Integrated process for the production of bio-oil from sludge coming from a wastewater purification plant

Patent metadata

Field	Value
Publication number	US-9650275-B2
Application number	US-201214002321-A
Country	US
Kind code	B2
Filing date	Feb 24, 2012
Priority date	Mar 3, 2011
Publication date	May 16, 2017
Grant date	May 16, 2017

Abstract

Integrated process for the production of bio-oil from sludge coming from a wastewater purification plant comprising the following steps: (a) sending wastewater to said purification plant obtaining sludge; (b) subjecting the sludge obtained in said step (a) to liquefaction, obtaining a mixture Including an oily phase consisting of bio-oil, a solid phase and an aqueous phase; (c) sending the aqueous phase obtained in said step (b) to said purification plant. The bio-oil (or “bio-crude”) thus obtained can be advantageously used in the production of bio-fuels which can be used as such, or in a mixture with other automotive fuels. Otherwise, said bio-oil (or “bio-crude”) can be used as such (bio-fuel), or in a mixture with fossil fuels (combustible oil, coal, etc.), for the generation of electric energy or heat.

First claim

The invention claimed:

1. Integrated process for the production of bio-oil from sludge coming from a wastewater purification plant, comprising the following steps:
(a) sending wastewater to said purification plant obtaining sludge;
(b) directly subjecting the sludge obtained in said step (a) to liquefaction obtaining a mixture comprising an oily phase consisting of bio-oil, a solid phase and an aqueous phase; and
(c) sending the aqueous phase obtained in said step (b) to said purification plant.

2. Integrated process according to claim 1 , wherein said sludge is selected from primary sludge, biologic sludge produced in purification plants of civil and/or industrial wastewater, or mixtures thereof.

3. Integrated process according to claim 1 , wherein said sludge is used in a mixture with other materials selected from the group consisting of:
urban solid waste selected from organic material coming from the sorted waste collection, organic material selected from not sorted urban solid waste, or mixtures thereof; or mixtures of said organic material with pruning cut-offs and/or agricultural residue;
residue and/or scraps coming from agricultural and/or zootechnical activities;
residue and/or scraps coming from the agricultural/food industry;
residue and/or scraps coming from agricultural processes, from forestation and/or from silviculture; and
oily by-products such as oils and/or fats, coming from the preliminary treatment of wastewater;
mixtures thereof.

4. Integrated process according to claim 3 , wherein said sludge is used in a mixture with oily by-products coming from the preliminary treatment of wastewater.

5. Integrated process according to claim 3 , wherein said urban solid waste, and/or said residue and/or scraps coming from agricultural and/or zootechnical activities, and/or said residue and/or scraps coming from the agricultural/food industry, and/or said residue and/or scraps coming from agricultural processes, from forestation and/or from silviculture, or mixtures thereof, are treated by subjecting them to a preliminary grinding or size-sorting process before subjecting them to the liquefaction step (b).

6. Integrated process according to claim 1 , wherein said liquefaction step (b) is carried out at a temperature ranging from 150° C. to 350° C.

7. Integrated process according to claim 6 , wherein said liquefaction step (b) is carried out at a temperature ranging from 250° C. to 320° C.

8. Integrated process according to claim 1 , wherein said liquefaction step (b) is carried out at a pressure ranging from 5 bar to 170 bar.

9. Integrated process according to claim 8 , wherein said liquefaction step (b) is carried out at a pressure ranging from 35 bar to 120 bar.

10. Integrated process according to claim 1 , wherein said liquefaction step (b) is carried out for a time ranging from 5 minutes to 240 minutes.

11. Integrated process according to claim 10 , wherein said liquefaction step (b) is carried out for a time ranging from 15 minutes to 180 minutes.

12. Integrated process according to claim 1 , wherein said oily phase, said solid phase and said aqueous phase included in the mixture obtained in said step (b) are separated by gravitational separation, filtering, or centrifugation.

13. Integrated process for the production of bio-oil from sludge coming from a wastewater purification plant, consisting essentially of:
(a) sending wastewater to said purification plant obtaining sludge;
(b) subjecting the sludge obtained in said step (a) to liquefaction obtaining a mixture comprising an oily phase consisting of bio-oil, a solid phase and an aqueous phase; and
(c) sending the aqueous phase obtained in said step (b) to said purification plant.

Assignees

• Bosetti Aldo
• Bianchi Daniele
• Franzosi Giuliana
• Eni Spa

Inventors

• Bosetti Aldo
• Bianchi Daniele
• Franzosi Giuliana

Classifications

• C10G2300/208

  Sediments, e.g. bottom sediment and water or BSW · CPC title

• Y02W10/37

  using solar energy · CPC title

• C10G2300/1018

  of animal origin · CPC title

• C10G2300/1014

  of vegetal origin · CPC title

• C10G3/40

  Thermal non-catalytic treatment · CPC title