Scavenging hydrogen sulfide

Patent metadata

Field	Value
Publication number	US-9638018-B2
Application number	US-201314108617-A
Country	US
Kind code	B2
Filing date	Dec 17, 2013
Priority date	Dec 19, 2012
Publication date	May 2, 2017
Grant date	May 2, 2017

Abstract

Alpha-hydroxy alkyl esters have been found to perform as hydrogen sulfide scavengers. A method of scavenging hydrogen sulfide includes contacting a fluid containing hydrogen sulfide with a treatment fluid including an alpha-hydroxy alkyl ester. Accordingly, the alpha-hydroxy alkyl ester reacts with the hydrogen sulfide to reduce the amount of hydrogen sulfide in the fluid. A broad range of alpha-hydroxy alkyl esters are disclosed.

First claim

What is claimed is:

1. A method of reducing the amount of hydrogen sulfide in a hydrocarbon-containing fluid, the method comprising:
contacting the hydrocarbon-containing fluid with a treatment fluid including at least one alpha-hydroxy alkyl ester, wherein the hydrogen sulfide reacts with the alpha-hydroxy alkyl ester to reduce an amount of the hydrogen sulfide in the hydrocarbon-containing fluid; and
wherein the alpha-hydroxy alkyl ester is selected from the group consisting of bis(hydroxymethyl) maleate; (2E, 4E)-hydroxymethyl hexa-2,4-dienoate; (E)-hydroxymethyl but-2-enoate; (E)-bis(hydroxymethyl) O,O′-(2-hydroxypropane-1,3-diyl) difumarate; hydroxymethyl 6-(2,5-dioxo-2,5-dihydro-1H-pyrrol-1-yl)hexanoate; and a combination thereof.

2. The method of claim 1 , wherein the reaction product is amine-free.

3. The method of claim 1 , wherein the treatment fluid includes between 5 and 20 volume percent of the alpha-hydroxy alkyl ester.

4. The method of claim 1 , wherein the treatment fluid includes between 10 and 15 volume percent of the alpha-hydroxy alkyl ester.

5. The method of claim 1 , wherein the treatment fluid includes a mixture of water and ethanol.

6. The method of claim 1 , wherein the hydrocarbon-containing fluid has been produced from a subterranean formation.

7. The method of claim 6 , wherein the hydrocarbon-containing fluid is a gas.

8. The method of claim 7 , wherein the contact between the hydrocarbon-containing fluid and the treatment fluid occurs in an absorption tower.

9. The method of claim 1 , wherein contacting the hydrocarbon-containing fluid with the treatment fluid including the at least one alpha-hydroxy alkyl ester comprises:
pumping the treatment fluid under pressure through a wellbore into a subterranean formation and maintaining the treatment fluid in the region around the wellbore for a predetermined period of time, wherein the alpha-hydroxy alkyl ester adsorbs onto the subterranean formation in a region around the wellbore; and
flowing the hydrocarbon-containing fluid from the subterranean formation into the wellbore, wherein the hydrogen sulfide reacts with the alpha-hydroxy alkyl ester as the hydrocarbon-containing fluid flows through the region around the wellbore to reduce an amount of hydrogen sulfide in the hydrocarbon-containing fluid before the hydrocarbon-containing fluid flows into the wellbore.

10. The method of claim 9 , wherein the treatment fluid is maintained in the region around the wellbore for a predetermined period of time to allow the alpha-hydroxy alkyl ester to absorb onto the subterranean formation.

11. The method of claim 1 , wherein the alpha-hydroxy alkyl ester comprises bis(hydroxymethyl) maleate.

12. The method of claim 1 , wherein the alpha-hydroxy alkyl ester comprises (2E, 4E)-hydroxymethyl hexa-2,4-dienoate.

13. The method of claim 1 , wherein the alpha-hydroxy alkyl ester comprises (E)-hydroxymethyl but-2-enoate.

14. The method of claim 1 , wherein the alpha-hydroxy alkyl ester comprises (E)-bis(hydroxymethyl) O,O′-(2-hydroxypropane-1,3-diyl) difumarate.

15. The method of claim 1 , wherein the alpha-hydroxy alkyl ester comprises hydroxymethyl 6-(2,5-dioxo-2,5-dihydro-1H-pyrrol-1-yl)hexanoate.

Assignees

• Ecolab Usa Inc

Inventors

• Martinez Aaron D
• Mukkamala Ravindranath
• Acosta Otero Erick J
• Bailey Joseph P

Classifications

• B01D53/52

  Hydrogen sulfide · CPC title

• B01D2252/202

  Alcohols or their derivatives · CPC title

• E21B43/25 Primary

  Methods for stimulating production {(by vibrating earth formations E21B43/003)} · CPC title

• E21B43/34 Primary

  Arrangements for separating materials produced by the well · CPC title

• B01D53/1493 Primary

  Selection of liquid materials for use as absorbents · CPC title