Fining molten material using reduced pressure
US-2024166545-A1 · May 23, 2024 · US
US9643870B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9643870-B2 |
| Application number | US-201514813570-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jul 30, 2015 |
| Priority date | Jun 17, 2010 |
| Publication date | May 9, 2017 |
| Grant date | May 9, 2017 |
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A melter apparatus includes a floor, a ceiling, and a substantially vertical wall connecting the floor and ceiling at a perimeter of the floor and ceiling, a melting zone being defined by the floor, ceiling and wall, the melting zone having a feed inlet and a molten glass outlet positioned at opposing ends of the melting zone. The melting zone includes an expanding zone beginning at the inlet and extending to an intermediate location relative to the opposing ends, and a narrowing zone extending from the intermediate location to the outlet. One or more burners, at least some of which are positioned to direct combustion products into the melting zone under a level of molten glass in the zone, are also provided.
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What is claimed is: 1. A melter apparatus comprising: a) a floor and a ceiling; b) a substantially vertical wall connecting the floor and ceiling at a perimeter of the floor and ceiling, the substantially vertical wall comprising two opposing substantially vertical side walls, a substantially vertical inlet end wall, and a substantially vertical outlet end wall, a melting zone being defined by the floor, ceiling and the substantially vertical wall, the melting zone having a feed inlet in the substantially vertical inlet end wall and a molten glass outlet in the substantially vertical outlet end wall, the substantially vertical inlet end wall and the substantially vertical outlet end wall positioned at opposing ends of the melting zone, the melting zone comprising an expanding zone beginning at the substantially vertical inlet end wall and extending to an intermediate location relative to the opposing ends of the melting zone, and a narrowing zone extending from the intermediate location to the substantially vertical outlet end wall, at least the substantially vertical side walls in the narrowing zone each having a free-flowing form devoid of angles; and c) a plurality of burners, at least some of which are positioned to direct combustion products into the melting zone under a level of molten glass in the melting zone. 2. The melter apparatus of claim 1 wherein the intermediate location is positioned where the melting zone has a maximum width. 3. The melter apparatus of claim 1 wherein at least some of the substantially vertical wall comprises fluid-cooled refractory panels. 4. The melter apparatus of claim 3 wherein the fluid-cooled refractory panels are liquid-cooled refractory panels comprising one or more passages for flow of a liquid into and out of the passages. 5. The melter apparatus of claim 3 wherein the fluid-cooled refractory panels are cooled by a heat transfer fluid selected from the group consisting of gaseous, liquid, or combinations of gaseous and liquid compositions that functions or is capable of being modified to function as a heat transfer fluid. 6. The melter apparatus of claim 5 wherein the gaseous heat transfer fluids are selected from the group consisting of ambient air, treated air, inert inorganic gases, inert organic gases, and mixtures of inert gases with small portions of non-inert gases, and wherein the liquid heat transfer fluids are selected from the group consisting of inert liquids which may be organic, inorganic, or some combination thereof. 7. The melter apparatus of claim 1 wherein the expanding zone has a plan view trapezoidal shape defined by a trapezoid having a base positioned at the intermediate location and substantially perpendicular to a longitudinal axis of the melter, the trapezoid having a side parallel to the base and positioned at the inlet end wall. 8. The melter apparatus of claim 1 wherein at least some of the plurality of burners are floor-mounted and positioned in one or more parallel rows substantially perpendicular to a longitudinal axis of the melter. 9. The melter apparatus of claim 8 wherein the number of the plurality of burners in each row is proportional to width of the melter. 10. The melter apparatus of claim 1 wherein depth of the melter decreases as width of the melter in the narrowing zone decreases. 11. The melter apparatus of claim 1 wherein the intermediate location comprises a constant width zone positioned between the expanding zone and the narrowing zone. 12. The melter apparatus of claim 1 wherein at least some of the plurality of burners are oxy-fuel burners. 13. The melter apparatus of claim 1 having a throughput of 2 ft 2 /stpd or less. 14. The melter apparatus of claim 13 having a throughput of 0.5 ft 2 /stpd or less. 15. The melter apparatus of claim 14 wherein the melter substantially vertical wall comprises all fluid-cooled panels, the substantially vertical wall comprising a refractory liner at least between the fluid-cooled panels and the molten glass. 16. The melter apparatus of claim 1 wherein each of the two opposing substantially vertical side walls in the expanding zone and the narrowing zone are non-linear. 17. The melter apparatus of claim 1 , wherein each of the two opposing substantially vertical side walls has a free-flowing form, devoid of angles in the expanding zone. 18. A melter apparatus comprising: a) a floor and a ceiling; b) a substantially vertical wall connecting the floor and ceiling at a perimeter of the floor and ceiling, the substantially vertical wall comprising two opposing substantially vertical side walls, a substantially vertical inlet end wall, and a substantially vertical outlet end wall, a melting zone being defined by the floor, ceiling and the substantially vertical wall, the melting zone having a feed inlet in the substantially vertical inlet end wall and a molten glass outlet in the substantially vertical outlet end wall, the substantially vertical inlet end wall and the substantially vertical outlet end wall positioned at opposing ends of the melting zone, the melting zone comprising an expanding zone beginning at the substantially vertical inlet end wall and extending to an intermediate location relative to the opposing ends of the melting zone, and a narrowing zone extending from the intermediate location to the substantially vertical outlet end wall, the intermediate location comprising a constant width zone positioned between the expanding zone and the narrowing zone, wherein at least some of the substantially vertical wall comprises fluid-cooled refractory panels, the two opposing substantially vertical side walls in the narrowing zone each having a free flowing form, and the two opposing substantially vertical side walls in the expanding zone each being linear and intersecting the substantially vertical wall in the constant width zone at an angle larger than 90 degrees; and c) a plurality of burners, at least some of which are positioned to direct combustion products into the melting zone under a level of molten glass in the melting zone. 19. The apparatus of claim 18 wherein at least some of the plurality of burners are floor-mounted and positioned in one or more parallel rows substantially perpendicular to a longitudinal axis of the melter. 20. The apparatus of claim 18 having a throughput of 2 ft 2 /stpd or less. 21. A process comprising: feeding at least one partially vitrifiable material into a feed inlet of a melting zone of a refractory melter apparatus comprising a floor, a ceiling, and a substantially vertical wall connecting the floor and ceiling at a perimeter of the floor and ceiling, the substantially vertical wall comprising two opposing substantially vertical side walls, a substantially vertical inlet end wall, and a substantially vertical outlet end wall, the melting zone comprising an expanding zone beginning at the substantially vertical inlet end wall and extending to an intermediate location relative to opposing ends of the melter, and a narrowing zone extending from the intermediate location to the substantially vertical outlet end wall, at least the substantially vertical side walls in the narrowing zone each having a free flowing form devoid of angles; heating the at least one partially vitrifiable material with at least one burner directing combustion products into the melting zone under a level of the molten glass in the melting zone; and discharging molten glass from a molten glass outlet positioned in the substantially vertical outlet end
using oxygen, i.e. pure oxygen or oxygen-enriched air · CPC title
with separate air and gas feed ducts, e.g. with ducts running parallel or crossing each other · CPC title
Devices for blowing onto the melt surface, e.g. high momentum burners · CPC title
by combustion with pure oxygen or oxygen-enriched air, e.g. using oxy-fuel burners or oxygen lances · CPC title
with pulsating oxidant supply · CPC title
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