation according to claim 1 wherein said molecule said R2 is H.

5. A formulation according to claim 1 wherein said molecule said R3 is selected from H, or substituted or unsubstituted C 1 -C 6 alkyl.

6. A formulation according to claim 1 wherein said molecule said R3 is selected from H or CH 3 .

7. A formulation according to claim 1 wherein said molecule said R4 is selected from Cl, or unsubstituted C 1 -C 6 alkyl.

8. A formulation according to claim 1 wherein said molecule R4 is Cl or CH 3 .

9. A formulation according to claim 1 wherein said molecule said R4 is Cl.

10. A formulation according to claim 1 wherein said molecule said R11 is CH 2 C≡CH and R8 is (unsubstituted C 1 -C 6 alkyl)-S(O) n -(unsubstituted C 1 -C 6 alkyl).

11. A formulation according to claim 1 wherein said molecule said R11 is CH 2 C≡CH and R8 is (unsubstituted C 1 -C 6 alkyl)-S(O) n -(unsubstituted C 1 -C 6 alkyl).

12. A formulation according to claim 1 wherein said molecule said R11 is CH 2 C≡CH and R8 is (unsubstituted C 1 -C 2 alkyl)-S(O) n -(unsubstituted C 1 -C 3 alkyl).

13. A formulation according to claim 1 wherein said molecule said R11 is unsubstituted C 1 -C 3 alkylC≡CH.

14. A formulation according to claim 1 wherein said molecule said R11 is unsubstituted C 1 -C 2 alkylC≡CH.

15. A formulation according to claim 1 wherein said molecule said R11 is CH 2 C≡CH.

16. A formulation according to claim 1 wherein said molecule said R7 is O.

17. A formulation according to claim 1 wherein said molecule said R8 is CH(CH 3 )CH 2 SCH 3 , C(CH 3 ) 2 , CH 2 SCH 3 , CH 2 CH 2 SCH 3 , CH 2 CH(CH 3 )SCH 3 , C(CH 3 ) 2 CH 2 SCH 3 , CH(CH 3 )CH(CH 3 )SCH 3 , CH(CH 3 )SCF 3 , CH 2 CH 2 S(═O)CH 3 , CH(CH 3 )CH 2 S(═O)CH 3 , CH 2 CH 2 S(═O) 2 CH 3 , CH(CH 3 )CH 2 S(═O) 2 CH 3 , CH 2 CH(CF 3 )SCH 3 , CH(CF 3 )CH 2 SCH 3 , CH(CH 3 )SCH 3 , CH 2 SCH 3 , CH 2 CH 2 SCH 2 CH 2 CF 3 , CH 2 S(O)CH 3 , or CH(CH 3 )CH 2 SCD 3 .

18. A formulation according to claim 1 wherein said molecule said X is CR n1 where R n1 is H or halo.

19. A formulation according to claim 1 wherein said molecule said X is CR n1 where R n1 is H or F.

20. A formulation according to one of claim 1 or 2 wherein said carrier is an agriculturally acceptable carrier.

21. A formulation according to claim 1 wherein said formulation is encapsulated inside, or placed on the surface of, a capsule, wherein said capsule has a diameter of about 100-900 nanometers.

22. A formulation according to claim 1 wherein said formulation is encapsulated inside, or placed on the surface of, a capsule, wherein said capsule has a diameter of about 10-900 microns.

23. A formulation according to one of claims 1 and 2 further comprising:
(a) one or more compounds having acaricidal, algicidal, avicidal, bactericidal, fungicidal, herbicidal, insecticidal, molluscicidal, nematicidal, rodenticidal, or virucidal properties; or
(b) one or more compounds that are antifeedants, bird repellents, chemosterilants, herbicide safeners, insect attractants, insect repellents, mammal repellents, mating disrupters, plant activators, plant growth regulators, or synergists; or
(c) both (a) and (b).

