Applicator with hydrophobic coating transferable to contacting surface

Patent metadata

Field	Value
Publication number	US-9637670-B2
Application number	US-201414202741-A
Country	US
Kind code	B2
Filing date	Mar 10, 2014
Priority date	Oct 29, 2012
Publication date	May 2, 2017
Grant date	May 2, 2017

Abstract

A coating composition for imparting a hydrophobic film on a target surface is provided that includes an oil of a silicone oil or a fluoropolymer oil or a combination thereof, a resin, and a dry lubricant. A solvent is present to form a solution of the oil and resin. A coating is imparted to an applicator that in turn can transfer the coating as a hydrophobic film. The coating composition is stable and able to impart hydrophobic film even after storage for several weeks at elevated temperature. The coating composition does so through the exclusion of synthetic waxes especially including silicone waxes. A kit is also provided that includes a wiper blade having the above coating composition applied along with instructions for the securement of the wiper blade to a vehicle to impart the hydrophobic film to a vehicle windshield contacted by the wiper blade.

First claim

The invention claimed is:

1. A kit for producing a hydrophobic film on a vehicle window surface, the kit comprising:
an applicator having an applicator surface;
a nonvolatile layer formed from a composition comprising: an oil selected liquid at 20° C. from a group consisting of a silicone oil, fluoropolymer oil, and a combination thereof; a resin soluble in said oil; and a particulate lubricant; the composition being free of all of: a silicone wax, a curing agent, and a curing catalyst operative to cross link said oil or said resin; said nonvolatile layer adhered to the applicator surface or applied thereto from a container;
a protective cover overlying said nonvolatile layer and having an internal surface, said protective cover is such that the coating is not in contact with the internal surface of the cover from the time said nonvolatile layer is produced to the time that the wiper blade is installed on a vehicle to produce a hydrophobic film on the vehicle window surface with a water droplet contact angle of greater than or equal to 80° with the contact angle being measured by ASTM C813, the kit having a storage stability of greater than one month at an average temperature of between −50° C. and 120° C.; and
instructions for contacting the applicator surface with the vehicle window surface to produce the hydrophobic film having a water contact angle of greater than or equal to 80°.

2. The kit of claim 1 wherein nonvolatile layer has a thickness of between 0.5 and 500 microns.

3. The kit of claim 1 wherein the nonvolatile layer is applied to both sides of a wiping lip of a rubber element of said applicator, said applicator is a wiper blade, and said nonvolatile layer is applied by spray, dip coating, or being brushed onto the rubber element in an amount ranging from 0.001 to 0.1 g per inch length per side.

4. The kit of claim 1 wherein said nonvolatile layer is non-drying and is transferrable from the applicator surface to the vehicle window surface by wiping.

5. The kit of claim 3 wherein the coated wiping lip of the rubber element causes the windshield to become hydrophobic after a number of wipe cycles either under dry, or wet, or combination of dry and wet condition.

6. The kit of claim 1 wherein the nonvolatile layer has a storage stability of greater than three months at an average temperature of −50 and 120° C.

7. The kit of claim 1 wherein said applicator is a wiper blade, and the vehicle window surface is a windshield.

8. The kit of claim 1 wherein said applicator is formed of at least material of chloroprene rubber, natural rubber, or silicone or any combination of them.

9. The kit of claim 8 wherein said applicator is coated with a friction coating prior to said nonvolatile layer being applied thereto.

10. The kit of claim 1 wherein said oil is only said silicone oil.

11. The kit of claim 1 wherein said oil is present from 1 to 95 total weight percent of said nonvolatile layer.

12. The kit of claim 1 wherein said resin is a silicone resin.

13. The kit of claim 1 wherein said resin is present from 0.1 to 80 total weight percent.

14. The kit of claim 1 wherein said particulate lubricant is selected from the group consisting of graphite, turbostratic carbon, boron nitride, boric acid, polytetrafluoroethylene (PTFE), molybdenum disulfide (MoS 2 ), and combinations thereof.

15. The kit of claim 1 wherein said particulate lubricant is present from 0.1 to 50 total solvated weight percent.

16. The kit of claim 1 further comprising a solvent in which said oil and said resins are dissolved.

Assignees

• Illinois Tool Works
• Illinois Tool Works

Inventors

• Fang Jiafu

Classifications

• C10N2030/26

  Waterproofing or water resistance · CPC title

• C10N2020/06

  Particles of special shape or size · CPC title

• C10N2050/02

  dissolved or suspended in a carrier which subsequently evaporates to leave a lubricant coating · CPC title

• C10N2030/40

  Low content or no content compositions · CPC title

• C10N2020/02

  Viscosity; Viscosity index · CPC title