Methods of using downhole compositions including an ion-sequestering compound

Patent metadata

Field	Value
Publication number	US-9650299-B2
Application number	US-201313929848-A
Country	US
Kind code	B2
Filing date	Jun 28, 2013
Priority date	Jun 28, 2013
Publication date	May 16, 2017
Grant date	May 16, 2017

Abstract

The present invention relates to methods and compositions for the treatment of subterranean formations. In various embodiments, the method includes obtaining or providing a composition including at least one-ion sequestering compound, sequestering at least one ion from a polymer in the composition with the at least one ion-sequestering compound, and contacting a subterranean material downhole with the composition.

First claim

What is claimed is:

1. A method of treating a subterranean formation, the method comprising:
placing in the subterranean formation a composition comprising
at least one polymer selected from the group consisting of starch, guar gum, a guar gum derivative, gum ghatti, tamarind, tragacanth, gum arabic, locust bean gum, gellan, alginate, curdlan, diutan, gellan, kefiran, levan, pullulan, scleroglucan, schizophyllan, succinoglycan, xanthan, welan, and polyacrylamide;
at least one ion selected from the group consisting of Na + , K + , Ag + , NH 4 + , Al 3+ , Cu 2+ , Fe 2+ , Fe 3+ , Mg 2+ and a combination thereof; and
at least one ion-sequestering compound selected from the group consisting of sodium metasilicate, sodium orthosilicate, sodium pyrosilicate, a metal chelator, a sarcosinate, a detergent, urea monochloride, urea sulfate, and an organic acid or a salt thereof, wherein the composition comprises about 0.000,000,001 wt % to about 30 wt % of the ion-sequestering compound,
wherein the organic acid is selected from the group consisting of lactic acid, oxalic acid, glutaric acid, glutamic acid, adipic acid, phthalic acid, and uric acid,
wherein the metal chelator is selected from the group consisting of a (C 2 -C 20 )hydrocarbylene polyamine, a porphyrin, phytochelatin, diethylenetriaminepentaacetic acid, N,N-bis(carboxymethyl)glycine, and 1,2-dihydroxybenzene-3,5-disulfonic acid; and

sequestering the ion from the polymer with the ion-sequestering compound.

2. The method of claim 1 , wherein the sequestering of the ion by the ion-sequestering compound comprises sequestering about 5 mol % to about 100 mol % of the ion in the composition.

3. The method of claim 1 , wherein the sequestering of the ion by the ion-sequestering compound is such that the polymer has at least one of a degree of hydration, a hydratability, a degree of gel contraction, a gel contractability, a degree of crosslinking, a crosslinkability, and a viscosity that is substantially the same as the corresponding one or more characteristics of the polymer in a corresponding composition comprising the polymer and the ion but comprising less or none of the ion-sequestering compound.

4. The method of claim 1 , wherein the sequestering of the ion by the ion-sequestering compound is such that the polymer has at least one of a degree of hydration, a hydratability, a degree of gel contraction, a gel contractability, a degree of crosslinking, a crosslinkability, and a viscosity that is substantially the same as the corresponding one or more characteristics of the polymer in a corresponding composition comprising the polymer but comprising less or none of the ion.

5. The method of claim 1 , wherein the ion-sequestering compound comprises at least one of sodium metasilicate, sodium orthosilicate, sodium pyrosilicate, a sarcosinate, urea monohydrochloride, and urea sulfate.

6. The method of claim 1 , wherein the polymer is at least one of hydratable, crosslinkable, and a drilling fluid viscosifier.

7. The method of claim 1 , wherein the polymer comprises a linear polysaccharide.

8. The method of claim 1 , wherein at least one of a degree of hydration of the polymer is increased, degree of crosslinking of the polymer is increased, or a viscosity of the composition is increased.

9. The method of claim 1 , wherein the composition comprises about 0.000,000,1 wt % to about 50 wt % of the polymer.

10. The method of claim 1 , wherein in a corresponding composition comprising the polymer and the ion but comprising less or none of the ion-sequestering compound, the ion at least one of decreases a degree of hydration of the polymer in the corresponding composition, decreases a hydratability of the polymer in the corresponding composition, decreases a degree of crosslinking of the polymer in the corresponding composition, decreases a crosslinkability of the polymer in the corresponding composition, increases a degree of gel contraction of the corresponding composition, increases a gel contractability of the corresponding composition, and decreases a viscosity of the corresponding composition.

11. The method of claim 1 , wherein the ion comprises fluoride, chloride, bromide, iodide, nitrate, hydrogen sulfate, dihydrogen phosphate, bicarbonate, nitrite, perchlorate, iodate, chlorate, bromate, chlorite, hypochlorite, hypobromite, cyanide, amide, cyanate, hydroxide, permanganate, acetate, formate, oxide, sulfide, nitride, arsenate, phosphate, arsenite, hydrogen phosphate, sulfate, thiosulfate, sulfite, carbonate, chromate, dichromate, peroxide, or oxalate.

12. The method of claim 1 , wherein the composition comprises about 0.000,000,001 wt % to about 30 wt % of the ion.

13. The method of claim 1 , further comprising combining the composition with an aqueous or oil-based fluid comprising a drilling fluid, stimulation fluid, fracturing fluid, spotting fluid, clean-up fluid, production fluid, completion fluid, remedial treatment fluid, abandonment fluid, pill, acidizing fluid, cementing fluid, packer fluid, diverting fluid, or a combination thereof, to form a mixture, wherein the placing of the composition in the subterranean formation comprises placing the mixture in the subterranean formation.

14. The method of claim 13 , wherein the cementing fluid comprises Portland cement, pozzolana cement, gypsum cement, high alumina content cement, slag cement, silica cement, or a combination thereof.

15. The method of claim 1 , wherein at least one of prior to, during, and after the placing of the composition in the subterranean formation, the composition is used downhole, at least one of alone and in combination with other materials, as a drilling fluid, stimulation fluid, fracturing fluid, spotting fluid, clean-up fluid, production fluid, completion fluid, remedial treatment fluid, abandonment fluid, pill, acidizing fluid, cementing fluid, packer fluid, diverting fluid, or a combination thereof.

16. The method of claim 1 , wherein the placing of the composition in the subterranean formation comprises fracturing at least part of the subterranean material to form at least one subterranean fracture.

17. The method of claim 1 , wherein the composition further comprises a proppant, a resin-coated proppant, an encapsulated resin, or a combination thereof.

18. A method of treating a subterranean formation, the method comprising:
placing in the subterranean formation a composition comprising
at least one polymer selected from the group consisting of guar gum, a guar gum derivative, and a combination thereof,
at least one ion selected from the group consisting of an Fe 2+ ion, an Fe 3+ ion, and a combination thereof;
at least one ion-sequestering compound that is selected from the group consisting of sodium metasilicate, sodium orthosilicate, and sodium pyrosilicate, wherein the composition comprises about 0.000,000,001 wt % to about 30 wt % of the ion-sequestering compound; and

sequestering the ion from the polymer with the ion-sequestering compound.

Assignees

• Halliburton Energy Services Inc

Inventors

• Alwattari Ali
• Singh Dipti

Classifications

• C09K8/467

  containing additives for specific purposes · CPC title

• C04B28/04

  Portland cements · CPC title

• C09K8/887

  containing cross-linking agents · CPC title

• C09K8/82

  Oil-based compositions (C09K8/64 takes precedence) · CPC title

• C09K8/725

  Compositions containing polymers · CPC title