Polyurethaneureas for wood coatings

Patent metadata

Field	Value
Publication number	US-9650467-B2
Application number	US-201514940729-A
Country	US
Kind code	B2
Filing date	Nov 13, 2015
Priority date	Nov 17, 2014
Publication date	May 16, 2017
Grant date	May 16, 2017

Abstract

The invention relates to a cationically hydrophilized polyurethaneurea characterized in that it is synthesized from
a) at least one aliphatic, araliphatic and/or cycloaliphatic polyisocyanate, b) polyols having a number-average molecular weight Mn≧400 and ≦6000 g/mol and a hydroxyl functionality of ≧1.5 and ≦4, comprising at least one polyester polyol b1), which has an amorphous structure and which comprises as synthesis component at least one aromatic dicarboxylic acid and/or the corresponding carboxylic anhydride, the fraction of aromatic dicarboxylic acids and/or their anhydrides in the polyester polyol being ≧35 wt %, based on the overall mass of the polyester polyol, c) at least one cationically hydrophilizing component which has at least one group that is reactive towards isocyanate groups, and has at least one cationic or potentially cationic group, d) at least one aliphatic, amino-functional compound which has at least two isocyanate-reactive amino groups, e) optionally at least one alcohol which has at least two hydroxyl groups and a molar mass ≧60 and ≦399 g/mol and f) optionally at least one compound which has a group that is reactive towards isocyanate groups.

The invention further relates to an aqueous dispersion comprising the polyurethaneurea and to a coating composition comprising the polyurethaneurea or the corresponding aqueous dispersion. Further subjects of the invention are a method for coating substrates using the coating composition of the invention, and the coated substrate obtainable in such a method.

First claim

The invention claimed is:

1. A cationically hydrophilized polyurethaneurea synthesized from
a) ≧20 and ≦55 wt % of at least one aliphatic, araliphatic and/or cycloaliphatic polyisocyanate selected from HDI, H12-MDI and/or IPDI,
b) ≧20 and ≦50 wt % of polyols having a number-average molecular weight Mn≧400 and ≦6000 g/mol and a hydroxyl functionality of ≧1.5 and ≦4,
(i) comprising at least one polyester polyol b1), which has an amorphous structure and which comprises exclusively aromatic dicarboxylic acids and/or the corresponding carboxylic anhydrides as acid component, the fraction of aromatic dicarboxylic acids and/or their anhydrides in the polyester polyol being ≧35 wt %, based on the overall mass of the polyester polyol, and
(ii) comprising at least one polyester polyol b2), which comprises exclusively aliphatic dicarboxylic acids and/or the corresponding carboxylic anhydrides as acid component,
wherein the weight ratio between polyester polyol b1) and polyester polyol b2) is between 2:1 and 1:3;

c) ≧5 and ≦15 wt % of at least one cationically hydrophilizing component selected from N,N′-bis(hydroxyalkyl)alkylamines,
d) ≧2 and ≦12 wt % of at least one aliphatic, amino-functional compound which has at least two isocyanate-reactive amino groups, comprising ≧95 wt % of isophoronediamine IPDA, based on the overall mass of component d),
e) ≧1 and ≦4 wt % of optionally at least one alcohol which has at least two hydroxyl groups and a molar mass ≧60 and ≦399 g/mol and
f) ≧0 and ≦10 wt % of at least one compound which has a group that is reactive towards isocyanate groups, based in each case on the overall mass of the polyurethaneurea, based in each case on the overall mass of the polyurethaneurea, with components a) to f) adding up to 100 wt %.

2. The polyurethaneurea according to claim 1 , wherein the polyester polyol b1) has a Tg≧−25° C., determined by dynamic scanning calorimetry DSC in accordance with DIN EN 61006, Method A.

3. The polyurethaneurea according to claim 1 , wherein the polyurethaneurea has a cationic and/or potentially cationic group content of ≧0.2 and ≦5 milliequivalents per g of polyurethaneurea.

4. The polyurethaneurea according to claim 1 , wherein component a) comprises ≧95 wt % of isophorone diisocyanate IPDI, based on the overall mass of component a).

5. The polyurethaneurea according to claim 1 , wherein the polyurethaneurea has no nonionically hydrophilizing groups.

6. The polyurethaneurea according to claim 1 , wherein the polyurethaneurea is obtained by reaction of components a), b), c) and optionally e) to give an isocyanate-terminated prepolymer, subsequent reaction of the prepolymer with component d) and optionally components e) and f), and, if component c) comprises a potentially cationic group, neutralization of this group by an acid before, during or after the reaction of the isocyanate-terminated prepolymer with component d) and optionally components e) and f).

7. An aqueous dispersion comprising the polyurethaneurea according to claim 1 .

8. A coating composition comprising the polyurethaneurea according to claim 1 or an aqueous dispersion comprising the polyurethaneurea according to claim 1 .

9. A method for the coating of substrates, comprising applying a coating composition according to claim 8 to a substrate.

10. The Method according to claim 9 , wherein the substrate is wood or an MDF (medium-density fibreboard) panel.

11. A coated substrate obtained by the method according to claim 9 .

12. The polyurethaneurea according to claim 1 , wherein the weight ratio between polyester polyol b1) and polyester polyol b2) is between 1:2 to 2:1.

Assignees

• Covestro Deutschland Ag

Inventors

• Nazaran Pantea
• Gertzmann Rolf
• Garcia Martinez Juan Miguel
• Almato Guiteras Maria
• Tejada Eva

Classifications

• C08G18/4238

  derived from dicarboxylic acids and dialcohols · CPC title

• C08G18/755 Primary

  and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate · CPC title

• C09D175/06

  from polyesters · CPC title

• C08G2150/00

  Compositions for coatings · CPC title

• C08G18/12

  using two or more compounds having active hydrogen in the first polymerisation step · CPC title