Compositions of hydrocarbon oils and oil soluble PAGS produced by DMC catalysts

Patent metadata

Field	Value
Publication number	US-9650588-B2
Application number	US-201214350094-A
Country	US
Kind code	B2
Filing date	Sep 14, 2012
Priority date	Oct 28, 2011
Publication date	May 16, 2017
Grant date	May 16, 2017

Abstract

A lubricant composition comprising a Group I, II, III or IV hydrocarbon oil and a polyalkylene glycol, the polyalkylene glycol having been prepared by reacting a C 8 -C 20 alcohol and a mixed butylene oxide/propylene oxide feed using a double metal cyanide catalyst catalyzed oxyalkylation process, and wherein the lubricant composition remains clear and shows no phase separation at temperatures equal to and greater than the pour point of the hydrocarbon oil is provided. A method for making a lubricant composition is also provided.

First claim

We claim:

1. A lubricant composition comprising:
a Group I, II, III or IV hydrocarbon oil; and
a polyalkylene glycol, the polyalkylene glycol having been prepared by reacting a C 8 -C 12 alcohol and a mixed butylene oxide/propylene oxide feed having a ratio of units derived from butylene oxide to the ratio of units derived from propylene oxide is from 3:1 to 1.3:1 using a double metal cyanide catalyst catalyzed oxyalkylation process, wherein the polyalkylene glycol has a kinematic viscosity of >100 cSt at 40° C.;
wherein the lubricant composition remains clear and shows no phase separation at temperatures equal to or greater than the pour point of the hydrocarbon oil.

2. The lubricant composition according to claim 1 , wherein the lubricant composition comprises from 99.5 to 0.5 weight percent of the hydrocarbon oil and from 0.5 to 99.5 weight percent of the polyalkylene glycol.

3. The lubricant composition according to claim 1 , wherein the hydrocarbon oil and the polyalkylene glycol are soluble with one another for at least one week under at least one temperature selected from temperatures from 80° C. to −15° C.

4. The lubricant composition according to claim 1 , wherein the polyalkylene glycol has a carbon to oxygen ratio of at least 4:1.

5. The lubricant composition according to claim 1 , wherein the polyalkylene glycol has a carbon to oxygen ratio that is from 4:1 to 6:1.

6. The lubricant composition according to claim 1 , wherein the polyalkylene glycol has an unsaturation level <0.05 meq/g.

7. The lubricant composition according to claim 1 , wherein, the polyalkylene glycol has a kinematic viscosity of >100 cSt at 40° C. and comprises a ratio of units derived from butylene oxide to units derived from propylene oxide from 3:1 to 1.3:1.

8. A method of preparing a lubricant composition comprising blending at least (a) a Group I, II, III, or IV hydrocarbon oil, and (b) a polyalkylene glycol prepared by reacting a C 8 -C 12 alcohol and a mixed butylene oxide/propylene oxide feed having a ratio of units derived from butylene oxide to the ratio of units derived from propylene oxide from 3:1 to 1.3:1 in a double metal cyanide catalyst catalyzed oxyalkylation process, wherein the polyalkylene glycol has a kinematic viscosity of >100 cSt at 40° C., under conditions such that the hydrocarbon oil and the polyalkylene glycol are soluble with one another.

Assignees

• Greaves Martin R
• Van Voorst Ronald
• Meertens Marinus
• Dow Global Technologies Llc

Inventors

• Greaves Martin R
• Van Voorst Ronald
• Meertens Marinus

Classifications

• C10N2020/04

  Molecular weight; Molecular weight distribution · CPC title

• C10N2030/70

  Soluble oils · CPC title

• C10N2070/00

  Specific manufacturing methods for lubricant compositions · CPC title

• C10M2209/1055

  used as base material · CPC title

• C10M169/041 Primary

  the additives being macromolecular compounds only · CPC title