Integrated process for production of high octane gasoline, high aromatic naphtha and high cetane diesel from high aromatic middle distillate range streams

Patent metadata

Field	Value
Publication number	US-9644155-B2
Application number	US-201514658036-A
Country	US
Kind code	B2
Filing date	Mar 13, 2015
Priority date	Mar 24, 2014
Publication date	May 9, 2017
Grant date	May 9, 2017

Abstract

An integrated process for production of ultra low sulfur products of high octane gasoline, high aromatic naphtha and high Cetane Diesel from high aromatic middle distillate range streams from any cracker units such as Light Cycle Oil (LCO) stream of Fluid catalytic cracking (FCC) units and subjected to hydrotreating for removal of heteroatoms like sulfur and nitrogen. The effluent from hydrotreating is subjected to hydrocracking at same pressure of hydrotreating step above for selective opening of saturated ring of multi-ring aromatics. The effluent from hydrocracking is separated in CUT-1, CUT 2 in which the monoaromatics and alkylated monoaromatics are concentrated and CUT-3 in which concentration of saturates significantly increased. The CUT-3 is selectively oxidized in selective oxidation step in presence of catalyst, an oxidizing agent and operating conditions such that it results in diesel product with more enhanced Cetane.

First claim

We claim:

1. An integrated process for production of high octane gasoline (gasoline having octane number greater than 84), high aromatic naphtha (naphtha having octane number more than 90 and mono-aromatics and alkylated mono-aromatics concentration more than 30 wt %) and high cetane diesel (diesel having cetane number more than 42), the process comprising:
a) subjecting a feed to a hydrotreating step at a predetermined pressure to obtain a first effluent having a reduced quantity of hetero-atoms compared to the feed, the feed comprising at least 30 wt % multi-ring aromatics and having a boiling point between 200 to 400° C., wherein the predetermined pressure is capable of saturating one or more rings of multi-ring aromatics while leaving unsaturated one or more rings of the multi-ring aromatics;
b) subjecting the first effluent to a hydrocracking step at the predetermined pressure to obtain a second effluent, the hydrocracking step resulting in selective opening of at least one saturated ring of the multi-ring aromatics;
c) separating the second effluent into a CUT-1, a CUT-2 and a CUT-3, with the CUT-1 having a boiling point between 35 to 70° C., the CUT-2 having a boiling point between 70 to 200° C. and comprising a concentration of mono aromatics and alkylated mono aromatics and the CUT-3 having a boiling point above 200° C. and comprising an enhanced concentration of saturates, wherein:
the CUT-1 corresponds to said high octane gasoline, the octane number of the CUT-1 is at least 84, and a sulphur content of the CUT-1 is below 50 ppmw; and
the CUT-2 corresponds to said high aromatic naphtha, the octane number of the CUT-2 is at least 90, and a sulphur content of the CUT-2 is below 50 ppmw; and

d) subjecting at least a part of the CUT-3 to a selective oxidation step to in the presence of a catalyst, and an oxidizing agent to obtain said high cetane diesel range product (hydrocarbon liquid having boiling range between 200−400° C.).

2. The process as claimed in claim 1 , wherein the feed is a high aromatic middle distillate or a diesel range feedstock selected from (a) mineral petroleum oil; (b) Light Cycle Oil stream of FCC unit; (c) gas oil stream of delayed coker unit; (d) pyrolysis oil; (e) thermally cracked bio-sources or mixtures thereof.

3. The process as claimed in claim 1 , wherein the hydrotreating step is carried out at a pressure of about 25 to 75 barg and temperature of about 280 to 450° C. and at a LHSV of 0.1 to 5.0 h −1 .

4. The process as claimed in claim 1 , wherein the hydrocracking step is carried out at a same pressure as that of hydrotreating step at a temperature of 300 to 450° C. and at a LHSV of 0.1 to 5.0 h −1 .

5. The process as claimed in claim 1 , wherein the hydrocracking step is carried out at a conversion level that gives combined yield of CUT 1 and CUT 2 of above of about at least 30 wt %.

6. The process as claimed in claim 1 , wherein the CUT-2 is having monoaromatics and alkylated monoaromatics concentration more than 30 wt %.

7. The process as claimed in claim 1 , wherein:
the CUT-3 having cetane number not more than 40 before oxidation step; and
the CUT-3 before oxidizing step is rich in a benzocycloparaffins and at least in the range of 10 to 30 wt %.

8. The process as claimed in claim 1 , wherein the CUT-3 stream is oxidized with oxidizing agent at a temperature in the range of 35 to 250° C., pressure in the range of 1 to 50 barg and reaction time of oxidation in the range of 0.1 to 36 hrs.

9. The process as claimed in claim 1 , wherein the oxidizing agent is selected from organic, inorganic, molecular oxygen or oxygen containing gases, ozone or ozone containing gas and mixtures thereof.

10. The process as claimed in claim 1 , wherein the oxidation product of the CUT-3 is partially recycled to the selective oxidation step during the oxidation step to increase the yield and selectivity of oxidized compounds in the product wherein the recycle ratio of oxidized product to feed (CUT-3) may vary from 1 to 20 vol %.

11. The process as claimed in claim 1 , wherein the cetane improvement of the CUT-3 after selective oxidation is between 2 to 15 units more than that the CUT-3.

12. The process as claimed in claim 1 , wherein the selective oxidation step is carried out over a catalyst selected from mixture of metal oxide and salts of organometallic oxide.

Assignees

• Indian Oil Corp Ltd

Inventors

• Butley Ganesh Vitthalrao
• Sarkar Mainak
• Gupta Yamini
• Arun Arangarasu
• Sau Madhusudan
• Sugumaran Vatsala
• Kagdiyal Vivekanand
• Sakthivel Paramasivam
• Kumar Brijesh
• Das Biswapriya

Classifications

• C10L1/06

  for spark ignition · CPC title

• C10L1/026

  for compression ignition · CPC title

• C10G2400/04

  Diesel oil · CPC title

• C07C2102/10

  Chemistry & Metallurgy · mapped topic

• C10L2270/026

  for diesel engines, e.g. automobiles, stationary, marine · CPC title