Perovskite with an ovlerlayer SCR component as an ammonia oxidation catalyst and a system for exhaust emission control on diesel engines

Patent metadata

Field	Value
Publication number	US-9649596-B2
Application number	US-201514788839-A
Country	US
Kind code	B2
Filing date	Jul 1, 2015
Priority date	Jul 2, 2014
Publication date	May 16, 2017
Grant date	May 16, 2017

Abstract

An ammonia slip control catalyst having a layer containing perovskite and a separate layer containing an SCR catalyst is described. The ammonia slip catalyst can have two stacked layers, with the top overlayer containing an SCR catalyst, and the bottom layer containing a perovskite. The ammonia slip catalyst can alternatively be arranged in sequential layers, with the SCR catalyst being upstream in the flow of exhaust gas relative to the perovskite. A system comprising the ammonia slip catalyst upstream of a PGM-containing ammonia oxidation catalyst and methods of using the system are described. The system allows for high ammonia oxidation with good nitrogen selectivity. Methods of making and using the ammonia slip catalyst to reduce ammonia slip and selectively convert ammonia to N 2 are described.

First claim

What is claimed is:

1. A catalyst article comprising:
(a) a wall flow monolith having an inlet face end and an outlet face and an axis of gas flow from said inlet face to said outlet face;
(b) a first composition comprising a layer A comprising a first SCR catalyst and a layer B comprising a perovskite, wherein layer A is arranged to contact an exhaust gas before layer B; and
(c) a second composition comprising layer C comprising a second SCR catalyst and layer D comprising a precious group metal, wherein layer Cis arranged to contact an exhaust gas before layer D;
wherein the first and second compositions are disposed within a portion of the wall flow monolith and in series along the axis, and wherein said first composition is disposed proximal to the inlet face, and said second zone is disposed proximal to the outlet face.

2. The catalyst article of claim 1 , wherein the first SCR catalyst and the second SCR catalyst are the same SCR catalyst.

3. The catalyst article of claim 1 , wherein the first SCR catalyst and the second SCR catalyst are different SCR catalysts.

4. The catalyst article of claim 1 , wherein layer A is an overlayer located over layer B.

5. The catalyst article of claim 1 , wherein layer A is supported on a first support material and layer B is supported on a second support material.

6. The catalyst article of claim 1 , wherein the first SCR catalyst comprises an oxide of a base metal, a molecular sieve, a metal exchanged molecular sieve or a mixture thereof.

7. The catalyst article of claim 6 , wherein the base metal is selected from the group consisting of cerium (Ce), chromium (Cr), cobalt (Co), copper (Cu), iron (Fe), manganese (Mn), molybdenum (Mo), nickel (Ni), tungsten (W) and vanadium (V), and mixtures thereof.

8. The catalyst article of claim 1 , wherein the first SCR catalyst comprises a metal exchanged molecular sieve and the metal is selected from the group consisting of calcium, cobalt, copper, gallium, indium, iron, nickel, silver and tin.

9. The catalyst article of claim 1 , wherein the first SCR catalyst comprises a molecular sieve or a metal exchanged molecular sieve.

10. The catalyst article of claim 9 , wherein the molecular sieve or the metal exchanged molecular sieve is small pore, medium pore or large pore sieve or a mixture thereof.

11. The catalyst article of claim 1 , wherein the perovskite has the formula ABO 3 , where A comprises at least one of calcium (Ca), barium (Ba), bismuth (Bi), cadmium (Cd), cerium (Ce), copper (Cu), lanthanum (La), lead (Pb), neodymium (Nd), nickel (Ni), strontium (Sr), and yttrium (Y), and B comprises at least one of aluminum (Al), cerium (Ce), chromium (Cr), cobalt (Co), iron (Fe), manganese (Mn), niobium (Nb), tin (Sn), titanium (Ti) and zirconium (Zr).

12. The catalyst article of claim 1 , wherein the perovskite has the formula LaCoO 3 , LaMnO 3 , La Y Sr (1-Y) CoO 3 , or La Y Sr (1-y) MnO 3 , where Y=0.6 to 1.0, inclusive.

13. The catalyst article of claim 1 , wherein the perovskite has the formula La Y Sr (1-Y) CoO 3 , where Y=0.6 to 1.0, inclusive, and the first SCR catalyst comprises a copper or iron exchanged molecular sieve.

14. The catalyst article of claim 1 , wherein the perovskite is present at a concentration of about 0.2 to about 5.0 g/in 3 .

15. The catalyst article of claim 1 , wherein the first SCR catalyst is present at a concentration of about 0.2 to about 5.0 g/in 3 .

16. The catalyst article of claim 1 , wherein the first composition has at least 70% N 2 selectivity at a temperature between about 250° C. and about 650° C.

17. The catalyst article of claim 1 , wherein the first composition has at least 80% N 2 selectivity at a temperature between about 250° C. and about 650° C.

18. An engine exhaust gas treatment system comprising: (a) a catalyst article according to claim 1 ; and (b) a source of ammonia or urea upstream of the catalytic article.

19. A method for treating an exhaust gas comprising contacting an exhaust gas stream having a concentration of NOx with a nitrogenous reductant at a temperature of about 150° C. to about 750° C. in the presence of a catalyst article according to claim 1 .

20. A method for reducing NOx in an exhaust gas comprising contacting the gas with a catalyst article according to claim 1 for a time and temperature sufficient to reduce the level of NOx compounds in the gas.

Assignees

• Johnson Matthey Plc

Inventors

• Chang Hsiao-Lan
• Chen Hai-Ying

Classifications

• B01J35/56

  Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional [3D] monoliths · CPC title

• B01J23/002 Primary

  Mixed oxides other than spinels, e.g. perovskite · CPC title

• B01J2229/186

  not in framework positions · CPC title

• F01N2510/063

  zeolites · CPC title

• B01D2255/20746

  Cobalt · CPC title