Electrophotographic photosensitive member and manufacturing method thereof, process cartridge and electrophotographic apparatus, and phthalocyanine crystal and manufacturing method thereof

Patent metadata

Field	Value
Publication number	US-9645515-B2
Application number	US-201514689341-A
Country	US
Kind code	B2
Filing date	Apr 17, 2015
Priority date	Apr 30, 2014
Publication date	May 9, 2017
Grant date	May 9, 2017

Abstract

An electrophotographic photosensitive member capable of outputting an image with suppressed positive ghosting, and a process cartridge and an electrophotographic apparatus each having the electrophotographic photosensitive member are provided. The electrophotographic photosensitive member has a photosensitive layer including a phthalocyanine crystal in which the compound represented by the formula (1) is contained, wherein the content of the compound represented by the formula (1) is 0.1% by mass or more and 1.7% by mass or less based on the phthalocyanine crystal.

First claim

What is claimed is:

1. An electrophotographic photosensitive member comprising:
a support; and
a photosensitive layer on the support, the photosensitive layer comprising a phthalocyanine crystal containing a compound represented by formula (1),

wherein X represents a hydrogen atom or an alkyl group having 1 or 2 carbon atoms, and
the content of the compound represented by formula (1) is 0.1 to 1.7% by mass based on a phthalocyanine in the phthalocyanine crystal.

2. The electrophotographic photosensitive member according to claim 1 , wherein the phthalocyanine crystal is a gallium phthalocyanine crystal.

3. The electrophotographic photosensitive member according to claim 2 , wherein the gallium phthalocyanine crystal is a hydroxygallium phthalocyanine crystal.

4. The electrophotographic photosensitive member according to claim 3 , wherein the hydroxygallium phthalocyanine crystal has peaks at Bragg angles 2θ±0.2° of 7.4° and 28.3° in CuKα characteristic X-ray diffraction.

5. The electrophotographic photosensitive member according to claim 1 , wherein the content of the compound represented by formula (1) is 0.2 to 1.2% by mass based on the phthalocyanine in the phthalocyanine crystal.

6. The electrophotographic photosensitive member according to claim 1 , wherein X is a hydrogen atom.

7. The electrophotographic photosensitive member according to claim 3 , wherein the hydroxygallium phthalocyanine crystal has a local maximal peak in the range of 642 to 650 nm in an optical absorption spectrum.

8. The electrophotographic photosensitive member according to claim 7 , wherein the hydroxygallium phthalocyanine crystal has a local maximal peak in the range of 810 to 820 nm in the optical absorption spectrum.

9. The electrophotographic photosensitive member according to claim 1 , wherein the phthalocyanine crystal comprises N,N-dimethylformamide.

10. A process cartridge which integrally supports: an electrophotographic photosensitive member according to claim 1 ; and at least one unit selected from the group consisting of a charging unit, a developing unit, a transfer unit and a cleaning unit, the cartridge being detachably mountable to a main body of an electrophotographic apparatus.

11. An electrophotographic apparatus comprising:
an electrophotographic photosensitive member according to claim 1 ; with
a charging unit, an exposing unit, a developing unit and a transfer unit.

12. A phthalocyanine crystal comprising a compound represented by formula (1)

wherein X represents a hydrogen atom or an alkyl group having 1 or 2 carbon atoms, and
the content of the compound represented by formula (1) is 0.1 to 1.7% by mass based on a phthalocyanine in the phthalocyanine crystal.

13. The phthalocyanine crystal according to claim 12 , wherein the content of the compound represented by formula (1) is 0.2 to 1.2% by mass based on a phthalocyanine in the phthalocyanine crystal.

14. A manufacturing method of the phthalocyanine crystal according to claim 12 , comprising transforming the phthalocyanine crystal by adding the compound represented by formula (1) to a phthalocyanine followed by milling treatment.

15. The manufacturing method of the phthalocyanine crystal according to claim 14 , further comprising obtaining the phthalocyanine by an acid pasting method prior to the step of transforming the phthalocyanine crystal.

16. The manufacturing method of the phthalocyanine crystal according to claim 14 , wherein a time period for the milling treatment is 200 hours or more.

17. A manufacturing method of an electrophotographic photosensitive member having a support and a photosensitive layer formed on the support, comprising:
manufacturing the phthalocyanine crystal by the manufacturing method according to claim 14 ; and
forming a coating film from a coating liquid for forming the photosensitive layer which contains the phthalocyanine crystal, and then drying the coating film to form the photosensitive layer.

18. A manufacturing method of an electrophotographic photosensitive member having a support, a charge generation layer formed on the support, and a charge transport layer formed on the charge generation layer, comprising:
manufacturing the phthalocyanine crystal by the manufacturing method according to claim 14 ; and
forming a coating film from a coating liquid for forming a charge generation layer which contains the phthalocyanine crystal, and then drying the coating film to form the charge generation layer.

Assignees

• Canon Kk

Inventors

• Kuno Junpei
• Nishida Tsutomu
• Tanaka Masato
• Kawahara Masataka
• Watariguchi Kaname

Classifications

• G03G5/06

  characterised by the photoconductive material being organic · CPC title

• G03G5/0696

  Phthalocyanines · CPC title

• G03G5/05

  Organic bonding materials; Methods for coating a substrate with a photoconductive layer; Inert supplements for use in photoconductive layers · CPC title

• G03G21/18

  using a processing cartridge {, whereby the process cartridge comprises at least two image processing means in a single unit} · CPC title

• G03G5/04

  Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor · CPC title