Zinc Halide Mediated Cyclization Process Leading to Tricyclic Indoles
US-2015336891-A1 · Nov 26, 2015 · US
US9650565B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9650565-B2 |
| Application number | US-201013502834-A |
| Country | US |
| Kind code | B2 |
| Filing date | Oct 20, 2010 |
| Priority date | Oct 20, 2009 |
| Publication date | May 16, 2017 |
| Grant date | May 16, 2017 |
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A carbazole compound represented by the following formula: wherein, when m=1, n=0, Ar 1 , Ar 2 , Ar 3 and X 2 are C 6-50 aryl or C 4-50 heteroaryl, provided that Ar 1 and Ar 2 , or Ar 3 and X 2 may form together a ring; X 1 =C 6-50 arylene; R 1 , R 2 , R 4 , R 5 and R 7 are H, halogen, amino, C 1-18 alkyl, C 1-18 alkoxy, C 6-50 aryl or C 4-50 heteroaryl, R 3 and R 6 are H, halogen, C 1-18 alkyl, C 1-18 alkoxy, C 6-50 aryl or C 4-50 heteroaryl; when m=0, n=1-3, Ar 3 , Ar 4 and Ar 5 are C 6-50 aryl or C 4-50 heteroaryl, Ar 4 and Ar 5 may form together a ring; X 1 =C 1-18 alkyl, C 6-50 aryl or C 4-50 heteroaryl; X 2 =C 6-50 arylene; R 1 -R 7 are H, halogen, C 1-18 alkyl, C 1-18 alkoxy, C 6-50 aryl or C 4-50 heteroaryl; when m=0, n=0, X 1 =C 1-18 alkyl, C 6-50 aryl or C 4-50 heteroaryl; Ar 3 and X 2 are C 6-50 aryl or C 4-50 heteroaryl; R 2 =H, halogen, C 1-18 alkyl, C 1-18 alkoxy; R 1 and R 3 -R 7 are H, halogen, C 1-18 alkyl, C 1-18 alkoxy, C 6-50 aryl or C 4-50 heteroaryl. The carbazole compound is suitable for an organic EL device.
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The invention claimed is: 1. A carbazole compound represented by the following general formula (12): wherein: Ar 15 and Ar 16 in the formula (12) independently represent a methyl-substituted or unsubstituted 4-biphenylyl group, a methyl-substituted or unsubstituted 3-biphenylyl group, a methyl-substituted or unsubstituted m-terphenylyl group, or a methyl-substituted or unsubstituted 2-fluorenyl group; R 35 represents a straight-chain, branched or cyclic alkyl group having 1 to 18 carbon atoms, a substituted or unsubstituted biphenylyl group, a substituted or unsubstituted terphenylyl group, a substituted or unsubstituted naphthyl group, a substituted or unsubstituted phenanthryl group, a substituted or unsubstituted anthryl group, a substituted or unsubstituted fluoranthenyl group, a substituted or unsubstituted perylenyl group, a substituted or unsubstituted pyrenyl group, a substituted or unsubstituted pycenyl group, a substituted or unsubstituted chrysenyl group, or a substituted or unsubstituted heteroaryl group having 4 to 50 carbon atoms; R 37 represents a hydrogen atom, a halogen atom, a straight-chain, branched or cyclic alkyl group having 1 to 18 carbon atoms, or a straight-chain, branched or cyclic alkoxy group having 1 to 18 carbon atoms; and R 36 and R 38 through R 42 independently represent a hydrogen atom, a halogen atom, a straight-chain, branched or cyclic alkyl group having 1 to 18 carbon atoms, a straight-chain, branched or cyclic alkoxy group having 1 to 18 carbon atoms, a substituted or unsubstituted aryl group having 6 to 50 carbon atoms, or a substituted or unsubstituted heteroaryl group having 4 to 50 carbon atoms.
with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to carbon atoms of the ring system · CPC title
containing one nitrogen atom as the heteroatom · CPC title
containing organic luminescent materials · CPC title
directly linked by a ring-member-to-ring-member bond · CPC title
characterised by the chemical or physical composition or the arrangement of the electroluminescent material {, or by the simultaneous addition of the electroluminescent material in or onto the light source} · CPC title
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