Gel polymer composite electrolyte, polymer lithium ion battery comprising the gel polymer composite electrolyte and methods of preparing the same

Patent metadata

Field	Value
Publication number	US-9647293-B2
Application number	US-201314414868-A
Country	US
Kind code	B2
Filing date	Aug 28, 2013
Priority date	Aug 28, 2012
Publication date	May 9, 2017
Grant date	May 9, 2017

Abstract

A gel polymer composite electrolyte, a polymer lithium ion battery comprising the gel polymer composite electrolyte and methods of preparing the polymer lithium ion battery are provided. The gel polymer composite electrolyte is formed by swelling after a polymer membrane absorbs an electrolyte, wherein the polymer membrane is formed by thermocuring a polymer mixture comprising an acrylic emulsion, water and ammonia water, and the acrylic emulsion has a glass transition temperature ranging from about −30° C. to about 50° C.

First claim

What is claimed is:

1. A gel polymer composite electrolyte comprising:
a polymer membrane comprising a three-dimensional network of cross-linked acrylic emulsion, wherein the acrylic emulsion having a glass transition temperature ranging from about −30° C. to about 50° C. is cross-linked in the presence of water and ammonia water;
an electrolyte absorbed in the polymer membrane, wherein the electrolyte comprises a lithium salt and an organic solvent; the organic solvent is selected from the group consisting of ethylene carbonate, propylene carbonate, diethyl carbonate, dimethyl carbonate, methyl ethyl carbonate, vinylene carbonate, or combinations thereof; and the concentration of the lithium salt ranges from about 0.8 mol/L to about 1.5 mol/L.

2. The gel polymer composite electrolyte of claim 1 , wherein the acrylic emulsion has a glass transition temperature ranging from about −18° C. to about 38° C.

3. The gel polymer composite electrolyte of claim 1 , wherein a volumetric ratio of the acrylic emulsion to the water is about 100:5 to about 100:50, and the amount of ammonia water ranges from about 0.001 wt % to about 10 wt %, based on the total weight of the acrylic emulsion and the water.

4. The gel polymer composite electrolyte of claim 1 , wherein the lithium salt is selected from the group consisting of lithium hexafluorophosphate, lithium perchlorate, and lithium tetrafluoroborate.

5. The gel polymer composite electrolyte of claim 1 , which connects a positive electrode and a negative electrode of a battery.

Assignees

• Byd Co Ltd

Inventors

• Shan Jun
• Liu Ronghua
• Jin Lina

Classifications

• C08F220/18

  with acrylic or methacrylic acids · CPC title

• H01M2300/0082

  Organic polymers · CPC title

• Y02E60/122

  Cross-Sectional Technologies · mapped topic

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M10/058

  Construction or manufacture · CPC title