Nonaqueous electrolyte secondary battery

Patent metadata

Field	Value
Publication number	US-9647264-B2
Application number	US-201214423571-A
Country	US
Kind code	B2
Filing date	Sep 4, 2012
Priority date	Sep 4, 2012
Publication date	May 9, 2017
Grant date	May 9, 2017

Abstract

A nonaqueous electrolyte secondary battery capable of achieving a high battery performance (e.g., high energy density and high power density) is provided. The nonaqueous electrolyte secondary battery is equipped with a positive electrode having a positive electrode current collector and a positive electrode active material layer that is formed on the positive electrode current collector and includes at least a positive electrode active material and a conductive material. The positive electrode active material includes a lithium-transition metal composite oxide. The conductive material includes a lithium phosphate compound coated, on at least part of the surface thereof, with a conductive carbon, and a proportion of the conductive material in the positive electrode active material layer is 10% by mass or less.

First claim

The invention claimed is:

1. A nonaqueous electrolyte secondary battery comprising an electrode assembly having a positive electrode and a negative electrode, and a nonaqueous electrolyte, wherein
the positive electrode has a positive electrode current collector and a positive electrode active material layer that is formed on the positive electrode current collector and includes at least a positive electrode active material and a conductive material,
the positive electrode active material includes at least a lithium-transition metal composite oxide,
the conductive material includes a lithium phosphate compound coated, on at least part of the surface thereof, with conductive carbon,
the lithium phosphate compound includes at least lithium iron phosphate,
the conductive carbon includes at least carbon black,
the conductive carbon is coated in an amount, per 100 parts by mass of the lithium phosphate compound, of from 40 parts by mass to 80 parts by mass,
the conductive carbon-coated lithium phosphate compound is configured to suppress direct contact between the lithium phosphate compound and the positive electrode active material, and
a proportion of the conductive material in the positive electrode active material layer is from 1% by mass to 10% by mass.

2. The nonaqueous electrolyte secondary battery according to claim 1 , wherein a proportion of the conductive carbon-coated lithium phosphate compound in the conductive material is from 20% by mass to 70% by mass.

3. The nonaqueous electrolyte secondary battery according to claim 1 , wherein the lithium phosphate compound has an average particle size for primary particles thereof, as determined by electron microscopy, of from 50 nm to 200 nm.

4. The nonaqueous electrolyte secondary battery according to claim 1 , wherein the conductive carbon has an average particle size for primary particles thereof, as determined by electron microscopy, of from 30 nm to 50 nm.

5. The nonaqueous electrolyte secondary battery according to claim 1 , wherein the positive electrode active material includes at least a lithium nickel cobalt manganese composite oxide having a layered structure.

6. The nonaqueous electrolyte secondary battery according to claim 1 , wherein the conductive carbon-coated lithium phosphate compound and the positive electrode active material are both in a particulate form, and
an average particle size for secondary particles of the conductive carbon-coated lithium phosphate compound is smaller than that of the positive electrode active material.

7. The nonaqueous electrolyte secondary battery according to claim 6 , wherein the average particle size for secondary particles of the conductive carbon-coated lithium phosphate compound is from 0.05 to 1 μm.

8. A vehicle comprising the nonaqueous electrolyte secondary battery according to claim 1 .

Assignees

• Mizuno Tomoyuki
• Toyota Motor Co Ltd

Inventors

• Mizuno Tomoyuki

Classifications

• H01M4/131 Primary

  Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx · CPC title

• H01M4/625

  Carbon or graphite · CPC title

• H01M4/525

  of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy · CPC title

• H01M4/624

  Electric conductive fillers · CPC title

• H01M4/505

  of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy · CPC title