Process and apparatus for online rejuvenation of contaminated sulfolane solvent

Patent metadata

Field	Value
Publication number	US-9649638-B2
Application number	US-201313757733-A
Country	US
Kind code	B2
Filing date	Feb 1, 2013
Priority date	Apr 30, 2008
Publication date	May 16, 2017
Grant date	May 16, 2017

Abstract

A continuous online process for rejuvenating whole stream of contaminated lean sulfolane in an extraction system is provided. A rejuvenator is installed in the solvent: circulation loop to remove the contaminants continuously to keep the solvent clean, effective and less corrosive. The rejuvenator includes a high pressure vessel with a removable cover and a round rack with vertical stainless steel tubes fitted in the high pressure vessel. A magnetic bar is placed in each stainless steel tube. A screen cylinder is installed outside the ring of stainless steel tubes. As the contaminated sulfolane is passed through the rejuvenator, the rejuvenator picks up contaminants. The rejuvenator can be dissembled to remove the contaminants periodically. The rejuvenator is simple in construction, reliable in operation, and low in operation and maintenance costs. With this rejuvenator, the extraction system operates at high efficiency and high capacity without the dreaded corrosion.

First claim

What is claimed is:

1. A method of removing organic contaminants from a contaminated solvent stream that contains acids and acid byproducts and an organic solvent where the contaminated solvent stream flows through a system that includes equipment that comes into contact with the organic solvent which method comprises the steps of:
(a) exposing the acids and acid byproducts in the contaminated solvent stream which contain organic contaminants to the equipment thereby causing release of ferric ions from the equipment into the contaminated solvent stream whereby the ferric ions form paramagnetic corrosion products in the contaminated solvent stream;
(b) maintaining the contaminated solvent stream at conditions that cause the paramagnetic corrosion products to become occluded in the organic contaminants that comprise organic degradation products; and
(c) exposing the contaminated solvent stream to magnets which are located in a solvent rejuvenation apparatus and that attract and remove the organic contaminants, that are occluded with the paramagnetic corrosion products, from the contaminated solvent stream to yield a clean organic solvent stream, wherein the solvent rejuvenation apparatus comprises:
a high pressure vessel with a removable cover;
a rack with a plurality of stainless steel tubes fitted within the high pressure vessel, wherein a magnet is inserted into each of the plurality of stainless steel tubes;
a screen cylinder fitted in the rack at a center of the high pressure vessel, wherein the screen cylinder partially encloses the plurality of stainless steel tubes and wherein each stainless steel tube has an exterior surface that contacts the contaminated solvent stream and onto which the organic contaminants accumulate;
an inlet through which the contaminated solvent stream enters the high pressure vessel such that the contaminated solvent stream comes into direct communication with the plurality of stainless steel tubes without having to pass through the screen cylinder; and
an outlet through which rejuvenated clean solvent, subsequent to passing through the screen cylinder, exits the high pressure vessel and wherein each of the plurality of stainless steel tubes is separated from the outlet by the screen cylinder.

2. The method of claim 1 wherein the ferric ions react with sulfur, oxygen and/or water to form paramagnetic materials.

3. The method of claim 2 wherein the paramagnetic materials are selected from the group consisting of FeS, FeO, Fe(OH) 2 and combinations thereof.

4. The method of claim 1 wherein the solvent comprises sulfolane.

5. The method of claim 1 wherein the contaminated solvent stream is cooled prior to being exposed to the magnets in step (c).

6. The method of claim 1 further comprising the step of establishing a closed organic solvent circulation loop that includes the equipment.

