Porous carbon and methods of production thereof

Patent metadata

Field	Value
Publication number	US-9642394-B2
Application number	US-201214233950-A
Country	US
Kind code	B2
Filing date	Jul 18, 2012
Priority date	Jul 21, 2011
Publication date	May 9, 2017
Grant date	May 9, 2017

Abstract

Embodiments of the invention relate to porous carbon and methods of preparing porous carbon. In some embodiments, the prepared porous carbon exhibits enhanced selectivity for hydrogen cyanide (HCN), In one embodiment, the method comprises impregnating activated carbon with a metal oxide, such as zinc oxide. The carbon is suitable for use in smoke filtration.

First claim

The invention claimed is:

1. A method of enhancing the selectivity of porous carbon for hydrogen cyanide (HCN), the method comprising:
impregnating activated carbon with zinc salt, the impregnating including at least one of: (1) dip impregnation with an aqueous solution of zinc salt, the solvent consisting of water, (2) spraying with an aqueous solution of zinc salt, the solvent consisting of water, or (3) soaking with an aqueous solution of zinc salt, the solvent consisting of water; and
thermally treating the impregnated activated carbon to form porous carbon impregnated with zinc oxide, wherein the activated carbon has at least 30% of the pore volume as micropores, and wherein, when used in a smoking article filter, the porous carbon has an enhanced selectivity for HCN relative to the activated carbon without impregnation with zinc oxide.

2. The method as claimed in claim 1 , wherein no cyanogen is formed as a by-product when the porous carbon is exposed to HCN.

3. The method as claimed in claim 1 , wherein the activated carbon is a carbonised form of an organic material.

4. The method as claimed in claim 1 , wherein the activated carbon is a resin-based synthetic carbon.

5. The method as claimed in claim 1 , wherein the activated carbon has a pore volume of at least 0.4 cm 3 /g.

6. The method as claimed in claim 5 , wherein the activated carbon is a sulfonated copolymer-derived activated carbon.

7. The method as claimed in claim 1 , wherein the zinc salt comprises zinc nitrate.

8. The method as claimed in claim 7 , wherein the zinc salt consists of zinc nitrate.

9. A filter element for a smoking article comprising the porous carbon as claimed in claim 1 .

10. A smoking article comprising the porous carbon as claimed in claim 1 .

11. The method as claimed in claim 5 , wherein the activated carbon is a sulfonated styrene-divinylbenzene copolymer-derived activated carbon.

12. The method as claimed in claim 1 , wherein the impregnated metal oxide is between 0.5 and 10% by weight of activated carbon.

13. The method as claimed in claim 1 , wherein the impregnated metal oxide is between 0.5 and 5% by weight of activated carbon.

14. The method as claimed in claim 1 , wherein the activated carbon has a particle size of from 0.1 to 1.5 mm.

15. The method as claimed in claim 1 , wherein the activated carbon has at least 20% to 65% of the pore volume as mesopores.

Assignees

• Branton Peter
• Bohringer Bertram
• Fichtner Sven
• Giebelhausen Jann-Michael
• British American Tobacco Investments Ltd

Inventors

• Branton Peter
• Bohringer Bertram
• Fichtner Sven
• Giebelhausen Jann-Michael

Classifications

• A24D3/16

  of inorganic materials · CPC title

• B01J20/3234

  Inorganic material layers · CPC title

• B01J20/3204

  Inorganic carriers, supports or substrates · CPC title

• C01B32/354

  After-treatment · CPC title

• A24D3/0287

  for composite filters · CPC title