Stabilized blends containing antioxidants

Patent metadata

Field	Value
Publication number	US-9650587-B2
Application number	US-201615206841-A
Country	US
Kind code	B2
Filing date	Jul 11, 2016
Priority date	May 26, 2011
Publication date	May 16, 2017
Grant date	May 16, 2017

Abstract

The present invention relates to functional fluid compositions containing antioxidants, and specifically stable compositions containing antioxidants with limited solubility in and/or limited compatibility with the functional fluids with which they are used. In particular the present invention deals with functional fluids used in internal combustion engines, such as engine oils, and antioxidants containing a phenolic or benzoic group, where the antioxidant is present in the functional fluid composition at levels that would otherwise cause the composition to be unstable and/or hazy.

First claim

We claim:

1. An additive concentrate composition comprising:
(a) a medium comprising a solvent, a functional fluid, or combinations thereof; and
(b) at least 10 wt % of an antioxidant component that is not fully soluble in the medium, wherein said antioxidant comprises:
an alkylated diphenyl amine antioxidant, an alkylated phenyl-naphthyl amine antioxidant, or a combination thereof; and

(c) at least 20 wt % of a stabilizing component that is soluble in (a) and that interacts with (b) such that (b)'s solubility in (a) is improved, wherein said stabilizing component comprises:
(i) a nitrogen-containing dispersant derived from a 1000 number average molecular weight polyisobutylene succinic anhydride and polyalkylene polyamines; (ii) a borated nitrogen-containing dispersant derived from a 2000 number average molecular weight polyisobutylene derived succinic anhydride and polyalkylene polyamines; (iii) a trialkyl borate, or combinations thereof; and

wherein components (b) and (c) are present in component (a) in the form of dispersed particles having an average diameter of less than 10 microns.

2. The composition of claim 1 wherein the turbidity of the overall composition is improved, as defined by a lower JTU and/or NTU value compared to the same composition that does not contain (c), the stabilizing component.

3. The composition of claim 1 wherein (b), the antioxidant component, comprises a compound containing at least one nitrogen atom, one or more aromatic groups, and at least one hydrocarbyl substituent group.

4. The composition of claim 1 wherein component (a), the medium, comprises: (i) a mineral oil; (ii) a polyolefin-based synthetic oil, or a combination thereof.

5. The composition of claim 1 wherein component (a), the medium, comprises a functional fluid selected from the group consisting of: gear oils, greases, turbine fluids, transmission oils, hydraulic fluids, engine oils, two cycle oils, metalworking fluids, fuels, oil field or pipeline fluids, or a combination thereof.

6. The composition of claim 1 wherein component (c), the stabilizing component, comprises (i) a compound that contains at least one B—O—R group where the R is hydrogen or a hydrocarbyl group; (ii) a borated nitrogen-containing dispersant; or (iii) combinations thereof.

7. The composition of claim 1 wherein component (c), the stabilizing component, comprises a quaternary salt comprising the reaction product of:
(i) at least one compound selected from the group consisting of: (a) the condensation product of a hydrocarbyl-substituted acylating agent and a compound having an oxygen or nitrogen atom capable of condensing with said acylating agent and said condensation product further having a tertiary amino group; (b) a polyalkene-substituted amine having at least one tertiary amino group; and (c) a Mannich reaction product having a tertiary amino group, said Mannich reaction product being prepared from the reaction of a hydrocarbyl-subsituted phenol, an aldehyde, and an amine; and
(ii) a quaternizing agent suitable for converting the tertiary amino group of compound (i) to a quaternary nitrogen, wherein the quaternizing agent is selected from the group consisting of dialkyl sulfates, benzyl halides, hydrocarbyl substituted carbonates; hydrocarbyl epoxides in combination with an acid or mixtures thereof.

8. A process of preparing a clear and stable additive concentrate composition comprising:
(a) a medium comprising a solvent, a functional fluid, or combinations thereof; and
(b) at least 10 wt % of an antioxidant component that is not fully soluble in the medium, wherein said antioxidant comprises:
an alkylated diphenyl amine antioxidant, an alkylated phenyl-naphthyl amine antioxidant, or a combination thereof; and

(c) at least 20 wt % of a stabilizing component that is soluble in (a) and that interacts with (b) such that (b)'s solubility in (a) is improved, wherein said stabilizing component comprises:
(i) a nitrogen-containing dispersant derived from a 1000 number average molecular weight polyisobutylene succinic anhydride and polyalkylene polyamines; (ii) a borated nitrogen-containing dispersant derived from a 2000 number average molecular weight polyisobutylene derived succinic anhydride and polyalkylene polyamines; (iii) a trialkyl borate, or combinations thereof; and;

said method comprising the steps of:
I. adding components (b) and (c) to component (a);
II. mixing the components so that particles of components (b) and (c) have an average diameter of less than 10 microns.

9. The process of claim 8 wherein the clarity of the resulting mixture is improved, as defined by a lower JTU and/or NTU value compared to the same composition that does not contain (c), the stabilizing component.

10. The composition of claim 1 wherein (i) a nitrogen containing dispersant has an N:CO ratio of at least 1:1.

11. The process of claim 8 wherein (i) a nitrogen containing dispersant has an N:CO ratio of at least 1:1.

Assignees

• Lubrizol Corp

Inventors

• Ivancic Danielle N
• Burrington James D
• Delbridge Ewan E

Classifications

• C10N2050/015

  Dispersions of solid lubricants · CPC title

• C10M2207/0406

  used as base material · CPC title

• C10M2215/065

  Phenyl-Naphthyl amines · CPC title

• C10L1/224

  Amides; Imides {carboxylic acid amides, imides (C10L1/221, C10L1/2227 take precedence)} · CPC title

• C10M2215/064

  Di- and triaryl amines · CPC title