Electric storage device
US-9455091-B2 · Sep 27, 2016 · US
US9647256B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9647256-B2 |
| Application number | US-201414650441-A |
| Country | US |
| Kind code | B2 |
| Filing date | Aug 21, 2014 |
| Priority date | Oct 15, 2013 |
| Publication date | May 9, 2017 |
| Grant date | May 9, 2017 |
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Provided is a battery in which an area density S (mg/cm 2 ) of a positive electrode active material layer is 27 mg/cm 2 or greater, and a porous film included in a separator has a structure satisfying the following Expressions. 0.04≦ Ri ≦−0.07 L −0.09× S +4.99 Ri=τ 2 L/ε′ ε′=[{( L ×ε/100)− Rz ×0.46/3}/ L ]×100 τ={(1.216×ε′ Td ×10 −4 )/ L} 0.5 (Expressions)
Opening claim text (preview).
The invention claimed is: 1. A battery, comprising: a positive electrode that includes a positive electrode current collector, and a positive electrode active material layer which includes a positive electrode active material and is provided on both surfaces of the positive electrode current collector; a negative electrode; a separator that includes at least a porous film; and an electrolyte, wherein the positive electrode active material includes a positive electrode material including a lithium cobalt composite oxide which has a layered structure and includes at least lithium and cobalt, an area density S (mg/cm 2 ) of the positive electrode active material layer is 27 mg/cm 2 or greater, and the porous film satisfies the following Expressions: 0.04≦ Ri≦− 0.07 L− 0.09× S+ 4.99 Ri=τ 2 L/ε′ ε′=[{( L×ε/ 100)− Rz× 0.46/3}/ L]× 100 τ={(1.216×ε′ Td× 10 −4 )/ L} 0.5 (Expressions) [provided that, Ri: a film leakage resistance (μm), L: a film thickness (μm), τ: a tortuosity factor, T: air permeability (sec/100 cc), d: a pore size (nm), Rz: a surface roughness maximum height (the sum of values of a front surface and a rear surface) (μm), ε: porosity (%), ε′: corrected porosity (%), and S: the area density of the positive electrode active material layer (mg/cm 2 )]. 2. The battery according to claim 1 , wherein the electrolyte includes an electrolyte solution and a polymer compound, and the electrolyte is a gel-type electrolyte in which the electrolyte solution is retained by the polymer compound. 3. The battery according to claim 2 , wherein the electrolyte further includes particles. 4. The battery according to claim 1 , wherein the area density S (mg/cm 2 ) of the positive electrode active material layer is 51 mg/cm 2 or less. 5. The battery according to claim 1 , wherein the thickness of the separator is 3 μm to 17 μm. 6. The battery according to claim 1 , wherein the positive electrode material is a coating particle that further includes a coating layer provided at least on a part of a surface of a particle of the lithium cobalt composite oxide. 7. The battery according to claim 1 , wherein the lithium cobalt composite oxide is at least one kind of a lithium cobalt composite oxide expressed by General Formula (Chem. 1): Li p Co (1-q) M1 q O (2-y) X z (Chem. 1) (In Formula, M1 represents at least one kind excluding cobalt (Co) among elements selected from Group 2 to Group 15, and X represents at least one kind excluding oxygen (O) among elements in Group 16 and elements in Group 17, and p, q, y, and z are values in ranges of 0.9≦p≦1.1, 0≦q<0.5, −0.10≦y≦0.20, and 0≦z≦0.1). 8. The battery according to claim 1 , wherein the separator further includes a surface layer which is provided at least on one main surface of the porous film and which includes particles and a resin. 9. The battery according to claim 1 , wherein the porous film is a polyolefin resin film. 10. The battery according to claim 1 , wherein the thickness of the separator is −0.0873S 2 +6.9788S−122.66 μm or less. 11. The battery according to claim 1 , wherein the positive electrode, the negative electrode, the separator, and the electrolyte are accommodated in a film-shaped exterior packaging member. 12. The battery according to claim 1 , wherein the open-circuit voltage in a fully charged state per a pair of the positive electrode and the negative electrode is 4.25 V or higher. 13. A battery pack, comprising: the battery according to claim 1 ; a control unit that controls the battery; and an exterior packaging member in which the battery is accommodated. 14. An electronic apparatus, comprising: the battery according to claim 1 , wherein electric power is supplied from the battery. 15. An electrically driven vehicle, comprising: the battery according to claim 1 ; a converting device to which electric power is supplied from the battery, and which converts the electric power to a driving force of a vehicle; and a control device that performs information processing relating to vehicle control on the basis of information relating to the battery. 16. An electrical storage device, comprising: the battery according to claim 1 , wherein the electrical storage device supplies electric power to an electronic apparatus that is connected to the battery. 17. The electrical storage device according to claim 16 , further comprising: a power information control device that transmits and receives a signal to and from other apparatuses through a network, wherein charging and discharging control of the battery is performed on the basis of information that is received by the power information control device. 18. A power system, wherein electric power is supplied from the battery according to claim 1 , or electric power is supplied to the battery from a power generating device or a power network.
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