Lithium transition metal oxide having layered structure

Patent metadata

Field	Value
Publication number	US-9640794-B2
Application number	US-201314396510-A
Country	US
Kind code	B2
Filing date	Apr 16, 2013
Priority date	Apr 27, 2012
Publication date	May 2, 2017
Grant date	May 2, 2017

Abstract

Provided is a lithium metal compound oxide having a layered structure, which is very excellent as a positive electrode active material of a battery that is mounted on, particularly, an electric vehicle or a hybrid vehicle.
Suggested is a lithium metal compound oxide having a layered structure which is expressed by general formula of Li 1+x M 1−x O 2 (M represents metal elements including three elements of Mn, Co, and Ni). In the lithium metal compound oxide having a layered structure, D50 is more than 4 μm and less than 20 μm, a ratio of a primary particle area to a secondary particle area of secondary particles having a size corresponding to the D50 (“primary particle area/secondary particle area”) is 0.004 to 0.035, and the minimum value of powder crushing strength that is obtained by crushing a powder using a microcompression tester is more than 70 MPa.

First claim

The invention claimed is:

1. A lithium metal compound oxide having a layered structure, which is expressed by general formula of Li 1+x M 1−x O 2 (M represents any one or more kinds among Mn, Co, Ni, transition elements that are present between group 3 elements and group 11 elements in a periodic table, and typical elements up to a third period in a periodic table), wherein 1+x=1.00 to 1.07 and a content molar ratio of Mn is 0.35 or less, a content molar ratio of Co is 0.05 to 0.40, and a content molar ratio of Ni is 0.45 or more,
wherein D50 according to volume-basis particle size distribution which is measured and obtained by a laser diffraction and scattering type particle size distribution measurement method (referred to as “D50”) is more than 4 μm and less than 20 μm,
a ratio of a primary particle area that is obtained by the following measurement method to a secondary particle area that is obtained by the following measurement method from secondary particles having a size corresponding to the D50 (referred to as “primary particle area/secondary particle area”) is 0.004 to 0.035, and
the minimum value of powder crushing strength that is obtained by crushing a powder using a microcompression tester is more than 70 MPa,
wherein the method of measuring the secondary particle area includes,
observing a lithium metal compound oxide using an electron microscope,
randomly selecting five secondary particles having a size corresponding to D50,
calculating an area by setting a length of the secondary particles as a diameter (μm) in a case where the secondary particles have a spherical shape, or calculating the area by carrying out approximation to a spherical shape in a case where the secondary particles have an indefinite shape, and
obtaining an average value of the five areas as the secondary particle area (μm 2 ), and
wherein the method of measuring the primary particle area includes,
observing a lithium metal compound oxide using an electron microscope,
randomly selecting five secondary particles per one visual field,
randomly selecting 10 primary particles from each of the five secondary particles that are selected,
calculating an area by setting the longest portion of spacing between grain boundaries to a major axis (μm) and setting of spacing between grain boundaries in a case where the primary particles have a rod shape, or calculating the area by setting the length of the spacing between the grain boundaries to a diameter (μm) in a case where the primary particles have a spherical shape, and
obtaining an average value of the fifty areas as the primary particle area (μm 2 ).

2. The lithium metal compound oxide according to claim 1 ,
wherein the lithium metal compound oxide is expressed by general formula of Li 1+x M 1−x O 2 (M represents any one or more kinds among Mn, Co, Ni, Al, V, Fe, Ti, Mg, Cr, Ga, In, Cu, Zn, Nb, Zr, Mo, W, Ta, and Re).

3. The lithium metal compound oxide according to claim 1 ,
wherein the lithium metal compound oxide is expressed by general formula of Li 1+x M 1−x O 2 (M includes Mn, Co, and Ni) and a content molar ratio of Mn, Co, and Ni is Mn:Co:Ni=35 or less:0.05 to 0.40:0.45 or more.

4. The lithium metal compound oxide according to claim 1 , wherein the lithium metal compound oxide is prepared by pulverizing a mixed powder of Li and the elements that comprise M using a high-speed rotary pulverizer at a rotation speed of 4000 rpm or more.

5. A lithium ion battery comprising:
the lithium metal compound oxide according to claim 1 as a positive electrode active material.

6. A lithium ion battery for a hybrid electric vehicle or an electric vehicle, comprising:
the lithium metal compound oxide according to claim 1 as a positive electrode active material.

7. A lithium ion battery comprising:
the lithium metal compound oxide according to claim 2 as a positive electrode active material.

8. A lithium ion battery comprising:
the lithium metal compound oxide according to claim 3 as a positive electrode active material.

9. A lithium ion battery for a hybrid electric vehicle or an electric vehicle, comprising:
the lithium metal compound oxide according to claim 2 as a positive electrode active material.

10. A lithium ion battery for a hybrid electric vehicle or an electric vehicle, comprising:
the lithium metal compound oxide according to claim 3 as a positive electrode active material.

Assignees

• Mitsui Mining & Smelting Co

Inventors

• Mitsumoto Tetsuya
• Ide Hitohiko
• Kagei Shinya
• Hata Yoshimi

Classifications

• Y02E60/10

  Energy storage using batteries · CPC title

• Y02T10/7011

  Cross-Sectional Technologies · mapped topic

• H01M2220/20

  Batteries in motive systems, e.g. vehicle, ship, plane · CPC title

• H01M4/485

  of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy (H01M4/505, H01M4/525 take precedence) · CPC title

• C01P2006/16

  Pore diameter · CPC title