24. A formulation according to one of claims 1 and 2 further comprising one or more compounds selected from the group consisting of: (3-ethoxypropyl)mercury bromide, 1,2-dichloropropane, 1,3-dichloropropene, 1-methylcyclopropene, 1-naphthol, 2-(octylthio)ethanol, 2,3,5-tri-iodobenzoic acid, 2,3,6-TBA, 2,3,6-TBA-dimethylammonium, 2,3,6-TBA-lithium, 2,3,6-TBA-potassium, 2,3,6-TBA-sodium, 2,4,5-T, 2,4,5-T-2-butoxypropyl, 2,4,5-T-2-ethylhexyl, 2,4,5-T-3-butoxypropyl, 2,4,5-TB, 2,4,5-T-butomethyl, 2,4,5-T-butotyl, 2,4,5-T-butyl, 2,4,5-T-isobutyl, 2,4,5-T-isoctyl, 2,4,5-T-isopropyl, 2,4,5-T-methyl, 2,4,5-T-pentyl, 2,4,5-T-sodium, 2,4,5-T-triethylammonium, 2,4,5-T-trolamine, 2,4-D, 2,4-D-2-butoxypropyl, 2,4-D-2-ethylhexyl, 2,4-D-3-butoxypropyl, 2,4-D-ammonium, 2,4-DB, 2,4-DB-butyl, 2,4-DB-dimethylammonium, 2,4-DB-isoctyl, 2,4-DB-potassium, 2,4-DB-sodium, 2,4-D-butotyl, 2,4-D-butyl, 2,4-D-diethylammonium, 2,4-D-dimethylammonium, 2,4-D-diolamine, 2,4-D-dodecylammonium, 2,4-DEB, 2,4-DEP, 2,4-D-ethyl, 2,4-D-heptylammonium, 2,4-D-isobutyl, 2,4-D-isoctyl, 2,4-D-isopropyl, 2,4-D-isopropylammonium, 2,4-D-lithium, 2,4-D-meptyl, 2,4-D-methyl, 2,4-D-octyl, 2,4-D-pentyl, 2,4-D-potassium, 2,4-D-propyl, 2,4-D-sodium, 2,4-D-tefuryl, 2,4-D-tetradecylammonium, 2,4-D-triethylammonium, 2,4-D-tris(2-hydroxypropyl)ammonium, 2,4-D-trolamine, 2iP, 2-methoxyethylmercury chloride, 2-phenylphenol, 3,4-DA, 3,4-DB, 3,4-DP, 4-aminopyridine, 4-CPA, 4-CPA-potassium, 4-CPA-sodium, 4-CPB, 4-CPP, 4-hydroxyphenethyl alcohol, 8-hydroxyquinoline sulfate, 8-phenylmercurioxyquinoline, abamectin, abscisic acid, ACC, acephate, acequinocyl, acetamiprid, acethion, acetochlor, acetophos, acetoprole, acibenzolar, acibenzolar-S-methyl, acifluorfen, acifluorfen-methyl, acifluorfen-sodium, aclonifen, acrep, acrinathrin, acrolein, acrylonitrile, acypetacs, acypetacs-copper, acypetacs-zinc, alachlor, alanycarb, albendazole, aldicarb, aldimorph, aldoxycarb, aldrin, allethrin, allicin, allidochlor, allosamidin, alloxydim, alloxydim-sodium, allyl alcohol, allyxycarb, alorac, alpha-cypermethrin, alph

Assignees

• Dow Agrosciences Llc

Inventors

• Niyaz Noormohamed M
• Garizi Negar
• Zhang Yu
• Trullinger Tony K
• Hunter Ricky
• Buysse Ann M
• Kubota Asako
• Leplae Jr Paul R
• Knueppel Daniel
• Lowe Christian T
• Pernich Dan
• Demeter David A
• Johnson Timothy C

Classifications

• A61K31/4439

  containing a five-membered ring with nitrogen as a ring hetero atom, e.g. omeprazole (nicotine A61K31/465) · CPC title

• C07D413/14

  containing three or more hetero rings · CPC title

• A01N47/18

  containing a —O—CO—N< group, or a thio analogue thereof, directly attached to a heterocyclic or cycloaliphatic ring · CPC title

• C07D409/14

  containing three or more hetero rings · CPC title

• C07D417/14

  containing three or more hetero rings · CPC title