Dielectric polyurethane film

Patent metadata

Field	Value
Publication number	US-9643840-B2
Application number	US-201314410178-A
Country	US
Kind code	B2
Filing date	Jun 24, 2013
Priority date	Jun 27, 2012
Publication date	May 9, 2017
Grant date	May 9, 2017

Abstract

The present invention relates to a process for producing a dielectric polyurethane film, in which at least the following steps are performed continuously: I) a mixture comprising: a) a compound containing isocyanate groups and having a content of isocyanate groups of >10% by weight and ≦50% by weight, b) a compound containing isocyanate-reactive groups and having an OH number of ≧20 and ≦150, at least one solvent having a vapor pressure at 20° C. of >0.1 mbar and <200 mbar, at least one wetting additive, is produced, where the sum of the number-average functionalities of isocyanate groups and of isocyanate-reactive groups in the compounds a) and b) is ≧2.6 and ≦6, II) immediately after production thereof, the mixture is applied to a carrier in the form of a wet film, III) the wet film is cured to form the polyurethane film and IV) the polyurethane film is separated from the carrier. The invention further provides a dielectric polyurethane film obtainable by the process according to the invention, a process for producing an electromechanical transducer, and an electromechanical transducer obtainable by this process.

First claim

The invention claimed is:

1. A process for producing a dielectric polyurethane film, in which at least the following steps are performed continuously:
I) producing a mixture comprising
a) a compound containing isocyanate groups and having a content of isocyanate groups of >10% by weight and ≦50% by weight,
b) a compound containing isocyanate-reactive groups and having an OH number of ≧20 and ≦150,
c) at least one solvent having a vapour pressure at 20° C. of >0.1 mbar and <200 mbar,
d) at least one wetting additive,
where the sum of the number-average functionalities of the isocyanate groups and of the isocyanate-reactive groups in the compounds a) and b) is ≧2.6 and ≦6,

II) immediately after production of the mixture, applying the mixture to a carrier in the form of a wet film,
III) curing the wet film to form the polyurethane film and
IV) separating the polyurethane film from the carrier,
wherein the wet film is cured in step III) by conducting the wet film through a first drying section having a temperature of ≧40° C. and ≦120° C., wherein the total residence time of the wet film in the drying section is ≧10 seconds and ≦60 minutes, wherein the dielectric polyurethane film has an electrical resistivity >1.5E12 ohm m determined according to ASTM D 257 and wherein the creep at 10% deformation after 30 min to DIN 53 441 is <30%.

2. The process according to claim 1 , wherein the mixture is applied to the carrier in step II) by means of a die.

3. The process according to claim 2 , wherein the distance of the die from the carrier is less than three times the thickness of the wet film.

4. The process according to claim 1 , wherein a wet film having a thickness of 10 to 300 μM is produced in step II).

5. The process according to claim 1 , wherein the wet film after the first drying section is additionally conducted through a second drying section having a temperature of ≧60° C. and ≦130° C.

6. The process according to claim 5 , wherein the wet film after the second drying section is additionally conducted through a third drying section having a temperature of ≧110° C. and ≦180° C.

7. The process according to claim 1 , wherein the solvent has a vapour pressure at 20° C. of >0.2 mbar and <150 mbar.

8. The process according to claim 1 , wherein the compound a) has a number-average functionality of isocyanate groups of ≧2.0 and ≦4.

9. The process according to claim 1 , wherein the compound a) comprises an aliphatic polyisocyanate.

10. The process according to claim 1 , wherein the compound b) has a number-average functionality of isocyanate-reactive groups of ≧2.0 and ≦4.

11. The process according to claim 1 , wherein the compound b) comprises a diol.

12. The process according to claim 1 , wherein the carrier comprises plastic or paper.

13. The process according to claim 1 , wherein the tensile strength of the dielectric polyurethane film is >2 MPa to DIN 53 504.

14. The process according to claim 1 , wherein the dielectric strength of the dielectric polyurethane film is >40 V/μm to ASTM D 149-97a.

15. A dielectric polyurethane film obtained by the process according to claim 1 .

16. A process for producing an electromechanical transducer comprising
producing a dielectric polyurethane film by a process according to claim 1 in a first step, and disposing an electrode on each of the opposite sides of the dielectric polyurethane film in a second step.

17. An electromechanical transducer obtained by the process according to claim 16 .

Assignees

• Bayer Materialscience Ag
• Covestro Deutschland Ag

Inventors

• Wagner Joachim
• Krause Jens
• Hönel Dennis

Classifications

• B29L2007/008

  Wide strips, e.g. films, webs · CPC title

• C08G18/7831

  containing biuret groups · CPC title

• Y10T29/43

  Electric condenser making · CPC title

• C08G18/44

  Polycarbonates · CPC title

• B32B27/40

  comprising polyurethanes · CPC title