System and method for generating power and enhanced oil recovery

Patent metadata

Field	Value
Publication number	US-9647286-B2
Application number	US-201213678942-A
Country	US
Kind code	B2
Filing date	Nov 16, 2012
Priority date	Nov 16, 2011
Publication date	May 9, 2017
Grant date	May 9, 2017

Abstract

A method for producing a purified carbon dioxide product suitable for EOR and surplus electricity uses a vaporous hydrocarbon feed and a SOFC system. A SOFC system includes a condensate removal system, an acid gas removal system, a hydrodesulfurization system, a sorption bed system, a pre-reformer, a solid oxide fuel cell, a CO2 separations system and a CO2 dehydration system operable to form the purified carbon dioxide product, where the SOFC system is operable to produce surplus electricity from the electricity produced by the solid oxide fuel cell. A method of operating the pre-reformer to maximize the internal reforming capacity of a downstream solid oxide fuel cell uses a pre-reformer fluidly coupled on the upstream side of a solid oxide fuel cell. A method of enhancing hydrocarbon fluid recovery from a hydrocarbon-bearing formation using a SOFC system.

First claim

What is claimed is:

1. A method for producing a purified carbon dioxide product suitable for enhanced oil recovery (EOR) and surplus electricity from a vaporous hydrocarbon feed using a solid oxide fuel cell (SOFC) system, the method comprising the steps of:
introducing the vaporous hydrocarbon feed into the SOFC system;
introducing steam into a pre-reformer of the SOFC system; and
operating the SOFC system such that a desulfurized process gas forms and passes into the pre-reformer; a reformed process gas forms in the pre-reformer by converting non-methane alkanes in the desulfurized process gas into methane and carbon oxides in the presence of a pre-reforming catalyst; the reformed process gas passes from the pre-reformer into a solid oxide fuel cell; gas egressing from an anode side of the solid oxide fuel cell is improved by a water-gas shift reactor coupled to the anode side of the solid oxide fuel cell to receive anode off-gas as a feed, and configured to increase the percent composition of carbon dioxide in the gas egressing from the solid oxide fuel cell; and the purified carbon dioxide product and surplus electricity are produced;

where the anode side receives methane-rich reformed process gas as a feed directly from the pre-reformer, the solid oxide fuel cell operable to produce electricity through internal reforming,
where the SOFC system is operable to both receive the vaporous hydrocarbon feed and produce the desulfurized process gas, the purified carbon dioxide product and surplus electricity, and
where the SOFC system includes the pre-reformer that fluidly couples directly to the anode side of the solid oxide fuel cell and is operable to both receive the desulfurized process gas and convert the non-methane alkanes using steam in the presence of an active metal pre-reforming catalyst into methane and carbon oxides, and the solid oxide fuel cell that is operable to produce electricity.

2. The method of claim 1 where the vaporous hydrocarbon feed comprises associated gas.

3. The method of claim 1 where introduced steam is superheated steam and has a temperature in the range of from about 250° C. to about 500° C. and a pressure in a range of from about 8 bars to about 12 bars.

4. The method of claim 1 where the desulfurized process gas has a temperature in a range of from about 200° C. to about 450° C.

5. The method of claim 1 where a steam-to-carbon ratio (SCR) of the introduced steam to the desulfurized process gas is in a range of from about 1.5 to about 3.0.

6. The method of claim 1 where a methane selectivity ratio (MSR) of the reformed process gas is in a range of from about 0.90 to about 0.99.

7. The method of claim 1 where the desulfurized process gas comprises methane in a range of from about 51 to about 66 mole percent of the composition and non-methane alkanes in a range of from about 33 to about 45 mole percent of the composition, each on a dry basis of the desulfurized process gas.

8. The method of claim 7 where the desulfurized process gas has a mole percent ratio of methane to non-methane alkanes in a range of from about 1.0 to about 2.0.

9. The method of claim 1 where the reformed process gas comprises methane in a range of from about 78 to about 88 mole percent of the composition, carbon oxides in a range of from about 9 to about 12 mole percent of the composition, and hydrogen in a range of from about 0.5 to about 10 mole percent of the composition, each on a dry basis of the reformed process gas.

10. The method of claim 9 where the reformed process gas is substantially free of non-methane alkanes on a mole basis.

11. The method of claim 9 where the reformed process gas is substantially free of sulfur and sulfur-bearing compounds on a mole basis.

12. The method of claim 1 where the purified carbon dioxide product is substantially free of non-carbon dioxide components on a mole basis.

13. The method of claim 1 further comprising the step of:
operating the SOFC system such that a carbon dioxide-rich gas forms in an acid gas removal system and passes into a CO2 dehydration system,

where the SOFC system further includes the acid gas removal system that fluidly couples to an upstream side of the pre-reformer and is operable to form a carbon dioxide-rich gas, and the CO2 dehydration system that fluidly couples to both a downstream side of the pre-reformer and the acid gas removal system.

14. The method of claim 1 further comprising the step of:
operating the SOFC system such that a hydrogen-rich gas forms in a CO2 separations system and passing a portion of the hydrogen-rich gas to a hydrodesulfurization system;

where the SOFC system further includes a CO2 separations system that fluidly couples to a downstream side of the pre-reformer and is operable to form a hydrogen-rich gas, and the hydrodesulfurization system that fluidly couples to both the upstream side of the pre-reformer and the CO2 separations system.

Assignees

• Saudi Arabian Oil Co

Inventors

• Jamal Aqil
• Pham Thang
• Harale Aadesh

Classifications

• Y02E60/50

  Fuel cells · CPC title

• E21B43/40

  Separation associated with re-injection of separated materials {(E21B43/385 takes precedence)} · CPC title

• E21B43/34

  Arrangements for separating materials produced by the well · CPC title

• H01M8/04097

  with recycling of the reactants (H01M8/04119, H01M8/04104 take precedence) · CPC title

• C01B3/38

  using catalysts · CPC title