Elastic terpolymer including diene group and preparation method thereof

Patent metadata

Field	Value
Publication number	US-9637579-B2
Application number	US-201314442382-A
Country	US
Kind code	B2
Filing date	Oct 14, 2013
Priority date	Jun 28, 2013
Publication date	May 2, 2017
Grant date	May 2, 2017

Abstract

The present invention relates to an elastic terpolymer which can satisfy excellent processability and elasticity (flexibility) at the same time, and a preparation method thereof. The elastic terpolymer is a copolymer of 40 to 70 weight % of ethylene, 15 to 55 weight % of a C 3 -C 20 alpha-olefin, and 0.5 to 20 weight % of a diene obtained in the presence of a group 4 transition metal catalyst, of which i) the weight average molecular weight measured by GPC is 100,000 to 500,000, and ii) Δ tan δ, the difference between the tan δ values at the angular frequencies of 0.2 rad/s and 100.0 rad/s, is 0.5 or less that is measured at 100° C. by using a rubber process analyzer.

First claim

The invention claimed is:

1. An elastic terpolymer of 40 to 70 weight % of ethylene, 15 to 55 weight % of a C 3 -C 20 alpha-olefin, and 0.5 to 20 weight % of a diene obtained in the presence of a group 4 transition metal catalyst, of which
i) the weight average molecular weight measured by GPC is 100,000 to 500,000, and
ii) Δ tan δ, the difference between the tan δ values at the angular frequencies of 0.2 rad/s and 100.0 rad/s measured at 100° C. by using a rubber process analyzer, is 0.5 or less.

2. The elastic terpolymer according to claim 1 , wherein the tan δ value at the angular frequency of 0.2 rad/s is 0.45 to 0.8.

3. The elastic terpolymer according to claim 1 , having density of 0.840 to 0.895 g/cm 3 .

4. The elastic terpolymer according to claim 1 , having Mooney viscosity (1+4 {circle around (a)} 125° C.) of 5 to 180.

5. The elastic terpolymer according to claim 1 , having a molecular weight distribution of 2 to 4.

6. The elastic terpolymer according to claim 1 , wherein the alpha-olefin is one or more compounds selected from the group consisting of propylene, 1-butene, 1-hexene, and 1-octene, and the diene is one or more compounds selected from the group consisting of 5-ethylidene-2-norbornene, 5-methylene-2-norbornene, and 4-hexadiene.

7. A method of preparing the elastic terpolymer of claim 1 , including copolymerizing the monomer composition including 40 to 70 weight % of ethylene, 20 to 50 weight % of a C 3 -C 20 alpha-olefin, and 2 to 20 weight % of a diene while feeding the composition continuously into a reactor, in the presence of a catalyst composition including a first transition metal compound represented by the following Chemical Formula 1 and a second transition metal compound represented by the following Chemical Formula 2:

wherein, in Chemical Formulae 1 and 2,
R 1 to R 13 may be equal to or different from each other, and may independently be hydrogen, a C 1 -C 20 alkyl radical, a C 2 -C 20 alkenyl radical, a C 6 -C 20 aryl radical, a silyl radical, a C 7 -C 20 alkylaryl radical, a C 7 -C 20 arylalkyl radical, or a metalloid radical of a group 4 metal substituted with a hydrocarbyl, wherein the 2 different neighboring groups among R 1 to R 13 may form an aliphatic ring or an aromatic ring by being connected with an alkylidene radical including a C 1 -C 20 alkyl or a C 6 -C 20 aryl radical;
M is a group 4 transition metal; and
Q 1 and Q 2 may be equal to or different from each other, and may independently be a halogen radical, a C 1 -C 20 alkyl radical, a C 2 -C 20 alkenyl radical, a C 6 -C 20 aryl radical, a C 7 -C 20 alkylaryl radical, a C 7 -C 20 arylalkyl radical, a C 1 -C 20 alkylamido radical, a C 6 -C 20 arylamido radical, or a C 1 -C 20 alkylidene radical.

8. The method according to claim 7 , wherein the first transition metal compound is one or more compounds selected from the group consisting of compounds represented by the following chemical formulae:

wherein, in above formulae, R 2 and R 3 are equal to or different from each other, and are independently hydrogen or a methyl radical, M is a group 4 transition metal, and Q 1 and Q 2 are equal to or different from each other, and are independently a methyl radical, a dimethylimido radical, or a chlorine radical.

9. The method according to claim 7 , wherein the second transition metal compound is one or more compounds selected from the group consisting of compounds represented by the following chemical formulae:

wherein, in above formulae, R 2 and R 3 are equal to or different from each other, and are independently hydrogen or a methyl radical, M is a group 4 transition metal, and Q 1 and Q 2 are equal to or different from each other, and are independently a methyl radical, a dimethylimido radical, or a chlorine radical.

10. The method according to claim 7 , wherein the catalyst composition further includes one or more cocatalyst compounds selected from the group consisting of the compounds represented by the following Chemical Formulae 3 to 5:
—[Al(R)—O] n —  [Chemical Formula 3]

in Chemical Formula 3, R's are equal to or different from each other, and are independently a halogen, a C 1 -C 20 hydrocarbon, or a C 1 -C 20 hydrocarbon substituted with a halogen, and n is an integer of 2 or more;
D(R) 3   [Chemical Formula 4]

in Chemical Formula 4, R's are the same as defined in Chemical Formula 3, and D is aluminum or boron; and
[L-H] + [ZA 4 ] − or [L] + [ZA 4 ] −   [Chemical Formula 5]

in Chemical Formula 5, L is a neutral or cationic Lewis acid, H is a hydrogen atom, Z is a group 13 element, and A's are equal to or different from each other, and are independently a C 6 -C 20 aryl group or a C 1 -C 20 alkyl group of which one or more hydrogen atoms are substituted with a halogen, a C 1 -C 20 hydrocarbon, an alkoxy, or a phenoxy, or are not substituted.

11. The method according to claim 7 , wherein the alpha-olefin is one or more compounds selected from the group consisting of propylene, 1-butene, 1-hexene, and 1-octene, and the diene is one or more compounds selected from the group consisting of 5-ethylidene-2-norbornene, 5-methylene-2-norbornene, and 4-hexadiene.

12. The method according to claim 10 , wherein the copolymerizing step is carried out while continuously providing the monomer composition, the first and second transition metal compounds, and the cocatalyst compound in the form of a liquid to the reactor.

13. The method according to claim 12 , wherein the copolymerizing step is continuously carried out while continuously discharging the copolymerized elastic terpolymer from the reactor.

14. The method according to claim 7 , continuously the copolymerizing step is carried out at a temperature of 100 to 170° C.

Assignees

• Lg Chemical Ltd

Inventors

• Yoon Sung-Cheol
• Park Sung-Ho
• Ko Jun-Seok
• Choi Soo-Young

Classifications

• C08L2314/06

  Metallocene or single site catalysts · CPC title

• C08F2420/02

  Cp or analog bridged to a non-Cp X anionic donor · CPC title

• C08F4/6592

  containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring · CPC title

• C08F4/65908

  in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+ · CPC title

• C08F4/65904

  in combination with another component of C08F4/64 · CPC title