Continuous solid-state polymerisation device and method

Patent metadata

Field	Value
Publication number	US-9649616-B2
Application number	US-201314899203-A
Country	US
Kind code	B2
Filing date	Oct 22, 2013
Priority date	Jun 21, 2013
Publication date	May 16, 2017
Grant date	May 16, 2017

Abstract

The continuous solid-state polymerization device of the present invention comprises: a feeder for continuously introducing a prepolymer; a horizontal reactor which is connected via a first connecting part to the feeder and receives the prepolymer from the feeder so as to subject same to solid-state polymerization, wherein the reactor itself is rotated; a stirring device which comprises a stirring shaft rotating inside the horizontal reactor, in the direction opposite to that of the rotational axis of the horizontal reactor, and comprises stirring blades joined vertically to the stirring shaft; and a chamber which is connected via a second connecting part to the horizontal reactor and, once the solid-state polymerization has been completed, receives the resulting polymer discharged from the horizontal reactor, and, here, the feeder, the horizontal reactor and the chamber are in a vacuum state. The continuous solid-state polymerization device prevents the formation of prepolymer stagnation zones, and allows solid-state polymerization to take place continuously in the vacuum state without any inert gas.

First claim

The invention claimed is:

1. A continuous solid-state polymerization apparatus comprising:
a feeder for continuously introducing prepolymers;
a rotatable transverse reactor connected to the feeder via a first connector and receiving the prepolymers from the feeder to perform solid-state polymerization;
a stirring device including a stirring shaft rotating in a direction opposite a rotational axis of the transverse reactor within the transverse reactor and a stirring vane vertically attached to the stirring shaft; and
a chamber connected to the transverse reactor via a second connector and receiving and discharging solid-state polymerized polymers from the transverse reactor,
wherein the transverse reactor has a release coating film formed on an inner wall thereof, and the feeder, the transverse reactor and the chamber are under a vacuum.

2. The continuous solid-state polymerization apparatus according to claim 1 , comprising: a sealing member preventing leakage/inflow of gas and liquid from/into the first and second connectors.

3. The continuous solid-state polymerization apparatus according to claim 2 , wherein the sealing member is a magnetic fluid seal.

4. The continuous solid-state polymerization apparatus according to claim 1 , wherein the stirring vane is a disk type.

5. The continuous solid-state polymerization apparatus according to claim 1 , wherein a vacuum pump is connected to the chamber.

6. The continuous solid-state polymerization apparatus according to claim 1 , wherein a vacuum pump is further connected to the feeder.

7. The continuous solid-state polymerization apparatus according to claim 1 , wherein the transverse reactor comprises a pre-heating zone, a main-heating zone, and a cooling zone.

8. The continuous solid-state polymerization apparatus according to claim 1 , further comprising:
a first hopper receiving the prepolymers from outside and maintained at atmospheric pressure; and
a second hopper connected to the first hopper and receiving the prepolymers from the first hopper under atmospheric pressure and transferring the prepolymers to the feeder under a vacuum.

9. The continuous solid-state polymerization apparatus according to claim 1 , further comprising:
a third hopper connected to the chamber and receiving the polymers from the chamber under a vacuum and discharging the polymers outside under atmospheric pressure.

10. The continuous solid-state polymerization apparatus according to claim 1 , wherein the prepolymer is a polymer having an intrinsic viscosity (IV) of about 0.09 dL/g to about 0.49 dL/g.

11. The continuous solid-state polymerization apparatus according to claim 1 , the solid-state polymerized polymer has an intrinsic viscosity (IV) of about 0.5 dL/g to about 1.5 dL/g.

12. A solid-state polymerization method using the continuous solid-state polymerization apparatus according to claim 1 , the method comprising:
introducing the prepolymers into the feeder;
solid-state polymerizing the introduced prepolymers in the transverse reactor; and
discharging the solid-state polymerized polymers to the chamber,
wherein the solid-state polymerization is performed while stirring by the transverse reactor and the stirring device, and the above steps are continuously performed.

13. The solid-state polymerization method according to claim 12 , wherein the solid-state polymerization is performed under a pressure of about 0.1 torr to about 100 torr.

Assignees

• Samsung Sdi Co Ltd
• Lotte Advanced Mat Co Ltd

Inventors

• Im Sang Kyun
• Jun Suk Min
• Bae Shin Hyo
• Kwon So Young
• Lee Eun Ju
• Jin Young Sub
• Park Kyoung Kyun

Classifications

• C08G63/80 Primary

  Solid-state polycondensation · CPC title

• B01J2219/00159

  controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling · CPC title

• B01J19/0073

  Sealings (sealings for pressure vessels per se F16J15/00) · CPC title

• Y02P20/149

  Cross-Sectional Technologies · mapped topic

• B01F9/08

  Operations & Transport · mapped topic