Aqueous dispersible polymer inks

Patent metadata

Field	Value
Publication number	US-9644105-B2
Application number	US-201314139708-A
Country	US
Kind code	B2
Filing date	Dec 23, 2013
Priority date	Dec 23, 2013
Publication date	May 9, 2017
Grant date	May 9, 2017

Abstract

An ink composition or ink concentrate for variable data lithographic printing or ink jet printing includes a nano-particle polymer or blend of nano-particle polymers, wherein the polymer or polymers of the blend are water dispersible at temperatures below 100 degrees Celsius; and solids content is in an amount of greater than 25 percent by total weight.

First claim

What is claimed is:

1. An ink composition for variable data offset printing or an ink jet printing process that uses an intermediate substrate, comprising:
nano-particles, wherein each nano-particle is a polymer or a polymer blend of polymers,
wherein the polymer or the polymers of the polymer blend are water dispersible at temperatures less than 100 degrees Celsius,
wherein the total solids content of the ink composition is an amount in a range of about 25% or greater by total weight of the ink composition,
wherein the polymer or the polymer blend comprises a sulfonated polyester, and
wherein the sulfonated polyester is copoly(1,2-propylene-dipropylene-terephthalate)-copoly(1,2-propylene-dipropylene-5-sodiosulfoisophthalate).

2. The ink composition of claim 1 , wherein the total solids content of the ink composition is an amount in a range of 25% to about 50% by total weight of the ink composition.

3. The ink composition of claim 1 , wherein the total solids content of the ink composition is greater than 50% by total weight of the ink composition.

4. The ink composition of claim 1 , wherein the polymer comprises a component derived from monomers selected from the group consisting of glycols, multifunctional glycols, alcohols, multifunctional alcohols, acids, and salts thereof, and
wherein the polymer blend comprises a component selected from the group consisting of carboxyl-polyester and polyester.

5. The ink composition of claim 1 , wherein the polymer or the polymers of the polymer blend have a molecular weight between 5000 and 20,000.

6. The ink composition of claim 1 , wherein the polymer or the polymers of the polymer blend contains a portion that is water soluble in an amount less than 10%, and is soluble in a non-aqueous liquid vehicle in an amount less than 30%, at a temperature between 20 and 50 degrees Celsius.

7. The ink composition of claim 1 , wherein the polymer or the polymers of the polymer blend are substantially soluble at temperatures above 70 to 95 degrees Celsius.

8. The ink composition of claim 1 , wherein the polymer or the polymers of the polymer blend comprises an unsaturated functional group.

9. The ink composition of claim 1 , comprising:
a co-solvent, the co-solvent having a surface tension of about 15 dynes/centimeter to about 40 dynes/centimeter, the co-solvent being selected from the group comprising alcohols, glycols, alkyl pyrrolidinones, isopropanol, ketones methyl ethyl ketone, amino alcohol and DMSO.

10. The ink composition of claim 1 , wherein the nano-particles are less than 200 nm, or mixtures of nano-particles forming bimodal or trimodal distributions.

11. The ink composition of claim 1 , further comprising one or more mixtures of the following: inorganic particles, silica, pigment, salts, bioside, buffer, or humectant.

12. The ink composition of claim 1 , further comprising:
a self-dispersing pigment of a particle size between 5 to 200 nm, wherein the pigment is chemically modified or resin encapsulated.

13. The ink composition of claim 1 , further comprising a self-dispersing pigment that is encapsulated by, or aggregated with the polymer or the polymer blend, thereby forming a nano-particle.

14. The ink composition of claim 1 , further comprising a surfactant.

15. The ink composition of claim 2 , wherein the ink composition has a viscosity of about 10 centipoise to about 1,000,000 centipoise in the temperature range of 20 degrees Celsius to 50 degrees Celsius.

16. The ink composition of claim 2 , wherein the ink composition has a viscosity of ink, after loss of 0 to 80 percent of liquid vehicle, in the range of between 10,000 centipoise and 1,000,000,000 centipoise at temperatures between 10 degrees Celsius to about 90 degrees Celsius.

17. The ink composition of claim 2 , wherein the ink composition has a viscosity of about 2 centipoise to about 10 centipoise in the temperature range of 20 degrees Celsius to 50 degrees Celsius.

18. The ink composition of claim 1 , wherein the polymer or the polymer blend has a critical phase separation temperature of about 50 degrees Celsius to about 90 degrees Celsius.

19. The ink composition of claim 1 , wherein the surface tension of the ink is between 15 and 40 dynes/centimeter at 25 degrees C., or over the temperature range between 20 to 50 degrees C.

20. The ink composition of claim 1 , wherein the density of the ink is between about 0.95 to 1.3, or between 1.1 and 1.2 g/mL.

21. The ink composition of claim 12 , wherein the resin that is used to encapsulate the pigment is be between 9 percent and 66 percent of the combined weight of the pigment and the encapsulating resin.

22. An ink composition for variable data offset printing or an ink jet printing process that uses an intermediate substrate, comprising:
nano-particles, wherein each nano-particle is a polymer or a polymer blend of polymers,
wherein the polymer or the polymers of the polymer blend are water dispersible at temperatures less than 100 degrees Celsius,
wherein the total solids content of the ink composition is an amount in a range of about 4% to about 25% by total weight of the ink composition,
wherein the polymer or the polymer blend comprises a sulfonated polyester, and
wherein the sulfonated polyester is copoly(1,2-propylene-dipropylene-terephthalate)-copoly(1,2-propylene-dipropylene-5-sodiosulfoisophthalate).

23. A method of printing using high solids content inks, comprising:
providing an ink comprising water and nano-particles, wherein each nano-particle is a polymer or a polymer blend of polymers; and
applying the ink to an intermediate transfer member,
wherein the polymer or polymers of the polymer blend are water dispersible at temperatures less than 100 degrees Celsius,
wherein a solids content of the ink is in an amount of about 5% to about 50% by total weight of the ink composition,
wherein the polymer or the polymer blend comprises a sulfonated polyester, and
wherein the sulfonated polyester is copoly(1,2-propylene-dipropylene-terephthalate)-copoly(1,2-propylene-dipropylene-5-sodiosulfoisophthalate).

24. The method of claim 23 , wherein the intermediate transfer member has a surface tension of about 18 dynes/centimeter to about 25 dynes/centimeter.

25. The method of claim 23 , wherein the intermediate transfer member has a surface comprising silicone or fluorosilicone.

26. The method of claim 23 , the applying further comprising:
applying the ink at an ink temperature above the upper critical phase separation temperature, the upper critical phase separation temperature being about 30 degrees Celsius to about 50 degrees Celsius;
cooling the ink on the intermediate transfer member; and
transferring the ink from the intermediate transfer member to a printable substrate.

27. The method of claim 26 , wherein the printable substrate is an imaging member of an ink-based digital printing system.

28. The method of claim 23 , further comprising:
diluting the ink with water before the step of applying, whereby the solid content of the ink is between 5% and 25% by weight, wherein, the step of applying the ink to an intermediate transfer member further comprises jetting the diluted ink from an inkjet printhead.

Assignees

• Xerox Corp

Inventors

• Breton Marcel
• Moorlag Carolyn
• Sacripante Guerino

Classifications

• C08K5/07

  Aldehydes; Ketones · CPC title

• C08K5/3415

  Five-membered rings · CPC title

• C08K5/053 Primary

  Polyhydroxylic alcohols · CPC title

• C08K5/41

  Compounds containing sulfur bound to oxygen · CPC title

• C09D11/102 Primary

  containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds · CPC title