Rubber tyre compound production method

Patent metadata

Field	Value
Publication number	US-9644085-B2
Application number	US-201414903358-A
Country	US
Kind code	B2
Filing date	Jul 8, 2014
Priority date	Jul 8, 2013
Publication date	May 9, 2017
Grant date	May 9, 2017

Abstract

A method of producing rubber compounds, in which the polymer base is composed partly of a first polymer material having a glass transition temperature of over −50° C., and partly of a second polymer material having a glass transition temperature of below −50° C. and silica as a filler. The method includes a preliminary first polymer material treating step, in which the first polymer material, a silica having a surface area of 80 to 135 m 2 /g, a silane bonding agent, and at least one nucleophile agent are mixed together; a preliminary second polymer material treating step, in which the second polymer material, a silica having a surface area of 150 to 220 m 2 /g, a silane bonding agent, and at least one nucleophile agent are mixed together; a mixing step, in which the compounds resulting from the preliminary treating steps are mixed together; and a final step, in which stearic acid and a curing system are added and mixed with the compound being produced.

First claim

The invention claimed is:

1. A method of producing a rubber compound, comprising:
a preliminary first polymer material treating step in which a first polymer material having a glass transition temperature of over −50° C., a silica having a surface area of 80 to 135 m 2 /g, a silane bonding agent, and at least one nucleophile agent are mixed together;
a preliminary second polymer material treating step in which a second polymer material having a glass transition temperature of below −50° C., a silica having a surface area of 150 to 220 m 2 /g, a silane bonding agent, and at least one nucleophile agent are mixed together;
a mixing step, in which the mixtures resulting from the preliminary first and second polymer material treating steps are mixed into one compound; and
a final step, in which stearic acid and a curing system are added to and mixed with the compound.

2. The method of producing a rubber compound as claimed in claim 1 , characterized in that said nucleophile agents are curing accelerants.

3. The method of producing a rubber compound as claimed in claim 2 , characterized in that the curing accelerants are selected from the group consisting of amines, disulphides, guanidines, and derivatives thereof, thiourea and derivatives thereof, thiazoles, thiurams, sulphenamides, and derivatives thereof, dithiocarbamates, dithiophosphates, and xanthates, and mixtures thereof; and preferably, the curing accelerants are selected from the group consisting of benzothiazyl-cyclohexyl sulphenamide (CBS), N-tert-butyl-2-benzothiazylsulphenamide (TBBS), 2-mercaptobenzothiazole (MBT), zinc salts of 2-mercaptobenzothiazole (ZMBT), benzothiazyl-2-dicyclohexyl sulphenamide (DCBS), diphenylguanidine (DPG), triphenylguanidine (TPG), di-ortho-tolyl-guanidine (DOTG), ortho-tolylbiguanidine (OTBG), diphenyl thiourea (DPTU), benzothiazole disulphide (MBTS), hexamethylenetetramine (HMT), tetrabenzyl thiuram disulphide (TBzTD), and mixtures thereof.

4. The method of producing a rubber compound as claimed in claim 1 , characterized in that, in each of said preliminary polymer material treating steps, the amount of silica ranges from 10 to 80 phr with respect to the polymer material.

5. The method of producing a rubber compound as claimed in claim 1 , characterized in that the rubber compound comprises 80 to 20 of said first polymer material and 20 to 80 phr of said second polymer material.

6. The method of producing a rubber compound as claimed in claim 1 , characterized in that said first polymer material is a styrene-butadiene copolymer (SBR).

7. The method of producing a rubber compound as claimed in claim 1 , characterized in that said second polymer material is polybutadiene (BR) or natural rubber (NR).

Assignees

• Botti Francesco
• Ascione Riccardo
• Privitera Davide
• Amurri Michele
• Agoretti Pasquale
• Bridgestone Corp

Inventors

• Botti Francesco
• Ascione Riccardo
• Privitera Davide
• Amurri Michele
• Agoretti Pasquale

Classifications

• C08K2201/006

  Additives being defined by their surface area · CPC title

• C08K2201/014

  Additives containing two or more different additives of the same subgroup in C08K · CPC title

• C08L21/00

  Compositions of unspecified rubbers · CPC title

• C08L9/00 Primary

  Compositions of homopolymers or copolymers of conjugated diene hydrocarbons · CPC title

• C08J2307/00

  Characterised by the use of natural rubber · CPC title