High-flow fiber reinforced polypropylene composition

Patent metadata

Field	Value
Publication number	US-9650504-B2
Application number	US-201314389543-A
Country	US
Kind code	B2
Filing date	Mar 27, 2013
Priority date	Apr 4, 2012
Publication date	May 16, 2017
Grant date	May 16, 2017

Abstract

Fiber reinforced composition comprising a heterophasic propylene copolymer, a propylene homopolymer and/or a propylene copolymer, and fibers having an average diameter of 12.0 μm or less, wherein the propylene copolymer comprises not more than 2.0 wt.-% C2 to C10 α-olefins other than propylene, the propylene homopolymer and the propylene copolymer have a melt flow rate MFR 2 (230° C.) of at least 100 g/10 min, and the composition has a melt flow rate MFR 2 (230° C.) of at least 10 g/10 min.

First claim

We claim:

1. A fiber reinforced composition comprising,
(a) a heterophasic propylene copolymer (HECO),
(b) a propylene homopolymer (H-PP1) and/or a propylene copolymer (C-PP1), and
(c) fibers (F) having an average diameter of 12.0 μm or less and an aspect ratio of 150 to 450,
wherein
(i) the propylene copolymer (C-PP1) comprises not more than 2.0 wt.-% C 2 to C 10 α-olefins other than propylene,
(ii) the propylene homopolymer (H-PP1) and the propylene copolymer (C-PP1) have a melt flow rate MFR 2 (230 ° C.) measured according to ISO 1133 of at least 50 g/10min, and
(iii) the fiber reinforced composition has a melt flow rate MFR 2 (230 ° C.) measured according to ISO 1133 of at least 10 g/10 min.

2. The fiber reinforced composition according to claim 1 , wherein the heterophasic propylene copolymer (HECO) comprises a polypropylene matrix (M-PP) and dispersed therein an elastomeric copolymer (E1) comprising units derived from
propylene and
ethylene and/or C4 to C20 α-olefin.

3. The fiber reinforced composition according to claim 2 , wherein the polypropylene matrix (M-PP) has a lower melt flow rate MFR 2 (230 ° C.) measured according to ISO 1133 than the propylene homopolymer (H-PP1) or the propylene copolymer (C-PP1).

4. The fiber reinforced composition according to claim 1 , wherein the composition comprises
(a) 10.0 to 50.0 wt.-% of the heterophasic propylene copolymer (HECO),
(b) 20.0 to 70.0 wt.-% of the propylene homopolymer (H-PP1), of the propylene copolymer (C-PP1), or of the mixture of the propylene homopolymer (H-PP1) and the propylene copolymer (C-PP1), and
(c) 5.0 to 50.0 wt.-% of fibers (F), based on the total weight of the fiber reinforced composition.

5. The fiber reinforced composition according to claim 1 , wherein the heterophasic propylene copolymer (HECO) has
(a) a xylene cold soluble content (XCS) measured according ISO 6427 (23 ° C.) of not more than 35 wt.-%, and/or
(b) a melt flow rate MFR 2 (230 ° C.) measured according to ISO 1133 of more than 15 g/10 min, and/or
(c) a total C 2 to C 10 α-olefin content other than propylene of 10 to 30 wt.-%.

6. The fiber reinforced composition according to claim 1 , wherein the propylene homopolymer (H-PP1) has a melt flow rate MFR 2 (230 ° C.) measured according to ISO 1133 in the range of 50 to 150 g/10 min.

7. The fiber reinforced composition according to claim 1 , wherein the fibers (F) are selected from the group consisting of glass fibers, metal fibers, ceramic fibers and graphite fibers.

8. An automotive article comprising the fiber reinforced composition according to claim 1 .

9. A foamed article, comprising the fiber reinforced composition according to claim 1 .

10. A process for the preparation of the fiber reinforced composition according to claim 1 comprising, the steps of adding
(a) the heterophasic propylene copolymer (HECO),
(b) the propylene homopolymer (H-PP1), the propylene copolymer (C-PP1), or the mixture of the propylene homopolymer (H-PP1) and the propylene copolymer (C-PP1), and
(c) the fibers (F)
to an extruder and extruding the same obtaining said fiber reinforced composition.

11. The fiber reinforced composition according to claim 1 , wherein the heterophasic propylene copolymer (HECO) comprises a polypropylene matrix (M-PP) that is a propylene homopolymer (H-PP2) and dispersed therein an elastomeric copolymer (E1) comprising units derived from
propylene and
ethylene and/or C4 to C20 α-olefin.

Assignees

• Borealis Ag

Inventors

• Kastner Erwin
• Kastl Jochen
• Hemmeter Markus

Classifications

• C08L2203/14

  used for foams · CPC title

• C08L2207/02

  Heterophasic composition · CPC title

• C08L23/16

  Ethylene-propylene or ethylene-propylene-diene copolymers · CPC title

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title

• C08L23/0815

  with aliphatic 1-olefins containing one carbon-to-carbon double bond · CPC title