Lead-free piezoelectric material
US-2015372221-A1 · Dec 24, 2015 · US
US9647197B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9647197-B2 |
| Application number | US-201313926347-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jun 25, 2013 |
| Priority date | Jul 26, 2012 |
| Publication date | May 9, 2017 |
| Grant date | May 9, 2017 |
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There is provided a piezoelectric ceramics, including a perovskite compound of a non-stoichiometric composition represented by a composition formula (K x Na 1-x ) y (Nb 1-z Ta z )O 3 (0<x≦1, 0<y<1, 0≦z≦0.5); and a sintering aid which includes an oxide containing K, Co, and Ta.
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What is claimed is: 1. A piezoelectric ceramic comprising: a perovskite compound of a non-stoichiometric composition represented by a composition formula (K x Na 1-x ) y (Nb 1-z Ta z )O 3 (0<x≦1, 0<y<1, 0<z≦0.5); and a sintering aid which includes an oxide containing K, Co, and Ta. 2. A piezoelectric ceramic comprising: a perovskite compound of a non-stoichiometric composition represented by a composition formula (K x Na 1-x ) y (Nb 1-z Ta z )O 3 (0<x≦1, 0<y<1, 0≦z≦0.5); and a sintering aid which includes an oxide containing K, Co, and Ta; wherein, in the sintering aid, a molar ratio of K to a total number of moles of K, Co, and Ta is not more than four-thirteenths. 3. A piezoelectric ceramic comprising: a perovskite compound of a non-stoichiometric composition represented by a composition formula (K x Na 1-x ) y (Nb 1-z Ta z )O 3 (0<x≦1, 0<y<1, 0≦z≦0.5); and a sintering aid which includes an oxide containing K, Co, and Ta; wherein, in the sintering aid, a molar ratio of Co to a total number of moles of K, Co, and Ta is not more than one-half. 4. The piezoelectric ceramic according to claim 3 ; wherein, in the sintering aid, a molar ratio of Co to a total number of moles of K, Co, and Ta is not more than three-tenths. 5. The piezoelectric ceramic according to claim 1 ; wherein, in the sintering aid, a molar ratio of Ta to a total number of moles of K, Co, and Ta is not less than three-tenths. 6. A method for manufacturing a piezoelectric ceramic, comprising: preparing a main component to form a perovskite compound of a non-stoichiometric composition represented by a composition formula (K x Na 1-x ) y (Nb 1-z Ta z )O 3 (0<x≦1, 0<y<1, 0<z≦0.5); preparing a sintering aid which includes an oxide containing K, Co, and Ta; preparing a raw material mixture by blending the main component to form the perovskite compound of the non-stoichiometric composition and the sintering aid; molding the raw material mixture in a predetermined shape; and performing sintering of the molded raw material mixture. 7. The method for producing the piezoelectric ceramic according to claim 6 ; wherein, in the sintering aid, a molar ratio of K to a total number of moles of K, Co, and Ta is not more than four-thirteenths. 8. The method for producing the piezoelectric ceramic according to claim 6 ; wherein, in the sintering aid, a molar ratio of Co to a total number of moles of K, Co, and Ta is not more than one-half. 9. The method for producing the piezoelectric ceramic according to claim 6 ; wherein, in the sintering aid, a molar ratio of Co to a total number of moles of K, Co, and Ta is not more than three-tenths. 10. The method for producing the piezoelectric ceramic according to claim 6 ; wherein, in the sintering aid, a molar ratio of Ta to a total number of moles of K, Co, and Ta is not less than three-tenths.
Compounds containing niobium, with or without oxygen or hydrogen, and containing two or more other elements · CPC title
Pressing at temperatures other than sintering temperatures · CPC title
Alkali metal oxides or oxide-forming salts thereof · CPC title
Solid density · CPC title
characterised by the treatment temperature · CPC title
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