Semi-closed loop LNG process

Patent metadata

Field	Value
Publication number	US-9651300-B2
Application number	US-201313963508-A
Country	US
Kind code	B2
Filing date	Aug 9, 2013
Priority date	Jun 16, 2004
Publication date	May 16, 2017
Grant date	May 16, 2017

Abstract

A semi-closed loop system for producing liquefied natural gas (LNG) that combines certain advantages of closed-loop systems with certain advantages of open-loop systems to provide a more efficient and effective hybrid system. In the semi-closed loop system, the final methane refrigeration cycle provides significant cooling of the natural gas stream via indirect heat transfer, as opposed to expansion-type cooling. A minor portion of the LNG product from the methane refrigeration cycle is used as make-up refrigerant in the methane refrigeration cycle. A pressurized portion of the refrigerant from the methane refrigeration cycle is employed as fuel gas. Excess refrigerant from the methane refrigeration cycle can be recombined with the processed natural gas stream, rather than flared.

First claim

What is claimed is:

1. A method for liquefying a natural gas stream comprising the steps of:
providing a liquefied natural gas facility having at least three sequential cooling cycles, each employing a different refrigerant;
wherein the at least three sequential cooling cycles comprise a first cooling cycle with a first refrigerant, a second cooling cycle with a second refrigerant, and a third cooling cycle with a third refrigerant, wherein the third refrigerant is a predominantly methane refrigerant;
wherein the third cooling cycle comprises an open-loop methane refrigeration cycle;

cooling the natural gas stream in the first cooling cycle with the first refrigerant;
cooling the natural gas stream in the second cooling cycle with the second refrigerant;
introducing the natural gas stream to a heavies removal column for separating the natural gas stream into a heavies stream and a heavies-reduced natural gas stream;
compressing a predominantly methane stream to form a compressed methane refrigerant;
separating the compressed methane refrigerant into a first compressed methane refrigerant portion and a second compressed methane refrigerant portion;
cooling the first compressed methane refrigerant portion in the second cooling cycle via indirect heat exchange with the second refrigerant to form a cooled intermediate refrigerant;
combining the cooled intermediate refrigerant with the second compressed methane refrigerant portion to form an intermediate refrigerant stream;
separating the intermediate refrigerant stream into a third compressed methane refrigerant portion and a fourth compressed methane refrigerant portion;
introducing the heavies-reduced natural gas stream into the open-loop methane refrigeration cycle by combining the heavies-reduced natural gas stream with the third compressed methane refrigerant portion to form a combined stream;
introducing the combined stream into a methane economizer for cooling to form a first natural gas stream;
cooling the fourth compressed methane refrigerant portion in the second cooling cycle via indirect heat exchange with the second refrigerant to form a cooled methane refrigerant product;
introducing the cooled methane refrigerant product to a methane refrigerant accumulation vessel wherein a liquid level is formed in the methane refrigerant accumulation vessel;
controlling a liquid level in the methane refrigerant accumulation vessel by adjusting a flow of the third compressed methane refrigerant portion with respect to a flow of the fourth compressed methane refrigerant portion to maintain the liquid level in the methane refrigerant accumulation vessel;
introducing the cooled methane refrigerant product from the methane refrigerant accumulation vessel into the methane economizer for cooling to form the predominately methane refrigerant;
cooling the first natural gas stream in a plurality of separate heat exchangers via indirect heat exchange with the predominately methane refrigerant to form a liquefied natural gas product and a vapor portion of the first natural gas stream;
combining a portion of the predominately methane refrigerant with the vapor portion of the first natural gas stream to form part of the predominantly methane stream that is compressed.

2. The method of claim 1 wherein the step of controlling the liquid level in the methane refrigerant accumulation vessel ensures a single phase fluid (liquid) being introduced to the methane economizer in the step of introducing the cooled methane refrigerant product from the methane refrigerant accumulation vessel into the methane economizer.

3. The method of claim 1 wherein the first refrigerant comprises propane and wherein the second refrigerant comprises predominantly ethylene.

4. The method of claim 1 wherein the first refrigerant comprises predominantly propane.

5. The method of claim 1 wherein the first refrigerant comprises predominantly propylene.

6. The method of claim 1 wherein the first refrigerant comprises predominantly carbon dioxide.

7. The method of claim 1 wherein the second refrigerant is predominantly ethylene.

8. The method of claim 1 wherein the second refrigerant is predominantly ethane or carbon dioxide.

Assignees

• Conocophillips Co

Inventors

• Eaton Anthony P

Classifications

• F25J2215/02

  Mixing or blending of fluids to yield a certain product · CPC title

• F25J2245/02

  Recycle of a stream in general, e.g. a by-pass stream · CPC title

• F25J1/025

  Details related to the refrigerant production or treatment, e.g. make-up supply from feed gas itself · CPC title

• F25J1/0045

  by vaporising a liquid return stream · CPC title

• F25J2220/64

  Separating heavy hydrocarbons, e.g. NGL, LPG, C4+ hydrocarbons or heavy condensates in general · CPC title