Polymer particle dispersions with polyols

Patent metadata

Field	Value
Publication number	US-9644062-B2
Application number	US-201314426410-A
Country	US
Kind code	B2
Filing date	Oct 17, 2013
Priority date	Oct 19, 2012
Publication date	May 9, 2017
Grant date	May 9, 2017

Abstract

A toughener composition comprising: a) a polyol component selected from the group consisting of a polyether polyol, a polyester polyol, a polycaprolactone polyol, a hydroxyl-terminated polybutadiene, and mixtures or copolymers thereof; and b) a core shell rubber comprising a rubber particle core and a shell layer wherein said core shell rubber has a particle size of from 0.01 μm to 0.5 μm is disclosed. The toughener can be used in epoxy resin compositions for composite applications.

First claim

The invention claimed is:

1. A process for preparing a composition comprising
a) a polyol component comprising a polyol with an average molecular weight of from 2000 to 12000 and an average functionality of 1.5 to 6; and
b) a core shell rubber comprising a rubber particle core and a shell layer wherein said core shell rubber has a particle size of from 0.01 μm to 0.5 μm,
the process comprising dispersing the core shell rubber into the polyol component with a high shear mixer in a dispersion zone under dispersion conditions wherein said dispersion zone does not contain a solvent and wherein said dispersion conditions comprise a dispersion temperature of 40° C. to 120° C., a Reynolds Number greater than 10, and a dispersion time of from 30 minutes to 480 minutes.

2. A process in accordance with claim 1 wherein said core shell rubber comprises a functional group selected from the group consisting of carboxyl groups, hydroxyl groups, carbon-carbon double bonds, anhydride groups, amino groups, amide groups, and combinations thereof.

3. A process in accordance with claim 1 wherein said polyol component is a copolymer selected from the group consisting of ethylene oxide propylene oxide block copolymers, ethylene oxide-butylene oxide block copolymers, ethylene oxide end-capped propylene oxide polyols, ethylene oxide end-capped butylene oxide polyols, and combinations thereof.

4. The process of claim 3 wherein the ethylene oxide content of the copolymer is 30 to 60 weight percent.

5. A process in accordance with claim 1 wherein said polyol component comprises a polyol selected from the group consisting of a polyether polyol, a polyester polyol, a polycaprolactone polyol, a hydroxyl-terminated polybutadiene, and mixtures or copolymers thereof.

6. A process in accordance with claim 1 wherein said dispersion zone further comprises a dispersion agent.

7. A process for forming an epoxy resin composition, comprising dispersing in the absence of a solvent a core-shell rubber comprising a rubber particle core and a shell layer wherein said core shell rubber has a particle size of from 0.01 μm to 0.5 μm into a polyol component comprising a polyol with an average molecular weight of from 2000 to 12000 and an average functionality of 1.5 to 6 to form a dispersion of the core-shell rubber in the polyol component, and then admixing said dispersion with the epoxy resin and a hardener to form the epoxy resin composition.

8. A process in accordance with claim 7 wherein said core shell rubber comprises a functional group selected from the group consisting of carboxyl groups, hydroxyl groups, carbon-carbon double bonds, anhydride groups, amino groups, amide groups, and combinations thereof.

9. A process in accordance with claim 7 wherein the polyol is present in an amount in the range of from 3.0 weight percent to 30.0 weight percent, and the core shell rubber is present in an amount in the range of from 3.0 weight percent to 20.0 weight percent, based on the total weight of the composition.

10. A process in accordance with claim 7 wherein the hardener is selected from the group consisting of aromatic amines, aliphatic amines, cycloaliphatic amines, anhydrides, amidoamines, polyamides and combinations thereof.

11. A process in accordance with claim 7 wherein said polyol component is a copolymer selected from the group consisting of ethylene oxide-proplylene oxide block copolymers, ethylene oxide-butylene oxide block copolymers, ethylene oxide end-capped proplylene polyols, ethylene oxide end-capped butylenes oxide polyols, and combinations thereof.

12. The process of claim 7 wherein the dispersing step is performed by dispersing the core shell rubber into the polyol component with a high shear mixer in a dispersion zone under dispersion conditions, wherein said dispersion zone does not contain a solvent and wherein said dispersion conditions comprise a dispersion temperature of 40° C. to 120° C., a Reynolds Number greater than 10, and a dispersion time of from 30 minutes to 480 minutes.

13. The process of claim 11 wherein the ethylene oxide content of the copolymer is 30 to 60 weight percent.

Assignees

• Dow Global Technologies Llc

Inventors

• Xie Rui
• Nunley Jeanette K

Classifications

• C08L63/00

  Compositions of epoxy resins; Compositions of derivatives of epoxy resins · CPC title

• C08F283/10 Primary

  on to polymers containing more than one epoxy radical per molecule {(C08F283/004 takes precedence)} · CPC title

• C08G59/4238

  heterocyclic · CPC title

• C08L51/04

  grafted on to rubbers · CPC title

• C08G59/245

  aromatic · CPC title