Single column stripping and drying process

Patent metadata

Field	Value
Publication number	US-9637593-B2
Application number	US-201615046357-A
Country	US
Kind code	B2
Filing date	Feb 17, 2016
Priority date	Sep 29, 2009
Publication date	May 2, 2017
Grant date	May 2, 2017

Abstract

Organic materials are stripped and dried in a single column having two contact zones. A stripping gas is introduced into an upper contact zone and flows through the organic material in that zone. A drying gas is introduced into a lower contact zone. The drying gas contacts the organic material in both the upper and lower contact zones, and is removed from the top of the column together with the stripping gas. This process permits very efficiently removal of volatile organic compounds as well as efficient drying, while requiring on low levels of the stripping and drying gasses.

First claim

What is claimed is:

1. A process for stripping and drying a starting organic material, comprising:
a) introducing the starting organic material into an upper contact zone of a column that has an upper contact zone and a lower contact zone, and allowing the starting organic material to travel downwardly through the column, through the upper contact zone and then through the lower contact zone to a bottom section of the column;
b) introducing 0.0002 to 0.02 kg of superheated steam per kg of starting organic material into the upper contact zone of the column and above the lower contact zone of the column such that the superheated steam moves upwardly through the upper contact zone, where it contacts the starting organic material and removes impurities therefrom, and then to a top section of the column;
c) introducing 0.0001 to 0.003 kg of nitrogen or argon per kg of starting organic material into the lower contact zone of the column such that the nitrogen or argon moves upwardly through the lower contact zone where it contacts a portion of the organic material and removes moisture therefrom, then moves upwardly through the upper contact zone where it contacts another portion of organic material, and then moves to a top section of the column;
d) removing the steam and the nitrogen or argon from the top section of the column above the upper contact zone; and
e) removing the stripped and dried organic material from the bottom section of the column below the lower contact zone,
wherein the starting organic material is a liquid polyether having a molecular weight of from 500 to 10,000 or crude polymer polyol, the starting organic material contains from 50 to 5,000 ppm of volatile organic impurities and up to 50,000 ppm of water, and the stripped and dried organic material contains up to 10 ppm of volatile organic compounds and up to 200 ppm of water.

2. The process of claim 1 wherein the nitrogen or argon contains no more than 50 ppm moisture.

3. The process of claim 2 , wherein the column is operated at a pressure of from 5 to 100 mbar.

4. The process of claim 3 , wherein the column is operated at a temperature of from 90 to 150° C.

Assignees

• Seavey Kevin C
• Moore Walter C
• Weston John W
• Villa Carlos M
• Dow Global Technologies Llc

Inventors

• Seavey Kevin C
• Moore Walter C
• Weston John W
• Villa Carlos M

Classifications

• C08G65/30 Primary

  Post-polymerisation treatment, e.g. recovery, purification, drying · CPC title

• B01D3/343

  the substance being a gas · CPC title

• B01D3/143 Primary

  by two or more of a fractionation, separation or rectification step · CPC title

• B01D3/26

  Fractionating columns in which vapour and liquid flow past each other, or in which the fluid is sprayed into the vapour, or in which a two-phase mixture is passed in one direction · CPC title

• C08F6/00

  Post-polymerisation treatments (C08F8/00 takes precedence; of conjugated diene rubbers C08C) · CPC title