7. A method of removing organic contaminants from a contaminated solvent stream that contains acids and acid byproducts and a solvent where the contaminated solvent stream, which comprises an organic solvent, flows through a system that includes equipment that comes into contact with the solvent which method comprises the steps of:
(a) exposing the acids and acid byproducts in the contaminated solvent stream which contain organic contaminants to the equipment thereby causing release of ferric ions from the equipment into the contaminated solvent stream whereby the ferric ions form paramagnetic corrosion products in the contaminated solvent stream;
(b) maintaining the contaminated solvent stream at conditions that cause the paramagnetic corrosion products to become occluded in the organic contaminants that comprise organic degradation products; and
(c) exposing the contaminated solvent stream to removable magnets, that are located in a device for removing organic contaminants from the contaminated solvent stream, and that attract and remove the organic contaminants, that are occluded with the paramagnetic corrosion products, from the contaminated solvent stream to yield a clean solvent stream, wherein the device for removing organic contaminants from the contaminated solvent stream comprises:
a vessel having a removable cover and defining an interior region and configured with an inlet through which the contaminated solvent stream enters the interior region and an outlet through which the clean solvent stream exits the interior region;
a plurality of stainless steel tubes positioned within the interior region wherein the plurality of stainless steel tubes enclose the removable magnets therein and wherein each stainless steel tubes has an exterior surface that contacts the contaminated solvent stream and onto which the organic contaminants accumlate; and
a screen positioned between the plurality of stainless steel tubes and the outlet, wherein the contaminated solvent stream is first channeled to contact the plurality of stainless steel tubes, which attract the organic contaminants occluded with the paramagnetic corrosion products that become adhered to the plurality of stainless steel tubes, to yield the clean solvent stream that passes through the screen and exits through the outlet and characterized in that accumulated organic contaminants occluded with the paramagnetic corrosion products drop off the plurality of stainless steel tubes when the magnets are removed therefrom.

8. The method of claim 7 wherein the screen is configured to partially enclose the plurality of stainless steel tubes.

9. The method of claim 8 wherein the screen has a configuration defining a hollow interior, wherein the plurality of stainless steel tubes is secured to a rack that is supported by the screen such that a lower portion of the plurality of stainless steel tubes is positioned within the hollow interior.

10. The method of claim 7 wherein the organic solvent stream comprises sulfolane.

11. The method of claim 7 wherein the contaminated solvent stream is cooled prior to being exposed to the magnet in step (c).

12. The method of claim 7 further comprising the step of establishing a closed organic solvent circulation loop that includes the equipment.

13. A method of removing polymeric contaminant products from an organic solvent circuit which includes process equipment that is subject to corrosion by acids and acidic byproducts, said method comprises the steps of:
(a) passing an organic solvent stream through the process equipment whereupon acids and acid byproducts in the organic solvent stream come into contact with the process equipment thereby releasing paramagnetic ferric ions into the organic solvent stream wherein the ferric ions react with sulfur, oxygen and/or water in the organic solvent stream to form paramagnetic corrosion particles;
(b) cooling the organic solvent stream to cause the paramagnetic corrosion particles to occlude into the polymeric contaminant products in a cooled organic solvent stream and thereby form paramagnetic polymeric contaminant products in the cooled organic solvent stream; and
(c) positioning one or more magnets in the cooled organic solvent stream such that the paramagnetic polymeric contaminant products are attracted by and adheres to the one or more magnets thereby removing the paramagnetic polymeric contaminant from the cooled organic solvent stream, wherein the one or more magnets are inserted inside one or more tubes with an exterior surface that contacts the cooled organic solvent stream and onto which the paramagnetic polymeric contaminant products accumulate.

14. The method of claim 13 wherein the organic solvent comprises sulfolane.

15. The method of claim 13 furth

Assignees

• Amt Int Inc
• Cpc Corp Taiwan

Inventors

• Yen Ping-Wen
• Ho Yuh-Sheve
• Chiu Hung-Tzu
• Hwu Chung-Jong
• Chang June-Cheng
• Lin Tzong-Bin
• Yang Tsoung Y
• Hong Cheng-Tsung
• Shen Hung-Chung

Classifications

• B01D35/06

  Filters making use of electricity or magnetism (ultrafiltration, microfiltration B01D61/14; electrodialysis, electro-osmosis B01D61/42; devices comprising filters and magnetic separators B03C1/30) · CPC title

• B01D29/23 Primary

  arranged for outward flow filtration · CPC title

• B03C1/015 Primary

  by chemical treatment imparting magnetic properties to the material to be separated, e.g. roasting, reduction, oxidation · CPC title

• B03C1/0332

  using permanent magnets · CPC title

• C10G21/28

  Recovery of used solvent · CPC title