Lithium carbon monofluoride-oxygen battery and method of using the same

Patent metadata

Field	Value
Publication number	US-9653729-B2
Application number	US-201113253142-A
Country	US
Kind code	B2
Filing date	Oct 5, 2011
Priority date	Oct 7, 2010
Publication date	May 16, 2017
Grant date	May 16, 2017

Abstract

A lithium carbon monofluoride-oxygen battery is provided that includes a lithium metal-containing electroactive anode; an electroactive cathode formed of a carbon monofluoride compound; an electrolyte solution formed of an organic solvent and a lithium salt; a casing surrounding the anode, the cathode, and the electrolyte solution; and a port bored through the casing wherein the port selectively allows the flow of gas into the casing. In addition, a method of using an electrochemical battery is provided that includes providing a lithium carbon monofluoride-oxygen battery; closing the valve of the electrochemical battery to block the flow of gas into the battery; discharging the electrochemical battery after closing the valve of the battery; opening the valve of the electrochemical battery after discharging the electrochemical battery to expose the cathode to the flow of oxygen containing gas; and discharging the electrochemical battery after opening the valve of the electrochemical battery.

First claim

We claim:

1. A sealably-enclosed storage lithium carbon monofluoride-oxygen battery system comprising:
a lithium metal-containing electroactive anode;
an electroactive cathode formed of a carbon monofluoride compound and wherein said electroactive cathode comprises a fluorinated carbon CFx mixed with a conductive carbon binder, where 0<x<1.2;
an electrolyte solution formed of a organic solvent and a lithium salt wherein said electrolyte comprises a polymer and forms a gel;
a casing surrounding said anode, said cathode, and said electrolyte solution; and
a port bored through said casing, wherein said port selectively allows the flow of an oxygen containing gas into said casing.

2. The system of claim 1 , further comprising a valve that controls the flow of a gas through said port.

3. The system of claim 2 , wherein said gas comprises oxygen.

4. The system of claim 1 , further comprising a removable covering that prevents the flow of a gas through said port.

5. The system of claim 1 , further comprising a microporous separator that separates said anode from said cathode.

6. The system of claim 5 , wherein said microporous separator comprises at least one of polypropylene, polyethylene, glass, and other compositions of matter insoluble in said electrolyte.

7. The system of claim 1 , wherein said lithium salt comprises any of LiCl, LiBr, LiI, LiClO4, LiBF4, LiPF6, LiAsF6, LiCH3CO2, LiCF3CO2, LiCH3SO3, LiCF3SO3, Li(CF3SO2)2N, LiB(C6H5)4, LiB(C2O4)2, LiB(C2O4)F2, LiB(OCH2CO2)F2, LiSCN, LiNO3, and LiBF4.

8. The system of claim 1 , wherein said solvent comprises any of N-methylpyrolidinone, N,N-dimethylacetamide, gamma-butyrolactone, methyl ethyl ketone, dimethoxyethane, tetrahydrofuran, dimethylformamide, ethylene carbonate, propylene carbonate, butylene carbonate, vinylene carbonate, dimethyl carbonate, diethyl carbonate, dipropyl carbonate, ethylmethyl carbonate, methylpropyl carbonate, ethylpropyl carbonate, methyl propionate, methyl butyrate, ethyl butyrate, and any mixture thereof.

9. The system of claim 1 , wherein said polymer comprises any of polyacrylon nitrile, polyacrylon nitrile methyl acrylate copolymers, polyethylene oxide, polyvinyldene fluoride, and polyimides.

10. A sealably-enclosed storage lithium carbon monofluoride-oxygen battery system wherein said-a cathode comprises 60% CFx active material, 35% carbon, and 5% polytetrafluoroethylene binder, where 0<x<1.2, and wherein said electrolyte comprises 1 M LiBF4 in PC/DME 1:1.

Assignees

• Foster Donald L
• Read Jeffery A
• Wolfenstine Jeffery
• Zhang Shengshui
• Us Army

Inventors

• Foster Donald L
• Read Jeffery A
• Wolfenstine Jeffery
• Zhang Shengshui

Classifications

• H01M6/50

  Methods or arrangements for servicing or maintenance, e.g. for maintaining operating temperature (constructional details of current conducting connections for detecting conditions inside cells or batteries, e.g. details of voltage sensing terminals, H01M50/569) · CPC title

• H01M4/5835

  Comprising fluorine or fluoride salts · CPC title

• H01M4/40 Primary

  Alloys based on alkali metals · CPC title

• H01M4/06

  Electrodes for primary cells · CPC title

• H01M12/06

  with one metallic and one gaseous electrode · CPC title