Electrophotographic photoreceptor, manufacturing method of electrophotographic photoreceptor, image-forming apparatus and image-forming method

Patent metadata

Field	Value
Publication number	US-9639010-B2
Application number	US-201414499900-A
Country	US
Kind code	B2
Filing date	Sep 29, 2014
Priority date	Oct 4, 2013
Publication date	May 2, 2017
Grant date	May 2, 2017

Abstract

Disclosed is an electrophotographic photoreceptor including a conductive support, a photosensitive layer on the conductive support and a surface layer on the photosensitive layer. The surface layer includes a cured resin prepared by polymerization of a compound having two or more radically polymerizable functional groups per molecule, the cured resin containing an organic resin fine particle and a metal oxide fine particle, and the organic resin fine particle comprising a resin containing a structural unit derived from at least one of melamine and benzoguanamine, the organic resin fine particle having a number average primary particle size of 0.01 to 3.00 μm.

First claim

What is claimed is:

1. An electrophotographic photoreceptor, comprising:
a conductive support;
a photosensitive layer on the conductive support; and
a surface layer on the photosensitive layer,
wherein
the surface layer comprises a cured resin prepared by polymerization of a compound having two or more radically polymerizable functional groups per molecule, the cured resin containing an organic resin fine particle, a metal oxide fine particle, and a charge transportable compound,
the organic resin fine particle comprising a resin containing a structural unit derived from at least one of melamine and benzoguanamine, the organic resin fine particle having a number average primary particle size of 0.01 to 3.00 μm, and
the charge transportable compound is represented by Formula 1:

wherein R 1 and R 2 each independently represent a hydrogen atom or methyl group, and R 3 represents a linear or branched alkyl group having one to five carbon atoms.

2. The electrophotographic photoreceptor according to claim 1 , wherein the organic resin fine particle comprises a polycondensate of melamine and formaldehyde.

3. The electrophotographic photoreceptor according to claim 1 , wherein the organic resin fine particle is contained in an amount of 5 to 40 parts by mass relative to 100 parts by mass of the cured resin.

4. The electrophotographic photoreceptor according to claim 1 , wherein the metal oxide fine particle is surface-treated with a surface treating agent comprising a compound having a radically polymerizable functional group.

5. The electrophotographic photoreceptor according to claim 1 , wherein the cured resin comprises an acrylic resin.

6. An image-forming apparatus, comprising:
an electrophotographic photoreceptor;
a charging unit to charge the surface of the electrophotographic photoreceptor;
an exposing unit to form an electrostatic latent image on the surface of the electrophotographic photoreceptor;
a developing unit to develop the electrostatic latent image with a developer comprising a toner to form a toner image;
a transferring unit to transfer the toner image onto a transfer medium;
a fixing unit to fix the transferred toner image on the transfer medium;
a cleaning unit to remove residual toner on the electrophotographic photoreceptor; and
a lubricant applying mechanism to apply a lubricant on the surface of the electrophotographic photoreceptor,
wherein
the electrophotographic photoreceptor is the electrophotographic photoreceptor according to claim 1 .

7. The image-forming apparatus according to claim 6 , wherein the charging unit is of a contact or contactless roller discharging mechanism.

8. A method of forming an image, comprising:
charging a surface of the electrophotographic photoreceptor;
exposing to form an electrostatic latent image on the surface of the electrophotographic photoreceptor;
developing the electrostatic latent image with a developer comprising a toner to form a toner image;
transferring the toner image on a transfer medium;
fixing the transferred toner image on the transfer medium; and
cleaning to remove a residual toner on the electrophotographic photoreceptor,
wherein
the developer further comprises a lubricant, and the electrophotographic photoreceptor is the electrophotographic photoreceptor according to claim 1 .

9. The method of forming an image according to claim 8 , wherein in the charging, the electrophotographic photoreceptor is charged by a contact or contactless roller discharging mechanism.

10. An electrophotographic photoreceptor, comprising:
a conductive support;
a photosensitive layer on the conductive support; and a surface layer on the photosensitive layer,
wherein

the surface layer comprises a cured resin prepared by polymerization of a compound having two or more radically polymerizable functional groups per molecule, the cured resin containing an inorganic fine particle and an organic resin fine particle, at least part of the surface of the inorganic fine particle comprising a metal oxide and the organic resin fine particle comprising a resin containing a structural unit derived from at least one of melamine and benzoguanamine, and
the organic resin fine particle is surface-treated with a coupling agent.

11. The electrophotographic photoreceptor according to claim 10 , wherein the organic resin fine particle has a number average primary particle size of 100 nm to 1500 nm.

12. The electrophotographic photoreceptor according to claim 10 , wherein the coupling agent contains a fluorine atom.

13. The electrophotographic photoreceptor according to claim 10 , wherein the inorganic fine particle has a number average primary particle size of 10 nm to 300 nm.

14. The electrophotographic photoreceptor according to claim 10 , wherein the inorganic fine particle comprises at least one of tin oxide and titanium oxide.

15. The electrophotographic photoreceptor according to claim 10 , wherein the inorganic fine particle is a composite fine particle comprising a core and a metal oxide sheath.

16. The electrophotographic photoreceptor according to claim 15 , wherein the core comprises at least one of aluminum oxide, barium sulfate, and silicon oxide.

17. The electrophotographic photoreceptor according to claim 15 , wherein the sheath comprises at least one of tin oxide and titanium oxide.

18. The electrophotographic photoreceptor according to claim 10 , wherein the radically polymerizable functional group is an acryloyl group or methacryloyl group.

19. An image-forming apparatus, comprising:
an electrophotographic photoreceptor;
a charging unit which charges a surface of the electrophotographic photoreceptor;
an exposing unit which forms an electrostatic latent image on the surface of the electrophotographic photoreceptor;
a developing unit which develops the electrostatic latent image with a developer comprising a toner to form a toner image;
a transferring unit which transfers the toner image onto a transfer medium;
a fixing unit which fixes the transferred toner image on the transfer medium; and
a cleaning unit which removes residual toner on the electrophotographic photoreceptor,
wherein
the cleaning unit comprises a blade, and
the electrophotographic photoreceptor is the electrophotographic photoreceptor according to claim 10 .

Assignees

• Konica Minolta Inc

Inventors

• Hatano Hokuto
• Kurimoto Kazunori
• Maeda Seisuke
• Takao Hiroki

Classifications

• G03G5/14734

  Polymers comprising at least one carboxyl radical, e.g. polyacrylic acid, polycrotonic acid, polymaleic acid; Derivatives thereof, e.g. their esters, salts, anhydrides, nitriles, amides · CPC title

• G03G5/14791

  Macromolecular compounds characterised by their structure, e.g. block polymers, reticulated polymers, or by their chemical properties, e.g. by molecular weight or acidity · CPC title

• G03G5/14769

  Other polycondensates comprising nitrogen atoms with or without oxygen atoms in the main chain · CPC title

• G03G5/0546

  Polymers comprising at least one carboxyl radical, e.g. polyacrylic acid, polycrotonic acid, polymaleic acid; Derivatives thereof, e.g. their esters, salts, anhydrides, nitriles, amides · CPC title

• G03G5/0575 Primary

  Other polycondensates comprising nitrogen atoms with or without oxygen atoms in the main chain · CPC title