Nanotube dispersants and dispersant free nanotube films therefrom

Patent metadata

Field	Value
Publication number	US-9642252-B2
Application number	US-201615065775-A
Country	US
Kind code	B2
Filing date	Mar 9, 2016
Priority date	Apr 4, 2011
Publication date	May 2, 2017
Grant date	May 2, 2017

Abstract

A degradable polymeric nanotube (NT) dispersant comprises a multiplicity of NT associative groups that are connected to a polymer backbone by a linking group where there are cleavable groups within the polymer backbone and/or the linking groups such that on a directed change of conditions, bond breaking of the cleavable groups results in residues from the degradable polymeric NT dispersant in a manner where the associative groups are uncoupled from other associative groups, rendering the associative groups monomelic in nature. The degradable polymeric nanotube (NT) dispersant can be combined with carbon NTs to form a NT dispersion that can be deposited to form a NT film, or other structure, by air brushing, electrostatic spraying, ultrasonic spraying, ink-jet printing, roll-to-roll coating, or dip coating. The deposition can render a NT film that is of a uniform thickness or is patterned with various thicknesses. Upon deposition of the film, the degradable polymeric nanotube (NT) dispersant can be cleaved and the cleavage residues removed from the film to yield a film where contact between NTs is unencumbered by dispersants, resulting in highly conductive NT films.

First claim

The invention claimed is:

1. A method of preparing a nanotube (NT)-comprising film, comprising:
providing an NT dispersion comprising a plurality of NTs or NT equivalents, a solvent, and a degradable polymeric NT dispersant comprising:
a soluble polymer or copolymer comprising a polymer backbone with a multiplicity of repeating units comprising:
an NT associative group comprising a polycyclic aromatic group capable of non-covalent association with an NT or NT equivalent;
a linking group coupling the polymer backbone to the NT associative group; and
at least one cleavable group residing in the polymer backbone or in the linking group, wherein each of the NT associative groups is separated from each other by at least one of the cleavable groups;

depositing the NT dispersion on a substrate as a film;
promoting cleavage of the cleavable groups by changing one or more conditions of the film to form cleaved residues of the degradable polymeric NT dispersant;
removing the cleaved residues from the degradable polymeric NT dispersant; and
removing the solvent.

2. The method of claim 1 , wherein depositing comprises air brushing, electrostatic spraying, ultrasonic spraying, ink-jet printing, roll-to-roll coating, or dip coating.

3. The method of claim 1 , wherein promoting cleavage comprises thermolysis, photolysis, addition of a catalyst, addition of one or more reagents, addition of one or more solvents, or any combination thereof.

4. The method of claim 1 , wherein removing comprises filtering, washing, or evaporating.

5. The method of claim 1 , wherein the at least one cleavable group comprises an acetal, a ketal, a silyl ester, a silazane, an ester, an ether, an anhydride, and/or an ene.

6. The method of claim 1 , wherein the at least one cleavable group resides in the polymer backbone.

7. The method of claim 1 , wherein the at least one cleavable group resides in the linking group.

8. The method of claim 1 , wherein the NTs or NT equivalents comprise single-walled carbon nanotubes (SWNTs), double-walled carbon nanotubes, multi-walled carbon nanotubes (MWNTs), graphene sheets, and/or other graphene structures.

9. The method of claim 1 , wherein the polycyclic aromatic groups comprise pyrene, anthracene, pentacene, benzo[a]pyrene, chrysene, coronene, corannulene, naphthacene, phenanthrene, triphenylene, ovalene, benzophenanthrene, perylene, benzo[ghi]perylene, anthanthrene, pentaphene, picene, dibenzo[3,4;9,10]pyrene, benzo[3,4]pyrene, dibenzo[3,4;8,9]pyrene, dibenzo[3,4;6,7]pyrene, dibenzo[1,2;3,4]pyrene, naphtho[2,3;3,4]pyrene, porphyrin derivatives, or any combination thereof.

10. The method of claim 1 , wherein the polymer backbone comprises at least two repeating units formed by a step-growth or chain-growth polymerization with a degree of polymerization of at least two.

11. The method of claim 1 , wherein the polymer backbone comprises cellulose or another polymer of natural origin.

12. The method of claim 1 , wherein the linking group comprises about 2 to about 20 covalent bonds.

13. The method of claim 12 , wherein the linking group comprises a chain of carbon atoms or a chain comprising carbon atoms and one or more heteroatoms.

14. The method of claim 13 , wherein the one or more heteroatoms comprise oxygen, nitrogen, silicon, phosphorus, and/or sulfur.

15. The method of claim 12 , wherein the linking group comprises a chain of silicon atoms or a chain comprising silicon atoms and one or more heteroatoms.

16. The method of claim 15 , wherein the one or more heteroatoms comprise oxygen, nitrogen, and/or carbon.

17. The method of claim 1 , wherein the solvent comprises water, C 1 to C 6 alcohol, dichloromethane, tetrahydrofuran, ethyl acetate, acetone, dimethylformamide, acetonitrile, dimethylsulfoxide, hexane, benzene, toluene, chloroform and diethyl ether, or any combination thereof.

18. The method of claim 1 , wherein the NT dispersion further comprises a nanoparticle or microparticle.

19. The method of claim 18 , wherein the nanoparticle or microparticle comprises a conductive, semiconductive, or insulating material.

20. The method of claim 19 , wherein the insulating material is a material insoluble in the solvent of the dispersion but soluble in a second solvent.

Assignees

• Univ Florida

Inventors

• Walczak Ryan M
• Reynolds John R
• Rinzler Andrew Gabriel
• Spring Andrew M
• Vasilyeva Svetlana V
• Wadhwa Pooja

Classifications

• B82Y30/00

  Nanotechnology for materials or surface science, e.g. nanocomposites · CPC title

• B05D1/04

  involving the use of an electrostatic field {(B05D1/025 and B05D1/14 take precedence)} · CPC title

• H05K2201/0323

  Carbon · CPC title

• C01B32/174

  Derivatisation; Solubilisation; Dispersion in solvents · CPC title

• C01B32/168

  After-treatment · CPC title