Method for producing metal hydride

Patent metadata

Field	Value
Publication number	US-9650247-B2
Application number	US-201415021533-A
Country	US
Kind code	B2
Filing date	Sep 25, 2014
Priority date	Sep 25, 2013
Publication date	May 16, 2017
Grant date	May 16, 2017

Abstract

A method for efficiently producing a high-purity metal hydride without contamination of other metals while initiating reaction rapidly is provided.
A method for producing a metal hydride from a metal selected from the group consisting of Group 2 metals and Group 3 metals comprising:
(A) charging the pressure resistant container with the metal, introducing hydrogen into the container, and heating the container to initiate reaction, wherein a gauge pressure (a) is set to 0.1 to 1.5 MPa, a heating temperature (b) is set to 50 to 250° C., and a product of the gauge pressure and the heating temperature, a×b, is set in the range of 20 to 100; (B) stopping the introduction of hydrogen to allow the reaction to proceed when the temperature in the reaction container is increased to a temperature higher by 10 to 100° C. than the heating temperature; (C) introducing hydrogen of 0.1 to 1.5 MPa to allow the reaction to proceed when the temperature in the reaction container is decreased to the temperature at which the introduction of the hydrogen has been stopped; and (D) repeating the steps (B) and (C) until an increase in temperature does not occur in the reaction container after the introduction of the hydrogen.

First claim

The invention claimed is:

1. A method for producing a metal hydride from a metal selected from the group consisting of Group 2 metals and Group 3 metals comprising:
(A) charging a pressure resistant container with the metal, introducing hydrogen into the container, and heating the container to initiate a reaction, wherein a gauge pressure (a) is set to 0.1 to 1.5 MPa, a heating temperature (b) is set to 50 to 250° C., and a product of the gauge pressure and the heating temperature, a×b, is set in the range of 20 to 100;
(B) stopping the introduction of hydrogen to allow the reaction to proceed when the temperature in the reaction container is increased to a temperature higher by 10 to 100° C. than the heating temperature;
(C) introducing hydrogen of 0.1 to 1.5 MPa to allow the reaction to proceed when the temperature in the reaction container is decreased to the temperature at which the introduction of hydrogen has been stopped; and
(D) repeating (B) and (C) until an increase in temperature does not occur in the reaction container after the introduction of the hydrogen.

2. The method for producing a metal hydride according to claim 1 , wherein an amount of hydrogen introduced in (A) and (C) is 0.002 to 0.2 of the theoretically required amount.

3. The method for producing a metal hydride according to claim 1 , wherein a maximum temperature in the reaction container in (A), (B), (C) and (D) is 800° C. or lower.

4. The method for producing a metal hydride according to claim 1 , wherein an average size of the metal as a raw material ranges from 0.1 mm to 300 mm.

5. The method for producing a metal hydride according to claim 1 , wherein said metal is a Group 2 metal.

6. The method for producing a metal hydride according to claim 1 , wherein said metal is a Group 3 metal.

7. The method for producing a metal hydride according to claim 1 , wherein said metal is selected from the group consisting of lanthanum, calcium, strontium, cerium, gadolinium, and yytrium.

8. The method for producing a metal hydride according to claim 1 , wherein said metal is selected from the group consisting of lanthanum, calcium, and strontium.

9. The method for producing a metal hydride according to claim 1 , wherein an average size of the metal as a raw material ranges from 0.5 mm to 200 mm.

10. The method for producing a metal hydride according to claim 1 , wherein an average size of the metal as a raw material ranges from 1 mm to 150 mm.

11. The method for producing metal hydride according to claim 1 , wherein in (A), the gauge pressure (a) is 1 to 1.3 MPa, the heating temperature (b) is 60 to 250° C. and the product (a×b) is 20 to 90.

12. The method for producing metal hydride according to claim 1 , wherein in (A), the gauge pressure (a) is 0.3 to 1.0 MPa, the heating temperature (b) is from 80 to 200° C., and the product (a×b) is 30 to 90.

13. The method for producing metal hydride according to claim 1 , comprising (B) stopping the introduction of hydrogen to allow the reaction to proceed when the temperature in the reaction container is increased to a temperature higher by 25 to 60° C. than the heating temperature.

Assignees

• Taiheiyo Cement Corp

Inventors

• Ishimoto Tetsuya
• Suzuki Shoji
• Matsui Katsumi
• Hatsumori Tomoki
• Tokoyoda Kazuhiko

Classifications

• C01B6/02

  Hydrides of transition elements; Addition complexes thereof · CPC title

• C01B6/04 Primary

  Hydrides of alkali metals, alkaline earth metals, beryllium or magnesium; Addition complexes thereof · CPC title