Thin high-performance polarizing film and method for manufacturing the same

Patent metadata

Field	Value
Publication number	US-9645292-B2
Application number	US-201213595532-A
Country	US
Kind code	B2
Filing date	Aug 27, 2012
Priority date	Mar 5, 2009
Publication date	May 9, 2017
Grant date	May 9, 2017

Abstract

A method for manufacturing a thin high-performance polarizing film includes coating a polyvinyl alcohol type resin on a resin substrate having a thickness of at least 20 μm and then drying the resin to thereby form a polyvinyl alcohol type resin layer, immersing thus produced polyvinyl alcohol type resin layer in a dyeing solution including a dichroic material to thereby have the dichroic material impregnated in the polyvinyl alcohol type resin layer, stretching the polyvinyl alcohol type resin layer having the dichroic material impregnated therein together with the resin substrate in a boric acid solution such that a total stretching ratio of 5.0 or more of the original length is achieved.

First claim

The invention claimed is:

1. A polarizing film comprising:
a layer of polyvinyl alcohol resin having a dichroic material impregnated therein in a molecularly oriented state,
wherein the polarizing film has a thickness of 7 μm or less and exhibits optical properties of a single layer transmittance of 42.0% or higher and a polarization rate of 99.95% or higher.

2. The polarizing film as defined by claim 1 , wherein said polarizing film is provided on a resin substrate.

3. The polarizing film as defined by claim 2 , wherein said resin substrate is made of a non-crystallizable ester thermoplastic resin.

4. The polarizing film as defined by claim 2 , wherein said resin substrate is an optically functional film.

5. The polarizing film as defined by claim 1 , wherein said dichroic material is iodine, an organic dye, or a mixture thereof.

6. The polarizing film as defined by claim 1 , wherein said layer of polyvinyl alcohol resin is in a stretched and molecularly oriented state, and said dichroic material is iodine complexes oriented substantially in a direction of molecular orientation of the polyvinyl alcohol resin.

7. The polarizing film as defined by claim 1 , wherein said layer of polyvinyl alcohol resin layer is a cross-linked polyvinyl alcohol resin.

8. The polarizing film as defined by claim 1 , wherein said layer of polyvinyl alcohol resin is selected from the group consisting of polyvinyl alcohol and ethylene-vinyl alcohol copolymer.

9. The polarizing film as defined by claim 1 , wherein the thickness of the polarizing film ranges from 0.5 microns (μm) to 5.0 μm.

10. The polarizing film as defined by claim 1 , wherein the polyvinyl alcohol resin has an extent of saponification of 85 mol % to 100 mol %.

11. A polarizing element comprising:
a layer of polyvinyl alcohol resin having a dichroic material impregnated therein in a molecularly oriented state;
a resin substrate; and
a bonding layer between the polyvinyl alcohol resin and the resin substrate, wherein the layer of polyvinyl alcohol resin has a thickness of 7 μm or less and exhibits optical properties of a single layer transmittance of 42.0% or higher and a polarization rate of 99.95% or higher.

12. The polarizing element as defined in claim 11 , wherein the resin substrate has a glass transition temperature ranging from 25° C. to 85° C.

13. The polarizing element as defined in claim 11 , wherein the resin substrate is selected from the group consisting of an ester and an olefin, and the resin substrate has a water absorption of 0.50% or higher.

14. The polarizing element as defined in claim 11 , wherein the resin substrate has a thickness of at least 20 microns (μm).

15. The polarizing element as defined in claim 11 , wherein the thickness of the layer of polyvinyl alcohol resin ranges from 0.5 microns (μm) to 5.0 μm.

16. The polarizing element as defined in claim 11 , wherein said resin substrate is made of a non-crystallizable ester thermoplastic resin.

17. The polarizing element as defined in claim 11 , wherein said dichroic material is iodine, an organic dye, or a mixture thereof.

18. A polarization intermediate product comprising:
a layer of polyvinyl alcohol resin having a dichroic material impregnated therein in a molecularly oriented state;
a resin substrate on a first surface of the polyvinyl alcohol resin; and
a transfer resin film on a second surface of the polyvinyl alcohol resin opposite the first surface,
wherein the layer of polyvinyl alcohol resin has a thickness of 7 μm or less and exhibits optical properties of a single layer transmittance of 42.0% or higher and a polarization rate of 99.95% or higher.

19. The polarization intermediate product as defined in claim 18 , wherein said resin substrate is made of a non-crystallizable ester thermoplastic resin.

20. The polarization intermediate product as defined in claim 18 , wherein the thickness of the layer of polyvinyl alcohol resin ranges from 0.5 microns (μm) to 5.0 μm.

21. The polarization intermediate product as defined in claim 18 , wherein the polyvinyl alcohol resin has an extent of saponification of 85 mol % to 100 mol %.

22. The polarization intermediate product as defined in claim 18 , wherein the polyvinyl alcohol resin has an extent of polymerization from 1,000 to 10,000.

23. The polarization intermediate product as defined in claim 18 , wherein said transfer resin film is bonded to the polyvinyl alcohol resin.

24. The polarization intermediate product as defined in claim 18 , wherein said dichroic material is iodine, an organic dye, or a mixture thereof.

25. The polarization intermediate product as defined in claim 18 , wherein said layer of polyvinyl alcohol resin is a cross-linked polyvinyl alcohol resin layer.

26. A thin high performance polarizing film comprising:
a layer of polyvinyl alcohol resin having a dichroic material impregnated therein in a molecularly oriented state,
wherein the polarizing film has a thickness from 0.5 microns (μm) to 5.0 μm and exhibits optical properties of a single layer transmittance of 42.0% or higher and a polarization rate of 99.95% or higher.

27. The thin high performance polarizing film as defined in claim 26 , wherein the polyvinyl alcohol resin has an extent of saponification of 85 mol % to 100 mol %.

28. The thin high performance polarizing film as defined in claim 26 , wherein said layer of polyvinyl alcohol resin is selected from the group consisting of polyvinyl alcohol and ethylene-vinyl alcohol copolymer.

29. The thin high performance polarizing film as defined in claim 26 , wherein said layer of polyvinyl alcohol type resin is a cross-linked polyvinyl alcohol resin layer.

30. The thin high performance polarizing film as defined in claim 26 , wherein the polarizing film is disposed on a non-crystallizable ester thermoplastic resin substrate.

Assignees

• Goto Shusaku
• Miyatake Minoru
• Mori Tomohiro
• Yoshida Kentaro
• Kitagawa Takeharu
• Nitto Denko Corp

Inventors

• Goto Shusaku
• Miyatake Minoru
• Mori Tomohiro
• Yoshida Kentaro
• Kitagawa Takeharu

Classifications

• G02B5/3033 Primary

  in the form of a thin sheet or foil, e.g. Polaroid · CPC title

• Y10T428/265

  1 mil or less · CPC title

• G02B5/30 Primary

  Polarising elements (light-modulating devices with active elements G02F1/00) · CPC title

• G02F1/1335

  Structural association of cells with optical devices, e.g. polarisers or reflectors · CPC title