Method for manufacturing solid electrolytic capacitor

Patent metadata

Field	Value
Publication number	US-9640325-B2
Application number	US-201414781237-A
Country	US
Kind code	B2
Filing date	Apr 4, 2014
Priority date	Apr 5, 2013
Publication date	May 2, 2017
Grant date	May 2, 2017

Abstract

A method for manufacturing a solid electrolytic capacitor, which includes the steps of: in a dispersion medium containing a monomer for obtaining a conjugated conductive polymer and a seed particle with protective colloid formed of a polyanion, polymerizing the monomer to obtain a conjugated conductive polymer-containing dispersion liquid; attaching the conjugated conductive polymer-containing dispersion liquid to the surface of a porous anode body at least having an anode body made of a valve metal and a dielectric film formed on the surface of the anode body; and removing a part or all of the dispersion medium from the conjugated conductive polymer-containing dispersion liquid attached to the porous anode body to form a solid electrolyte layer. Also disclosed is a solid electrolytic capacitor obtained by the method.

First claim

The invention claimed is:

1. A method for manufacturing a solid electrolytic capacitor, comprising the steps of:
in a dispersion medium comprising a monomer for obtaining a conjugated conductive polymer and a seed particle with protective colloid formed of a polyanion coordinated on a surface of the seed particle, polymerizing the monomer to obtain a conjugated conductive polymer-containing dispersion liquid;
attaching the conjugated conductive polymer-containing dispersion liquid to the surface of a porous anode body at least having an anode body made of a valve metal and a dielectric film formed on the surface of the anode body; and
removing a part or all of the dispersion medium from the conjugated conductive polymer-containing dispersion liquid attached to the porous anode body to form a solid electrolyte layer.

2. The method according to claim 1 , wherein the seed particle is a homopolymer or a copolymer obtained by polymerizing an ethylenically unsaturated monomer.

3. The method according to claim 1 , wherein the particle size D50 of the seed particle with protective colloid formed of a polyanion is from 0.01 to 10 μm.

4. The method according to claim 1 , wherein in the step to obtain the conjugated conductive polymer-containing dispersion liquid, an additional dispersion liquid containing a seed particle with protective colloid formed of a polyanion is added during the polymerization of the monomer.

5. The method according to claim 1 , wherein in the step to obtain the conjugated conductive polymer-containing dispersion liquid, the generated conjugated conductive polymer is subjected to dispersion treatment during the polymerization of the monomer.

6. The method according to claim 5 , wherein the dispersion treatment is conducted under ultrasonic irradiation.

7. The method according to claim 1 , wherein the monomer for obtaining a conjugated conductive polymer is at least one selected from a group consisting of a pyrrole containing or not containing a substituent, an aniline containing or not containing a substituent, and a thiophene containing or not containing a substituent.

8. The method according to claim 1 , wherein the monomer for obtaining a conjugated conductive polymer comprises a compound expressed by the following formula (I):

wherein R 1 and R 2 each independently represent a hydrogen atom, a hydroxyl group, an alkyl group with 1 to 18 carbon atoms containing or not containing a substituent, an alkoxy group with 1 to 18 carbon atoms containing or not containing a substituent, or an alkylthio group with 1 to 18 carbon atoms containing or not containing a substituent, or may bind to each other to form a ring such as an alicycle with 3 to 10 carbon atoms containing or not containing a substituent, an aromatic ring with 6 to 10 carbon atoms containing or not containing a substituent, an oxygen atom-containing hetero ring with 2 to 10 carbon atoms containing or not containing a substituent, a sulfur atom-containing hetero ring with 2 to 10 carbon atoms containing or not containing a substituent, or an oxygen and sulfur atom-containing hetero ring with 2 to 10 carbon atoms containing or not containing a substituent.

9. The method according to claim 1 , wherein the polyanion is a polymer with a sulfonate group.

10. The method according to claim 1 , wherein the anion group of the polyanion is from 0.25 to 30 mol based on 1 mol of the monomer for obtaining a conjugated conductive polymer.

11. The method according to claim 1 , wherein the step to obtain the conjugated conductive polymer-containing dispersion liquid,
the dispersion medium comprises water, and
the polymerization is conducted by using at least one oxidant selected from a group consisting of a peroxodisulfuric acid and salts thereof.

12. The method according to claim 1 , wherein the conjugated conductive polymer-containing dispersion liquid comprises at least one electric conductivity improver selected from a group consisting of ethylene glycol, propylene glycol, and glycerin.

Assignees

• Showa Denko Kk

Inventors

• Tagawa Yasuyuki
• Murata Naoki
• Araki Motoaki
• Ohkubo Takashi

Classifications

• H01G9/048

  characterised by their structure (H01G11/22 takes precedence) · CPC title

• H01G9/0036 Primary

  Formation of the solid electrolyte layer · CPC title

• H01G9/028

  Organic semiconducting electrolytes, e.g. TCNQ · CPC title

• H01G9/15

  Solid electrolytic capacitors (H01G11/00 takes precedence) · CPC title